Chapter 11 And 12

Front 1

Alkoxides (R-O(-)) from alcohols

Back 1

R-OH + base like K or NaH or NaH2 or grinard reagent

Front 2

Hydrobation

Back 2

Syn addition of H and OH

Anti markovnikov

CH3CH=CH2 + BH3/THF = CH3CH2-CH2-OH

Front 3

Oxymercuration

Back 3

Marovikov Hydration

Ch3CH=CH2 + Hg(OAC)2/H20 = Ch3CH(OH)-CH3

Front 4

Alkene + 1. OsO4 + pyridine 2. NaHSO3/H20

Back 4

Cis diols

Front 5

Cycloalkene + RCO3H (m-Chloroperoxy-benzoic acid)/Ch2Cl2

Back 5

Expoxide and then + H30 will make a trans diol cycloalkane

Front 6

Aldehyde + NaBH4 OR LiAlH4/H3O+

Back 6

Primary alcohol

Front 7

Ketone + NABH4 OR LIALH4/H30+

Back 7

Secondary alcohol

Front 8

ketone and aldehyde slide

Back 8

Front 9

Carboxylic acid or ester + LiAlH4/H30+

Back 9

Primary alcohols

But for ester 2 of them

Front 10

C=O + RMgX

Back 10

RC(OH)-R

Front 11

Gignard reaction don't add to what?

Back 11

Carboxylic acids

Front 12

R3C-OH + HCL

Back 12

SN1

R3-C-CL

Front 13

1 alcohol + SOCl2 or PBr3

Back 13

SN2

C-CH2-CL or C-CH2-Br

Front 14

2 alcohol with Socl2 or PBr3

Back 14

SN2

C2-CH-Cl or C2-CH-Br

C2 = 2 carbons

Front 15

Alkene + H20

Back 15

C=C -> HC-C-OH

Front 16

3° alcohols + H30

Back 16

Alkene (slide 16)

Front 17

Alcohols + POCl3/Pyridine

Back 17

Alkene

Front 18

1° Alcohols or 2° + PCC/CH2CL2

Back 18

1° = Aldehyde

2°= Ketone

Front 19

R-OH + Cro3/Base

Back 19

C=O

Front 20

Alcohol + N(CH2Ch3)3 + (Ch3)3Si-CL

(Protecting alcohols)

Back 20

R-O-(Ch3)3Si + NH(CH2Ch3)3 + Cl-

Front 21

R-O-(Ch3)3Si + Mg if R was Br

Back 21

MgR-O-(Ch3)3Si

Front 22

R-O-(Ch3)3Si R is Alcohol (C-OH)

Back 22

OH-CR-CR-OH + HO-(Ch3)3Si

Front 23

Alcohol + acid and alcohol

Back 23

Ether (slide 28)

Front 24

Alcohol + Base like NaH or Naoh and alkyl halide

Back 24

Ether (slide 29)

Front 25

Ether + H-X, H20

Back 25

Alcohol + R-X (slide 30)

primary over secondary

tertiary over secondary and primary

look at ** card at the end

Front 26

Alkene + MCPBA/ CH2CL2

Back 26

Epoxide

Front 27

Alkene + Cl2/H20

Back 27

Halohydrin RC(X)-C(OH)-R then with NaOH or other base/H20 -> epoxide

Front 28

Epoxide + H-X

Back 28

Trans RC(X)-C(OH)-R

Front 29

Epoxide + H3O or Br2

Back 29

Trans alcohol

Or

Trans diBromo

Front 30

Epoxide + H-X

Back 30

OH-CR-CR-X

Front 31

Epoxide + OH/H20 and then water

Back 31

Trans 1,2 diols

Front 32

Crown ethers

Back 32

X-crown-y

X= total number of atoms

Y= # of oxygen atoms

Front 33

Tosylate

Back 33

R-O-SO2-PH-Ch3

Front 34

Cl-SO2-PH-CH3 + Alcohols and pyridine

Back 34

Toyslate

Front 35

*****

Back 35

Front 36

**

Back 36