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216 Cards in this Set

  • Front
  • Back

Explusion of Hydrocarbons from source rock

Primary Migration

The two types of evolution of Organic Matter in source rocks during burial

1. Bacterial Decay:


Organic Matter -> Methane



2. Increasing Temperature


Organic Matter -> Kerogen -> Bitumen -> Oil + Gas + Residue

Kerogen Maturation and Hydrocarbon Generation Graph

How does Oil get out of the Source Rock?



Source rocks are _____ ______ with high total organic content (TOC)



Source rocks have very low permeability around ________ to ________ Darcy

black shales



1 x 10^-9 to 1 x 10^-7 Darcy

What is the problem with expulsion during compaction? (Proposed Expulsion Mechanism)

Wrong Timing

Wrong Timing


What is the problem with the dissolution in water? (Proposed Expulsion Mechanism)

Insufficient

Insufficient



What is the problem with the natural detergents or micelles? (Proposed Expulsion Mechanism)

Insufficient


What is the problem with the dissolution in gas phase? (Proposed Expulsion Mechanism)


Works for light oil, but not for heavy oil

Works for light oil, but not for heavy oil

Explain the Oil Phase Migration. (Proposed Expulsion Mechanism)

Kerogen is 5-10% of source rocks and is load bearing.



Maturation transforms kerogen to a hydrocarbon fluid.



The fluid is also load-bearing, therefore overpressured.



Overpressure fractures the rock.



Hydrocarbons escape through microcracks.



Cracks close up until a new episode of generation takes place.

Hydrocarbon maturation creates ________ ________ that allows the oil and gas to escape the impermeable source rock.

fracture porosity

Name four main characteristics of Primary Migration.

High % TOC (Total Organic Content)



Kerogen to liquid transformation



Microfracturing



Expulsion

Secondary Migration consists of these 6 things.

Driving Force


Resisting Forces


Phase Behavior


Rates of Migration


Efficiency


Long Distance Migration

Secondary migration is driven by ________ and opposed by __________ _________.

bouyancy



capillary pressure

Secondary Migration



Movement from source to ____.



Along _______ bed.



As separate hydrocarbon _____. (mostly)

trap



carrier



phase

State the capillary pressure equation.

Mercury pressure vs. Mercury saturation

The larger the column of oil, the higher the _______ force.

bouyancy

Seals are not absolute. They depend on _____.

forces

The smaller the pore space, the harder it is for oil to get through.

Displacement Pressure in Seal Rock

Because rocks are inhomogeneous , oil does not fill the entire reservoir. (The capillary sizes are different.)

The WOC and GOC are horizontal if hydrostatic.

___ can move through seals easier because it is more bouyant.

Gas

Migration Pathways

Migration Pathways


(up dip: perpendicular to contours)

Evidence for long distance migration

Term for when bacteria eat short-chain hydrocarbons

biodegradation

Oil can move ______ miles from the source rock.

hundreds of miles

Migration is relatively short when compared to the _____ ____.

basin life

During migration there is a loss of some oil due to ________.

wetting

____ sorting typically leads to low porosity and permeability.

Poor

What is % of void space in rock?

Porosity

What is ease of fluid flow?

Permeability

Total porosity and Effective Porosity

View of Porosity


0-5% _____


5-10% _____


10-15% _____


15-20% ______


20-25% _____





0-5% Negligible


5-10% Poor


10-15% Fair


15-20% Good


20-25% Very Good

For ___, lower porosity is still viable.

gas

______________ makes low porosity less of a problem.

Hydrofracturing

Name the five things that control primary porosity.

1. Degree of Uniformity of Grain Size (Sorting)


2. Shape of the Grains


3. Method of Deposition (Manner of Packing)


4. Compaction


5. Cementation

Classify the sorting.

Classify the sorting.

Poor sorting

Classify the sorting.

Classify the sorting.

Intermediate sorting

Cubic packing has __% in the ideal situation.

Rhombohedral packing has __% porosity in the ideal situation.

Additional open space developed after sedimentation.

Secondary porosity

Name 3 Sandstone modifications to porosity

1. Pressure Solution


2. Cementation


3. Fracturing

Name 5 Carbonate modifications to porosity

1. Compaction - 2 to 20%


2. Solution


3. Recrystalization - Dolomitization


4. Fracturing


5. Cementation


Name 2 Shale modifications to porosity

1. Compaction - 50%


2. Bound Water Expulsion

What does the % cement affect the porosity?

More cement means less porosity.

Porosity in Sandstone

More fractures leads to more porosity.

________ Porosity

________ Porosity

Secondary Porosity

When limestone is exposed to water with Mg, some Ca are replaced by Mg.

