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25 Cards in this Set

  • Front
  • Back

carbon compounds

-make up most of living organisms


-forms large complex molecules


-form Proteins, DNA, carbohydrates and other life molecules

organic chemistry

§thestudy of compounds that contain carbon

vitalism

§thebelief in a life force outside the jurisdiction of physical and chemical laws

mechanism

§theview that physical and chemical laws govern all natural phenomena

Wohler (1828)

§able to synthesize (organic) urea from(inorganic) ammonium (NH4+) andcyanate (CNO-)ions – cyanate ions derived from human blood

Miller (1953)

§Experimentssupport the idea that abiotic synthesis of organic compounds, perhaps nearvolcanoes, could have been a stage in the origin of life

length

double bond position

branching

rings

hydrocarbons

§organicmolecules consisting of only carbon and hydrogen


-can release a lot of energy


-found in fats

isomers

§compoundswith the same molecular formula but different structures and properties

structural isomers












§different covalent arrangements of their
atoms

§different covalent arrangements of theiratoms

cis-trans isomers (geometric isomers)












§have the same covalent bonds but differ
in spatial arrangements

§have the same covalent bonds but differin spatial arrangements

enantiomers












§isomers that are mirror images
of each other

§isomers that are mirror imagesof each other

§organismsare sensitive to even subtle variationsin molecules


-ex. S-ibuprofen vs. R-ibuprofen

Differing effects of enantiomersdemonstrate that



functional groups

§thecomponents of organic molecules that are most commonly involved in chemicalreactions

§Hydroxyl group


§Carbonyl group


§Carboxyl group


§Amino group


§Sulfhydryl group


§Phosphate group


§Methyl group

The seven functional groups

hydroxyl group












Polar due to electronegative oxygen. Forms hydrogen bonds with water.

Compound name: Alcohol

Polar due to electronegative oxygen. Forms hydrogen bonds with water.Compound name: Alcohol

carbonyl group

           Sugars with ketone groups are called ketoses; those with aldehydes

are
called aldoses.

Compound name: Ketone or aldehyde      

Sugars with ketone groups are called ketoses; those with aldehydesarecalled aldoses.Compound name: Ketone or aldehyde

carboxyl group












Acts as an acid.

Compound name: Carboxylic acid, or organic acid

Acts as an acid.Compound name: Carboxylic acid, or organic acid

amino group












Acts as a base.

Compound name: Amine

Acts as a base.Compound name: Amine

sulfhydryl group












Two —SH groups can react, forming a “cross-link” that helps stabilize

protein structure.

Compound name: Thiol

Two —SH groups can react, forming a “cross-link” that helps stabilizeprotein structure.Compound name: Thiol

phosphate group












Contributes negative charge. When attached, confers on a molecule the
ability

to react with water, releasing energy.

Compound name: Organic phosphate

Contributes negative charge. When attached, confers on a molecule theabilityto react with water, releasing energy.Compound name: Organic phosphate

methyl group












Affects the expression of genes. Affects the shape and function of

sex hormones.

Compound name: Methylated compound

Affects the expression of genes. Affects the shape and function ofsex hormones.Compound name: Methylated compound