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93 Cards in this Set

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Atomic number

The number of protons in the nucleus of an atom

Protons in

Mass Number

The number of protons and neutrons in the nucleus of an atom

Number of isotopes

Isotopes

Atoms of the same element (same number of protons and electrons) With a different number of neutrons

Atoms of

Atomic orbital

Region around the nucleus that can hold up to two electrons, with opposite spins

A region around

P block element

Element which has the highest energy electron in a p sub shell

Element which

First ionisation energy

The energy required to remove One electron from each atom in One mole of gaseous atoms to form one mole of gaseous 1+ ions kjmol

Energy required

Successive ionisation energy

Measure of the energy required to remove one electron in turn

In turn

Acid

Proton donor

Donor

Base

Proton acceptor

Acceptor

Alkali

Base that dissolves in water and releases 0H- ions in aqueous solution

OH-

Salt

Compound produced when a H+ ion from an acid is replaced with a metal ion or another positive ion such as an ammonium ion

Replaced

Molar Mass

The mass in grams per mole of a substance gmol

In G

Relative isotopic mass

The mass of an atom of an isotope compares with 1/12 the mass of an atom of carbon 12

Of an atom

Relative atomic mass

The weighted mean mass of an atom of an element compared with 1/12 of the mass of an atom of carbon 12

Weighted

Mole

Amount of substance containing as many particles as there are carbon atoms in exactly 12 g of carbon 12

Amount

Avogadro's constant

Number of particles per mole of a substance 6.02×10^23

Empirical formula

The Simplest whole number ratio of atoms of each element present in a compound

Ratio

Molecular formular

The actual number of atoms of each element in a molecule

Actual

Water of crystallisation

Water present in a compound giving the compound a crystalline appearance

Appearence

Water of crystallisation

Water present in a compound giving the compound a crystalline appearance

Appearence

Anhydrous

When all the water of crystallisation have been removed from a compound

Removed

Water of crystallisation

Water present in a compound giving the compound a crystalline appearance

Appearence

Anhydrous

When all the water of crystallisation have been removed from a compound

Removed

Hydrated

When water of crystallisation is present in a compound

When

Metallic bonding

Strong electrostatic attraction between metal cations (positive ions) and delocalised electrons (The giant metallic lattice structure)

Electrostatic

Ionic Bond

The electrostatic attraction between oppositely charged ions

Between

Covalent bond

Strong electrostatic attraction between a shared pair of electrons and the nuclei of the bonded atoms

Strong

Covalent bond

Strong electrostatic attraction between a shared pair of electrons and the nuclei of the bonded atoms

Strong

Dative co-ordinate bond

Strong electrostatic attraction between a shared pair of electrons and the nuclei of the bonding atoms, where one of the atoms supply is both of the electrons shared

Both

Covalent bond

Strong electrostatic attraction between a shared pair of electrons and the nuclei of the bonded atoms

Strong

Dative co-ordinate bond

Strong electrostatic attraction between a shared pair of electrons and the nuclei of the bonding atoms, where one of the atoms supply is both of the electrons shared

Both

Electronegativity

The ability of an atom to attract bonding electrons towards itself in a covalent bond

Bonding electrons

Electron pair repulsion theory

electron pairs repel each other as far apart as possible


• lone pairs of electrons repel more stronger than bonding pairs of electrons

Oxidation number

A measure of the number of electrons that an atom uses to bond atoms of another element

Uses

Oxidation

Loss of electrons and increase in oxidation number

Loss

Reduction

Gaining electrons and loss in oxidation number

Gain

Oxidising agent

Reagent that oxidises another species (Itself reduced)

Oxidising agent

Reagent that oxidises another species (Itself reduced)

Reducing agent

A Reagent that reduces another species (itself oxidised)

Redox

Reaction were both oxidation and reduction take place

Both

Periodicity

Repeating trends in the physical and chemical properties across different periods

Repeating trends

Displacement reaction

A reaction in which a more reactive element (halogen) displaces a less reactive element (halogen) from an aqueous solution of its halide ions

Disproportionation

Reaction in which the same element is oxidised and reduced


Enthalpy Change

Amount of heat released or absorbed Chemical reaction, carried out under constant pressure Kjmol-1