Dolomitization

Since dolomite is more compact than calcite, this leads to ___ ______.

new porosity

Dolomitization

Shale

Large well connected pores are ______.

permeable

Smaller, fewer or less interconnected pores are _________.

impermeable

Darcy's Equation

Permeability Values


1-10md ____


10-100md ____


100-1000md ____

Permeability Values


1-10md Fair


10-100md Good


100-1000md Very Good

1 _____ permits a flow of 1cm3/s of fluid with viscosity 1cp under a pressure gradient of 1atm/cm acting across an area of 1cm2.

darcy

Highest permeability to lowest

Clean sand -> Silty sand -> Sandstone & Limestone -> Marine Clay -> Shale

Porosity can be measured by _____ and _____ logs.

density and neutron logs

Permeability requires ____ for lab injection tests.

cores

Log (permeability) vs. porosity is linear.

Flow changes with _______ saturation.

multi-fluid

Relative Permeability

Petroleum exists in ___ _____.

pore space

______ and _____ decrease porosity.

compaction and cementation

_____, _____, and _____ increase porosity.

Dissolution, fracturing and dolomitization

______ controls migration and production

Permeability

Oil, gas and water _____ each other's flow.

impede

_____ ______ are necessary to manage reservoirs effectively.

Reservoir models

What makes a carbonate reservoir?

1. porosity strongly controlled by post-depositional processes


2. high initial porosity


3. rapid cementation


4. dissolution creates secondary porosity (usually due to acidic water.

Carbonate Porosity Types

Intergranular Porosity

Vuggy and Moldic Porosity

Beach Systems

Dissolution by Meteoric Water

Karst and Unconformities

Persian Gulf Petroleum System

Arab D Reservoir - Ghawar

Daily Oil Production as of 2008

1. Russia


2. Saudi Arabia


3. USA


4. Iran


5.China

What is Dolomitization?

When dolomite forms during diagenesis or hydrothermal alteration.


Fractured Reservoirs

Evidence for fluid flow along Fractures in Sandstone.

Systematic Orthogonal Fractures

Fracture Spacing/Bedding

Sealed Fractures

Ooids

Intragranular porosity

Estimated Ultimate Recovery Map

Net Pay Isopach

Important things to know

Important things to know

Calcite filled vugs and fractures

Fault well production

What is very important in carbonate reservoirs?

secondary porosity

What creates new porosity?

dolomitization, dissolution, and fracturing

What does exposure to meteoric water lead to?

limestone dissolution

What does natural fracture networks enhance?

permeability

There is no way to control formation fluids and pressures with...

a cable tool drilling rig

Cable Tool Drilling Rig

A rotary drilling rig consists of

engines, hoist system, rotating system, mud system

Rotary Drilling

Traveling Block

The Rotary System

Tricone Bit

Drilling Rates

-Sandstones are fast


-Limestone/dolomite can be slow


-Shales are slow

Mud System

Drilling Mud

-Bentonite (clay) - 9-10 lb/gal


-Barite (BaSO4) - 15-20 lb/gal

Casing

Coring Assembly and Core Bit

Types of offshore oil and gas structures

Horizontal Drilling Components

What is used downhole in deviation drilling?

knuckles or swivel joints

What is the aim for directional control?

The aim is to create the appropriate side force on the bit so that the resultant force drives the bit to the desired direction.

Drilling tools and methods

Drilling tools and methods

Logging-while Drilling tools

-Directional Data (inclination, azimuth, tool-face)


-Formation characteristics (gamma-ray, resistivity logs, etc)


-Drilling parameters (down-hole WOB, torque, rpm)

Logging a horizontal well

Hydraulic fracturing in a wellbore

Where was the Macondo Well located?

On a deepwater horizon rig off the coast of Alabama, Mississippi, and Louisiana in the Gulf of Mexico.

About how many active platforms are in the US Gulf?

about 4000

DeepWater Horizon Rig

-owned and operated by Transocean


-Contracted by BP and it partners (Anadarko, Mitsui)


-state of the art vessel


-dynamically positioned

Macondo Well Reservoir Properties

Problems Prior to Accident

Why did they prepare to temporarily abandon the well?

-long string casing


-nitrogen foam cement job by Halliburton


-cement test by Halliburton showed 48 hours needed for cement to set at 180 F.


