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15 Cards in this Set

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Crystalline solids


Examples

Those solids whose cons particles are arranged in a definite geometric pattern in 3d.


NaCl, quartz


Long range order is possessed by (and what does it mean)

Regular pattern(of particles) which repeats itself periodically (over the entire crystal).

Amorphous solids

Solids whose constituent particles are NOT arranged in a regular arrangement.


A-morpho= No form

Short range order

In A solids, a regular pattern (of cons particles) is repeated over short distances only

Crystal lattice/space lattice

Regular arrangement of cons particles (of a crystalline solid) in 3d space.

Unit cell

A small 3d repeating portion of crystal lattice which when repeated over and over again(in 3d space) generates the entire crystal lattice.


Types(on the basis of distribution of const particles)


•primitive unit cell


•centered/non-primitive " "

3 characteristics of crystal lattice

• eacg point in a lattice is Ka lattice point.


lattice points rep constituent particles.


lattice points are joined using strght lines to bring out geometry of the crystal lattice.


Chara of unit cell

•edge length a b c ( x b ee za re cy )


• angles (start from z and clockwise, assign alpha beta gamma)

Crystal defects

Irregularities in arrangement (of const particles in a crystal).

Types of crystal defects

Point defects


Line defects

Point defects

(arise due to) irregularities/deviation from ideal arrangement around points or atoms(in a crystal subs)

Line defects

Irregularities/ deviation from ideal arrangement in entire rows of lattice points in a crystal.

Point defects types

• Stoichiometric defects


•Non stoichiometric defects


•impurity defects

Stoichiometric defects definition

Point defects that do NOT disturb the stoichiometry of the solid.

Stoichiometric defects are aka

Intrinsic/ thermodynamic defects