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39 Cards in this Set

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  • Back

How are particles in a solid arranged?

Packed closely together


Vibrate around fixed positions

How are particles in a liquid arranged?

Particles are packed closely together, but can slip over each other in a random motion

How are the particles in a gas arranged?

Move randomly


Have lots of space between them

Give reasons for the limitations of the particle model:

It assumes that substances are made up of solid spheres with no forces acting between them


Substances are made up of atoms, molecules and ions, which are mostly empty space


They are not solid spheres and have different sizes and shapes with forces between them

What changes occur to the particles of a gas as it is cooled to a temperature below its boiling point?

Gas particles slow down and come closer together


New intermolecular forces are formed between the particles


Energy is given out


This stops when all the gas has become liquid

What happens to particles when a solid is heated above its melting point?

Solid particles absorb energy


Energy is used to overcome strong forces of attraction between neighbouring particles


They break away from their fixed positions and start moving around


No temperature rise until all the particles have melted

Is energy transferred to or from the surroundings in melting/ boiling?

From surroundings to the substance

Is energy transferred to or from the surroundings in condensation/ freezing?

To the surroundings from substance

Why do substances have different melting and boiling points?

Have different intermolecular forces between the particles

What is a mixture?

A substance made up of two or more elements or compounds that are not chemically bonded together

What are 3 ways that mixtures are different to compounds?

1) have no fixed composition


2) elements/ compounds can be easily separated


3) no chemical bonds between components of mixture

What main 4 techniques are used to separate mixtures?

Filtration, crystallization, distillation, chromatography

When is filtration used?

Insoluble solid from a solvent

How might you separate a soluble solid from a solution?

By evaporation followed by crystallization.


Slowly heat a solution in an evaporating basin to remove some of the solvent.


Using a glass rod, dip the end of the rod into the solution and dab onto a white tile.


If solution starts to crystalize, remove the basin from the heat and allow to cool.


The salt will become insoluble in the cool highly concentrated solution and crystals will start to form.


Filter the crystals out of solution and place in drying oven.


How can the process of distillation be used to remove dissolved impurities from a sample if water?

Heat the mixture until boiling.


Evaporated solvent passes down condenser and the vapour is cooled below its boiling point and condenses.


Any dissolved solid will remain in the flask.

What is an acid?

Substance that produces H+ ions when added to water


Eg: HCl, HNO3, H2SO4

What is a base?

Substance that will neutralise an acid


Eg: metal oxide, metal hydroxide

How is an alkali different to a base?

Alkali is a soluble base. Produce OH- ions when added to water


Eg: metal hydroxide

What is the general equation for a neutralisation reaction?

Acid + alkali -> salt + water

What is the ionic equation for neutralisation?

H+ + OH- -> H2O

What pH is neutral?

pH7

What range of pH is alkali?

8-14

What is the product of reaction between hydrogen and hydroxide ions?

Water

pH of 4.2 us?

Acidic

Lithium hydroxide (alkali) reacts with hydrochloric acid


A) what type of reaction is this?


B) what is formed in this reaction?

A) neutralisation


B) salt (lithium chloride) + water

What are the 4 main neutralisation reactions?

Acid + alkali


Metal + acid


Metal oxide + acid


Metal carbonate + acid

What happens to the total energy in the universe during a chemical reaction?

Stays the same as overall amount of energy in the reactants and surroundings doesn't change- energy is conserved

What do you call a reaction that transfers energy to its surroundings?

Exothermic

What do you call a reaction that takes in energy from its surroundings?

Endothermic

Examples of exothermic reactions?

Combustion


Neutralisation


Oxidation reactions


Examples of endothermic reactions?

Thermal decomposition


Electrolysis


Photosynthesis

What is an example of an everyday use of an endothermic reaction?

Sports injury packs- takes in heat and the chemicals become very cold, removing heat from to the site of the injury

A) How would you measure the energy released by a chemical reaction between two solutions?


B) what is one common error with this experiment?

A) Measure the volume of known solutions and record the starting temperatures.


Pour both solutions into an insulating polystyrene cup and stir.


Observe the temperature of the mixture and record the max temperature it reaches


B) energy lost to the surroundings

What is the activation energy?

Minimum amount of energy the reactant particles need to collide with each other to start a reaction

Is breaking bonds exo or endothermic?

Endothermic

What energy change takes place when new bonds are formed?

Exothermic

Why is energy released to surroundings during exothermic reaction?

Energy released by bond formation is greater than the energy used to break bonds

What is the bond energy of a chemical bond?

Amount of energy required to break a bond (or released when is made)

How do you calculate energy change of reaction?

Energy change = energy of bond breaking - energy of bond making