-April 18- Casing installed with only 6 centralizers (instead of 21)


-Had trouble with bottoms-up circulation

The Blow Out - April 20

The Blow Out

Aftermath

Efforts to stop the leak

Blow Out Preventer

-Shear ram blocked by buckled pipe


-Miss wiring and battery failure in the emergency system

(Maconda Well) Small errors can

add up

(Maconda Well) Economic pressures and safety are in a

natural conflict

(Maconda Well) "Getting the job done" sometimes leads you to a

bad outcome

The Logging Operation

-100 and 200 feet repeat section measured at the bottom


-then tool is raised through the entire well


-casing may prevent some logs from working


-logging speed: 1800 to 3600 ft/hour


-information pertinent to both the logging run and the well is recorded on the header


-logs recorded digitally

Log Types

Spontaneous Potential (SP)

-one of the oldest logging measurements (used commercially in 1931)


-discovered as noise in resistivity


-found to be related to presence of sandstone

The well works like a battery

SP (Spontaneous Potential)

has poor limestone response

Gamma Ray Log

Spectral Gamma Ray

distinguishes the different sources of gamma rays

The Borehole Environment

Resistivity

What are the 3 classes of resistivity tools

-electrode logs


-laterologs (focused electrodes)


-induction

The normal resistivity tool spacing of electrodes determines

penetration

The guard or laterolog electrodes focus

the current in a narrow disk

(Induction) Receiver coil measures

the induced electrical field created in the rocks by the transmitter coil

ID (deep induction), IM (medium induction), and LL8 (shallow induction) measures

resistivity at different distances form the borehole

Calculating Fluid Saturation

Sonic (Acoustic) Logs

Sonic (Acoustic) Logs

Which unit is the best reservoir?

low shale and high porosity

Creating synthetic seismic data

Density Log

-measures of density


-tied to lithology, porosity, and fluid content


-tool emits gamma rays


-detects returning scattered gamma rays


-gamma ray absorption is proportional to rock density

Porosity Calculation

Neutron Log (CNL)

If lithology is known...

neutron and density logs can be calibrated for porosity

Gamma Ray Response to Grain Size

Relating log character to sedimentary facies

 


 


Steps of building a reservoir model

1. define facies in core


2. relate facies to log


3. predict facies in wells without core, but with good logs.

Log Datum Terminology

Mud pulse telemetry

pressure pulses

electromagnetic telemetry

using conductivity of drill pipe

wired drill pipe

The future. Faster and better, but delicate.

Dipmeter

vertical dip variation is characteristic of the structure

Well logs provide

key data for understanding the subsurface

Lithology, porosity and fluids are

3 important log families

Usually you can't measure these properties directly, so you must use

proxies or indirect measurements

Multiple logs used in combination are

most powerful

Label

Label

_____ _____ is the process by which hydrocarbons are expelled from the source rock into an adjacent permeable carrier bed.

Primary migration


Solution: The solubility of hydrocarbons is water is very low, usually less than 50 ppm. Exceptions are methane, benzene and toulene which may have solubilities of 500 to 2000 ppm at reservoir conditions. Solubility is enhanced by increasing temperature, but within the oil window temperatures are too low to make any difference. In summary, the volumes of water required to move the hydrocarbons found in a normal oil field would huge due to the low solubility. So this is not an important mechanism for primary migration.

_____ are molecules that behave like soap, attaching themselves to a hydrocarbon molecule on one end and to an OH- at the other end. These could increase the amount of hydrocarbons transported by water. However, micelles are not found in rocks in sufficiently large quantities to explain most hydrocarbon accumulations.

Micelles

_______ of most hydrocarbons through rocks is also exceedingly slow. Methane can diffuse through shales, but very slowly. This helps to explain why small quantities of methane can be detected in many sedimentary rocks, but cannot explain the formation of any significant gas deposit. Molecules larger than butane are to big to move by diffusion at all.

Diffusion

Gas phase migration- Compressed gas can dissolve liquid hydrocarbons. For example at 5000 psi (conditions found at about 10,000 feet) methane and decane (C1 and C10) form a single gas phase. Migration of hydrocarbons dissolved in the gas phase can facilitate the movement of hydrocarbons through the source rock, as the gas phase migrates into shallower regions where temperature is lower, the liquid hydrocarbons come out of solution. However, the gas/oil ratio of most oil fields is too low for the gas to be the only means of transporting the oil out of the source rock. Also at the onset of generation most the kerogen produces little gas, most gas is generated late during the maturation history.

Oil Phase Migration- Most hydrocarbons probably are expelled from the source rock as liquids. The expulsion of the oil out of the source rock is a dynamic process driven by the oil generation itself. Good source rocks have TOC (total organic content) ranging from 3 to 10%. At low TOC the kerogen may occupy a position within the matrix porosity of the rock, at high TOC the kerogen can form connected bands within the rock. Then the kerogen is bearing part of the lithostatic load. As he organic matter transforms into oil this load-bearing kerogen turns into liquid. The fluid pressure of the oil within the black shales can become high enough to produce microfractures in the rock. Once the microfractures form, the oil is squeezed out and the source rock collapses. So primary migration can be viewed as a second episode of compaction. Microfractures of this type can be seen in most productive source rocks and they are often filled with remnants of oil.

