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33 Cards in this Set

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Relative atomic mass from isotopic abundance

Multiply each relative isotopic mass by its % isotopic abundance


Add up results


Divide by 100

Use mass spectra to work out relative atomic mass

Multiply each isotopic mass by its isotopic abundance


Add up results


Divide by sum of the isotopic abundance

Avogadro constant

Number of particles in one mole


6.02x10^23

Finding the number of moles from the number atoms or molecules

Number of particles you have


Divided by


Number of particles in a mole

Find the number of moles using Mr

Mass of substance


Divided by


Molar mass

Molar gas volume

Volume in dm3


Divided by


Molar gas volume


Equals number of moles

At r.t.p it is 24

Ideal gas equation

pV=nRT


Let’s you find the number of moles in a certain volume at any temperature and pressure

Gas constant

8.134 JK-1mol-1

Empirical formula

Smallest whole number ration of atoms in a compound

Molecular formula

The actual number of atoms of each type of element in a molecule

Ionic equations show reacting particles

Nitric acid with sodium hydroxide


HNO3+NAOH=NaNO3+ H2O


Ionic substances will dissolve, braking u the ions.


(H+)+(NO3-) +(Na+) +OH-=(Na+) +(NO3-)+H2O


Cross out ions that appear on both sides.


Ionic equation is H+OH=H2O


Make sure the charges balance

Actual yield

Actual mass of product


Always less then theoretical yield

Percentage yield

Actual yield/theoretical yield x100


Tells how wasteful the process is. But not how wasteful the reaction is.

Atom economy

Measure of the proportion of reactant atoms that become the desired product


Molecular mass of desired product/ sum of molecular masses of ALL products


X100

Ionic structure

Ionic compounds conduct electricity when molten or dissolved. Not when they are solid


Have high melting and boiling points held together by strong electrostatic forced. Takes a lot of energy to break them.


Tend to dissolve in water

Covalent bonding

A covalent bond is the strong electrostatic attraction between a shared pair of electrons and the nuclei of the bonded atoms.

Strength of a covalent bond

Shown by its Average Bond Enthalpy


Measures energy required to break a covalent bond.

Dative covalent bonding

Where both electrons come from one atom

Balance equations show reaction stoichiometry

Calculate the mass of iron oxide produced if 28g of iron is burnt in the air.


2Fe+3/2O2=Fe2O3


Molar mass of Fe is 55.8g mol-1


Number of moles in 28g is 28/55.8=0.50 moles


2 moles of age produces 1 mole of Fe2O3


0.50 moles of Fe produced 0.25 moles of Fe2O3


Molar mass of Fe2O3 is 159.6g mol-1


Mass of Fe2O3 is 0.25*159.6= 40g

Reaction stoichiometry

Tells the ratio of reactants to products

Stat

How much gas is produced when 15g of sodium is reacted with excess water at rtp


2Na+2H2O=2NaOH+H2


M of Na is 23.0g mol-1


In 15g 15/23.0 =0.65 moles


2 moles of Na produces 1mole of H2


Volume of H2 is 0.325*24=7.8dm3

Acids

Means all of the chemical will react

State symbols

S=solid


L=liquid


G=gas


Aq=aqueous (solution in water)

The

Proton donors


Release H ions


Common acids: HCl, H2SO4, HNO3, CH3COOH

Bases

Proton acceptors


Grab H ions


Bases that are Soluble in water known as alkalis


They release OH- ions


Common bases: NaOH, KOH and NH3

Find moles from concentration

Concentration*volume (cm)


Divide by 1000

Theoretical yield

The maximum product you can get


If no chemical are lost


Mass of reactants and number of moles

How to measure liquid

Always read the volume from the bottom of the meniscus when it is at eyelevel.

How to measure gases?

Gases can be measured with a gas syringe. They should be measured at room temperature pressure as the volume of a gas changes with temperature and pressure.


Make sure it’s completely sealed and that the plunger move smoothly.

How to measure solid?

You weigh solids using a balance. Make sure that your balance is set to exactly 0 before weighing your substance. If you need to transfer the solid to another container make sure that it’s all transferred or you could reweigh the Weighing container after you transferred the solid so that you can work out exactly how much you’ve added to your experiment.

Precise results are repeatable meaning that if the same person does the experiment again is in the same methods and equipment they will get the same results. They also need to be reproducible meaning that if someone else does experiment with a different method or piece of equipment results will still be the same.

Precise results are repeatable meaning that if the same person does the experiment again is in the same methods and equipment they will get the same results. They also need to be reproducible meaning that if someone else does experiment with a different method or piece of equipment results will still be the same.

How to minimise any errors that might sneak into your data?

Use apparatus and techniques correctly.


Take measurements correctly.


And repeat your experiments and calculate the mean

Percentage error

To calculate percentage error



Uncertainty divided by reading times by 100.



E.g. the balance measures to the nearest 0.2 g and is used to measure the change in mass of a substance. But initial mass is measured as 40.4 g. The final mass is measured at 22.0 g calculate the percentage error?


40.4 takeaway 22.0 equals 18.4 g – the change in mass. The balance measures to the nearest 0.2 g so each reading has an uncertainty of 0.1 g to readings have been combined so the total uncertainty is 0.1×2 which equals 0.2 g so the change in mass percentage error is 0.2 divided18.4×100 = 1 .1%

For any piece of equipment you use, that uncertainty will be half the smallest increments they equipment to measure in either direction.


If combining measurements you will need to combine their uncertainties