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13 Cards in this Set

  • Front
  • Back
What component of the body creates an environment that favors the corrosion of metallic implants?
presence of aqueous media containing ions
What local changes may occur around a device after implantation?
Actions of inflammatory cells:
1) Excretion of strong oxidizing agents (peroxides)
2) Lowering of pH
all of which affect degradation time
What material is subject to more degradation and why?
metal because of the chemical composition of physiologic fluids
what is degradation of metals referred to as?
Corrosion
How can corrosion of metals affect the body?
Leaching of ions from the metallic surface occurs which may have deleterious short or long term biological consequences
they can also induce hypersensitivity or allergic reactions
what is the voltage between the anode and the cathode dependent on?
temperature and concentration of metals
what does a more negative voltage difference indicate?
more favorable disintegration from electrochemical standpoint
The galvanic series was measured in what environment?
sea water, to mimic the ions in the body
What is galvanic corrosion?
corrosion when two metals are present in a corrosive environment, the more active metal will dissolve at an accelerated pace
What becomes the salt bridge for two metals in the body?
physiological fluids
What is one way to prevent corrosion
Having oxidation and reduction rates equal, such as passivation
What is a pourbaix diagram
for given metals depicts regions of corrosion and noncorrosion as a function of pH and voltage which is formed by the nernst equation
What occurs in between the dashed lines of the pourbaix diagram, and what happens outside of the pourbaix diagram?
inside: aqueous corrosion/passivation
outside: water breaks down, not the metals