In order for expulsion to take place a minimum level of saturation of the source rock with oil must be reached. This minimum level depends on the viscosity ratio between the oil and the water. Low viscosity oils can be expelled at low saturation (less than 10%), high viscosity oils require saturations larger than 50%. This means that the efficiency of generation is greater for low viscosity (high API) oil than for high viscosity (low API).

______ _____ is the movement of hydrocarbons along a "carrier bed" from the source area to the trap. Migration mostly takes place as one or more separate hydrocarbons phases (gas or liquid depending on pressure and temperature conditions). There is also minor dissolution in water of methane and short chain hydrocarbons.

Secondary migration

Driving forces for migration:

* _______ (This force acts vertically and is proportional to the density difference between water and the hydrocarbon so it is stronger for gas than heavier oil)
* ______ ____ (water potential deflect the direction of oil migration, the effect is usually minor except in over pressured zones (primary migration))

Buoyancy



Hydrodynamic flow

Resisting forces:

* _____ ____ (opposes movement of fluid from coarse-grain to fine- grain rock, also the capillary pressure of the water in the reservoir resists the movement of oil)

Capillary pressure

One result of hydrodynamic flow is a tilted oil-water contact (OWC) in a trap. OWC is an equipotential surface, but if the water is flowing the equipotential surfaces are inclined in the direction of flow, so the OWC will be tilted too.

During migration the pressure and temperature conditions of the hydrocarbons can change a lot affecting the _____ _______ of the oil.

phase behavior

Example 1: Type I, oil prone source rock during peak generation produces oil with a gas-oil ratio (GOR) of 0.2 kg/kg (1000 cf/bbl). At depths greater than ~10,000 ft all the gas can be dissolved in the oil.Migration will be as a single liquid hydrocarbon phase. Above ~10,000 ft the gas will begin to exsolve, like opening a soda can. At that point two hydrocarbon phases will migrate together.

Example 2: A gas-prone source rock produces a gas condensate with high proportion of dissolved liquid C6+ hydrocarbons. As pressure and temperature drop the C6+ fraction will condensate as a minority liquid phase.

___ __ ______ is controlled by Darcy's law q= -k/v dp/dz (for a single fluid phase)


where q=volumetric flow rate, k=permeability, v=viscosity, dp/dz=pressure gradient.


Given typical permeabilities of sandstone, and flow rate of oil can range from 1 to 1000 km per million years. This is faster than rate of generation and expulsion, so oil generation is the rate-limiting factor.

Rate of migration

Because the carrier bed has to reach a minimum oil saturation before oil can flow, there is a volumetric loss associated with migration. The oil will seek a tortuous path of least resistance which typically will be a small portion of the total carrier bed volume.

Very long horizontal migration distances have been documented in some basins, in the Alberta basin of Canada the oil has migrated more than 400 km. In other cases the dominant direction of migration is vertical following fault or fracture systems, such as some accumulation in the North Sea.


What is good porosity?


0-5% - Negligible


5-10%- Poor


10-15%- Fair


15-20%- Good


>20% - Very good

Practical cut off for oil



Sandstone ~8%


Limestone ~5%


For gas the cut off is lower

This microphotographs illustrates the typical components of a sandstone reservoir: quartz grains (gray), secondary quartz cement (also gray), pore space (dark), and secondary minerals in the pore spaces (brownish). Notice that the original grains are well rounded, but the quartz cement is forming a polygonal crystal.

This is an example of well-rounded, clean sandstone. The green area is open pore space. This rock has high porosity and probably high permeability also.

Poorly sorted coarse sandstone. The spaces between the large, well-rounded grains are filled by small angular fragments in a dark clay-rich matrix. This rock has very low porosity and permeability.

This is a sandstone that has been completely cemented. It is now a quartzite: a metamorphic rock with no porosity left. Notice that irregular grain boundaries, like a jig-saw puzzle.This is the result of pressure solution under high stress conditions. Pressure solution causes the grains to indent each other at the points of contact.

This is an oolitic sandstone with most of the primary porosity (space between the round oolites) filled with secondary quartz crystals.

This is the key parameter in determining reservoir quality. Many rocks (shales for example) have high porosity, but very low permeability. Determined from Darcy's law.

