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22 Cards in this Set
- Front
- Back
Properties of Water
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1. Water is polar
2. Hydrogen bonds |
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Why is water polar?
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- Oxygen is more electronegative than hydrogen
- Shared electrons spend more time around the oxygen (O slightly negative and H slightly positive) |
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Properties of Water's hydrogen bonds
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- Charge attraction (H+ attracted to O-)
- Each water molecule can form a maximum of 4 hydrogen bonds |
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Consequences of Water's Polarity
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A. Strong cohesive and adhesive properties
B. Moderates the temperature of the Earth C. Oceans and lakes don't freeze from the bottom-up D. Solvent properties |
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Cohesion
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- H-bonds cause water molecules to stick together
- Upward transport of water in plants |
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Adhesion
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H-bonds to vessel walls counteracts gravity
- Water has a high surface tension |
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Ways Water moderates the temperature of the Earth
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1. Water stabilizes air temperatures
2. Evaporative cooling |
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How does water stabilize air temperatures?
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- Absorbs heat from warmer air
- Releases heat to cooler air Due to high specific heat: water can absorb or release relatively large amounts of heat with only a slight change in its own temperature |
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Water resists changes in temperature (Yes/No)
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Yes.
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How does water have high specific heat?
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Hydrogen bonds:
- Heat must be absorbed to break hydrogen bonds - Heat is released when hydrogen bonds form |
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What is the result of water's high specific heat?
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A large body of water acts as a heat sink.
- it absorbs heat from the sun and releases it at night and during winter |
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What is evaporative cooling?
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Liquid -> Gas
vaporization or evaporization |
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Evaporative cooling is due to?
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High heat of vaporization (caused by H-bonds)
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Evaporative cooling moderates climate by:
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- absorbing heat in the tropics
- releasing heat when it rains |
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Evaporative cooling moderates the temperature of animals:
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Liquid evaporates at the skin
- most energetic molecules leave - lower kinetic molecules remain - surface is cooler |
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Why don't oceans and lakes freeze from the bottom-up?
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Water is less dense as a solid than as a liquid.
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Why is water less dense as a solid than as a liquid?
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Liquid water: H-bonds are continually breaking and forming (water molecules can get close together)
Ice: H-bonds no longer break and reform (water molecules are locked at a fixed distance) |
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Ice is about how much lighter than liquid water?
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10% less dense
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Ice floats in liquid water (Yes/No)
Conclusion? |
Yes. This prevents deep bodies of water from freezing bottom-up.
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Solvent properties of water (define)
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Water is a versatile solvent
- due to its polarity - forms hydrogen bonds with polar and charged covalent molecules (e.g. NaCl) Water surrounds individual ions, separates and shields them from one another |
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Hydrophilic (define)
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has an affinity for water
e.g. ionic and polar substances |
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Hydrophobic (define)
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has no affinity for water
e.g. non-ionic and nonpolar Thus, water cannot form H-bonds |