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14 Cards in this Set

  • Front
  • Back

State the meaning of the term electronegativity

The power of an atom or nucleus to withdraw or attractelectrons OR electron density OR a pair of electrons(towards itself)

State the type of bonding in lithium fluoride.Explain why a lot of energy is needed to melt a sample of solid lithium fluoride.

IonicStrong or many or lots of (electrostatic) attractions(between ions)

Explain why the boiling point of X is lower than that of its straight-chain isomer (X has many branches)

Because molecule is smaller / less polarisable / has lesssurface (area)/ is more spherical / molecules can’t get asclose to one another (to feel the vdW forces)

State the type of cracking that produces a high proportion of ethene and propene.Give the two conditions for this cracking process.

Thermal (cracking)High pressure AND high temperature

Give one reason why excess air is used in the Ostwald Process.

ensure completereaction or combustion

Explain why the AsCl4+ ion has a bond angle of 109.5º

There are 4 bonds or 4 pairs of electrons (around As)(Electron pairs / bonds) repel equally

In a mass spectrometer, the relative abundance of each isotope is proportional to thecurrent generated by that isotope at the detector. Explain how this current is generated.

Electron(s) transferred / flow (at the detector)(From detector / plate) to the (+) ion

State the meaning of the term structural isomers.

(Compounds with the) same molecular formulaBut different structural formula / different displayedformula/different structures / different skeletal formula

Identify a catalyst used in a catalytic converter

Pt / platinumORPd / palladiumORRh / rhodium

Explain, in terms of its structure and bonding, why nickel has a high melting point

Contains positive (metal) ions or protons or nuclei anddelocalised / mobile / free / sea of electronsStrong attraction between them or strong metallic bonds

Explain why nickel is ductile (can be stretched into wires).

Layers or ions can slide over one another

Fluorine and iodine are elements in Group 7 of the Periodic Table.


3 (a) Explain why iodine has a higher melting point than fluorine.

Iodine has more electrons and is bigger (atom or molecule) so bigger surface area and hence Stronger van der Waals forces between molecules

Name the type of bond formed when a molecule of BF3 reacts with an F– ion. Explainhow this bond is formed.


Type of bond:


Explanation:

Coordinate bond


pair of electrons/ both electrons (on Donated from and donated to the BF3

State the trend in first ionisation energies in Group 2 from beryllium to barium.Explain your answer in terms of a suitable model of atomic structure.


Trend:


Explanation:

Decreases, Atomic radius increases as as well as electron removed further from nucleus electron in higher energy level and more shells As group is descended so more shielding