Permeability

Main controls on permeability are:


Grain size (determines the size of the pore throats)


Pore connectivity

When multiple fluids are present they interfere with each other. So that the effective permeability of the moving fluid is much lower than if a single fluid is present. In a typical reservoir at least water and oil are present, frequently water, oil, and gas share the pore space.

Effective permeability

What is good permeability?


<1 millidarcy - Poor


1-10 md- Fair


10-100 md- Good


100-1000 md- Very good

Processes that reduce porosity and permeability:

Compaction


Cementation


Heavy hydrocarbon residue

Processes that enhance porosity and permeability:

Dissolution


Fracturing


Dolomitization

____ ___ are often subjected to early cementation, so reservoir quality depends very strongly on dissolution, fracturing and dolomitization. Most carbonate reservoirs are due to secondary porosity.


Reefs sometimes preserve primary porosity.

Carbonate rocks

total thickness of the reservoir unit

Gross pay

the fraction of the reservoir that has porosity above a minimum threshold (this is the sum of the productive zones)

Net pay

Reservoir barriers



Reservoirs are heterogeneous in both vertical and horizontal dimension at all scales. This is due to Stratigraphic facies changes, faults, variation in diagenetic features such as cementation or dissolution, etc. A huge body of data is needed to adequately characterize most reservoirs. Most often reservoir barriers are revealed by the pressure history of neighboring wells.

A modern rotary drill rig is composed of four separate systems:


Engines-Power everything


Hoist syst.-Used to lift, lower and suspend the drill string in the well


Rotating syst.-


Mud System

The rotating system consists of the kelly, rotary table, the drill string, the drill collars and the bit.

The mud system is used to pump drilling mud down the drill string and back up to the surface. This system has multiple functions:


Control the subsurface pressure via


Mud weight


Blow-out preventers (valves)


Prevent the hole from collapsing


Cool the drill bit


Remove the drill cuttings



Drilling mud is a key element of the drilling process. If the mud weight is too high the reservoir may be damaged, if too low there may be a blow out if a high pressure zone is encountered.


Steel casing (heavy gage pipe) is used to maintain the integrity of the hole and to isolate specific strata.



Surface casing is always set in order to attach the blow-out preventers to control pressure. If the well is successful, production casing is lowered to the reservoir, cemented to the walls and perforated in front of the reservoir unit in order to be able to test and produce that interval.


In some cases it is necessary to set an intermediate casing in order to isolate an over pressured (or under pressured) layer. Otherwise it would be necessary to maintain excessively high mud weight that would invade the reservoir damaging it.

Wells are not always vertical. If the beds are tilted the well will tend to "walk" up-dip causing the well to deviate. In other cases the well is deviated on purpose, such as in order to drill several wells from a single surface location, or if it necessary to "side-track" the hole to avoid an obstruction. Directional drilling is done with a bit that is powered by a down hole motor (or turbine) instead of powered by turning the entire drill string from the surface.

During drilling well side geologists monitor many parameters that help figure out the stratigraphy that is being drilled, as well as detect any hydrocarbons that may be present.


Log of the well cuttings


Log of gas and gas chromatography


Oil shows


Drilling rate


Mud weight


Any kicks (high pressure zones)

Drilling rate depends on lithology.

Sandstones are fast to drill, shales are more difficult as well as carbonates.

Cores can be used to sample any unit of interest. Sidewall cores are collected by lowering a tool that has hollow sampling bullets attached with a wire. Small cylindrical plugs are recovered when the tool is pulled back out.


Conventional cores are cut with a bit that cuts a cylinder of rock and traps it inside the drill string.

Drill-stem-tests (DST): It is possible to test the fluids in an open hole by setting packers above and below the interval of interest. This way a unit is isolated and the formation fluids are allowed to flow into the drill string. This way the formation pressure, and permeability can be measured and the formation fluids sampled. DST's are often unreliable because it is difficult to completely isolate the reservoir unit. Also frequently some of the drilling mud has invaded the formation, so pristine fluids do not flow into the well.

The table on the left summarizes the main types of logs and their uses. The principal uses of well logs are:


Lithologic determinations


Stratigraphic correlations


Evaluation of formation fluids


Porosity determination


Correlation with seismic data


Location of faults and fractures


Determination of the dip of strata

This is an example of the use of the Gamma ray (GR), SP, Resistivity (Rsn, Ril), Neutron (CNL), and Density (FDC) logs to identify a gas-rich zone. The Gamma Ray and SP indicate the location of the reservoir bed, the high Resistivity at the top of the bed shows that it is saturated with hydrocarbons, the cross-over of the Neutron and Density logs shows that the hydrocarbon in question is gas.