more pressure gauges and thermometer at various points in the system. Good insulation and shorter piping through good design planning can reduce the heat loss and gain in the system. ________________________________________ 2.3.2 VA cycle The thermodynamic calculations of the VA cycle is described by Shukla, et al. (2015) and Eastop and McConkey(2009). The designation of each character in the equations has been changed to reflect the naming of each state in figure 3. The following assumptions…
1.0) The Ellingham Diagram 1.1) Introduction The Gibbs free energy (∆G) of a reaction is defined as the measure of the thermodynamic force that drives a reaction to occur. When ∆G is positive, it indicates that a reaction will not occur spontaneously while when ∆G is negative, the reaction is spontaneous. The Gibbs free energy equation is given by : ∆G = ∆H –T∆S ∆H refers to the enthalpy and is a measure of the actual energy that is released when the reaction occurs. A negative…
In his video “"The Laws of Thermodynamics and Fate of the Universe," Michio Kaku, an American theoretical physicist, states that “one day, Universe will freeze to death.” He supports his idea by using the first and second laws of thermodynamics, which highlight such as frightening prediction. However, I don’t think it’s enough to make the final conclusion. It’s not just thermodynamics that reveal molecular life and its processes. Biological and physical conditions should also be applied even…
Abstract— The present study was made to evaluate the performance of Braysson cycle. Braysson cycle is a hybrid gas turbine, combination of Brayton cycle and Ericsson cycle. The hybrid gas turbine is proposed based on the Brayton cycle at high temperature heat addition and low temperature heat rejection at Ericsson cycle. The performance was evaluated in terms of thermal efficiency, exergy losses and specific power output. Energy and exergy analysis was carried out on Braysson cycle and Brayton…
This photo is a picture of my lofted bed next to a large two-paned window. This is just one of two windows in my dorm room in De Smet Hall. The concept that I will discuss regarding my photo is thermodynamics and transfer of heat. Specifically, I will be discussing conduction from the temperature outside of De smet and the temperature of my dorm room. The material that the energy will transfer through is the two large two-paned windows that are on each wall. I will complete example calculations…
Evaporation Model, Kohler modification and Surface Phenomena The process of microdroplet evaporation is associated with the mass and heat transport through the microdroplet surface [1,2] . [2]: [ 1] Where a is the droplet radius, Pa and Pcc are the saturated vapor pressures near the droplet surface and far from the droplet respectively. Ta and Tcc are the temperatures at the microdroplet surface and the reservoir. D is the diffusion constant of vapor in the ambient gas. M and are the…
The Calorimetric Determination of Enthalpy and Entropy Changes of the Thermal Decomposition of Sodium Sulphate Decahydrate Abstract Sodium sulphate decahydrate thermally decomposes to anhydrous sodium sulphate at 50⁰ C and cools to form anhydrous sodium sulphate. Using Hess's Law the enthalpy and entropy changes of this process can be determined in order to deduce the spontaneity of the reaction. The transition temperature was determined by melting the hydrated crystals at 50⁰ C and allowing…
• The heat (q) “lost” or “gained” is related to a) sample mass b) change in T and c) specific heat capacity Specific heat capacity = heat lost or gained by substance (J) (mass, g)(T change, K) © 2006 Brooks/Cole - Thomson 11 Change in Temperature (T) ∆T of System Increase Sign of ∆Tsystem + Tfinal >Tinitial Tfinal < Tinitial Sign of q + Direction of Heat Transfer Heat transferred from surroundings to system (_____thermic) Heat transferred from system to surroundings (_____thermic)…
1 Introduction Since the early 1970s the need for a clean and environmental friendly alternative to the use of fossil fuel in combustion engines, especially in individual transportation, has grown with ups and downs over time. Increased awareness of climate change and global warming have enforced the so called hydrogen energy transition, which describes the significant change from the dominant oil based technologies towards the use of hydrogen as a clean fuel in transportation. Although hydrogen…
percent difference of 1.99%, and -185.50.0013kJ/mol with a percent difference of 129.9%, respectively. Overall, the experiment showed that heats of combustions of substances can be determined via bomb calorimetry. Introduction The first law of thermodynamics states that energy is conserved.1 Using that law it can be said that the change in the internal energy of a system () depends on the heat added (q) to the system and the work (w) done by the system.1 Equation 1 illustrates the relationship…