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The Basicity Of Amines

-Lone pair of electrons on nitrogen atom can form a dative bond with a H+ ion


-Donates electrons and "accepts" proton


Amine are Neutralised by acids


Form Amine Salts

CH₃NH₂ + HCl→ CH₃NH₃+Cl-


Methylamine +Hydrochloric Acid








2CH₃CH₂NH₂ + H₂SO₄→ (CH₃CH₂NH₃+)₂SO₄²⁻


Ethylamine +Sulphuric Acid


Preparation of a Amine


-Heat Halogenoalkane with excess ammonia and ethanol solvent


(Forms NHBr) 1


-Excess of ammonia prevents hydrogen from further substituting to form 2° and 3° amines


Without excess of ammonia


HBr formed



Reduction of Nitrobenzene


Tin (Sn) and conc HCL (reducing agent)


Nitrobenzene + 6[H] → Phenylamine +2H₂O


Sn+HCl and then NaOH


Functional Group:


Amides

H₂N-C=O