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25 Cards in this Set

  • Front
  • Back

Bromination rxn

Br2/FeBr3

Chloronation

Cl2/FeCl3

Sulfination

So3/h2So4

Nitration

HNo3/H2SO4

Fridel crafts

RCl/AlCl3

What does Zn(Hg)/HCl do?

Knocks off the =O

KMnO4

Replaces on the most substituted carbon with cooh

H2 PdC or Fe/HCl or Sn/HCl

Changed NO2 to NH2

HCOOH




1

Methanoic Acid




Formic Acid

CH3COOH




2

Ethanoic Acid




Acidic Acid

CH3CH2COOH




3

Propanoic Acid




Propionic Acid

CH3CH2CH2COOH




4

Butanoic Acid




Butyric Acid

CH3CH2CH2CH2COOH




5

Pentanoic Acid




Valeric Acid

CH3CH2CH2CH2CH2COOH




6

Hexanoic Acid




Caproic Acid

NaBH4, CH3OH


or


LiAlH4 + H2O


or


H2 PdC

Adds H to =O and to the carbon eliminating the double bond on the O

H2 1 eq. PdC

reduction of C=C

H2 excess PdC

Reduction of both C=C and C=O

NaBH4 CH3OH

reduction of C=O

S or R CBS and H2O

Elimination of C=O to C-O

Any Cr or Ag2O, NH4OH

adding a OH replacing H on a carboxilic acid

RMgX or RLi with H2O

Changing O=C to OH and adding R to C also gets rid of any OH on C if thats the starting point.

RMgX with CO2 and H3O

RCOOH

Epoxide with RLi, RMgX or R2CuLi and H2O

Separate epoxide and add H to O and R to free Carbon

RLi or RMgX and H20

O=C bond to OH

R2CuLi with H2O

C=C bond to single bond and add R