Enthalpy Change

Amount of heat released or absorbed Chemical reaction, carried out under constant pressure Kjmol-1

Exothermic reaction

Reaction in which heat energy is released into the surroundings ( H- )

Endothermic reaction

A reaction in which heat energy is absorbed from the surroundings

Average bond enthalpy

Average enthalpy change when one mole of gaseous bonds are broken by homolytic fission

Standard conditions

•25° C or 298K


• 1 atmosphere pressure or 100kPa


• 1.0dm^3 concentration

Standard states

Physical states under standard conditions

Standard states

Physical states under standard conditions

Standard enthalpy change of a reaction

The enthalpy change that accompanies a reaction in the molar quantities expressed in a chemical equation under standard conditions, all reactants and products being in their standard states.

Accompanies

Standard enthalpy change of neutralisation

Change that accompanies the neutralisation of an aqueous acid by an aqueous base form one mole of H2O under standard conditions

Standard enthalpy change of formation

The Enthalpy change when One mole of a compound is formed from its constituent elements in their standard states under standard conditions

Standard enthalpy change of combustion

The enthalpy change when one mole of a substance reacts completely with oxygen understand the conditions all products and reactants in their standard states

Hess' Law

The enthalpy change of reaction depends only on the initial and final states and is independent on the route taken

Activation energy

Minimum energy required to start a reaction by the breaking of bonds in the reactants

Activation energy

Minimum energy required to start a reaction by the breaking of bonds in the reactants

Catalyst

Increases the rate of reaction without being used up by the overall reaction

Hydrocarbon

Compounds containing only hydrogen and carbon

Homologous series

Series of organic compounds having the same functional group but with each successive member differing by CH2

Structural isomers

Compounds with the same molecular formula but different structural formula

Structural isomers

Compounds with the same molecular formula but different structural formula

Stereo isomerism

Compounds with the same structural formula but different arrangement of atoms in space

Structural isomers

Compounds with the same molecular formula but different structural formula

Stereo isomerism

Compounds with the same structural formula but different arrangement of atoms in space

E/Z isomerism

An example of stereoisomerism in which there is a restricted rotation around a C=C double bond, and each of the CC double bond have two different groups attached to it.

Cis/Trans Isomerism

A special case of ez isomerism in which there is a hydrogen atom on each carbon atom of the CC double bond

Radical

Species with an unpaired electron

Curly arrow

The movement of an electron pair showing either heterolytic fission or the formation of a covalent bond

Electophile

Electron pair acceptor

Nucleophile

Electron pair donor

Substitution reaction

Reaction where atom or group in a molecule is replaced by another atom or group

Addition reaction

Reaction where a group is added over the double bond of another atom or group

Elimination reaction

Reaction where an atom or group is removed from a molecule to make an unsaturated molecule

Oxidation reaction

Reaction where oxygen is added and/or hydrogen is removed from a molecule

General formula

CnH2n+2

Structural formula

CH3CH2CH3

Displayed formula

Showing all the bonds

Skeletal formula

Showing the bonds only and functional groups

Functional group

A group of atoms within a molecule responsible for the characteristic reactions of a compound

Aliphatic

Compound containing carbon and hydrogen join together in straight chains, branched chains or non-aromatic rings

Alicyclic

And aliphatic compound arranged and non-aromatic rings with or without sidechains

Aromatic


Chem

Compound containing a benzene ring

Condensation reaction

A reaction where a H2O molecule is lost when two molecules are joined together

Dehydration reaction

A reaction where a H2O molecule is removed from a saturated molecule to form an unsaturated molecule

Hydrolysis reaction

Chemical reaction involving water or an aqueous solution, which causes the breaking of a bond, splitting a reactant molecule into two products

Sigma Bond

Single end-on (axial) overlap of orbitals directly between bonding atoms, allowing free rotation of the bond

Pi Bond

Double sideways overlap of adjacent P orbitals above and below the plane of bonding atoms, with restricted rotation of the bond

Volatility

Ease with which a liquid turns into a gas

Precipitate

And insoluble solid formed when two solutions are mixed together

Distillation

Is the technique of heating a liquid to create vapour which is collected when cooled and condensed, separate from the original liquid

Heat under reflux

The continuous boiling and condensing of the liquid preventing loss of volatile liquids from a heated reaction vessel