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26 Cards in this Set

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What are the 3 gas laws?

Boyle's Law


Charles' Law


Pressure Law

What does Boyle's Law explain?

How the temperature and volume of a gas vary when the temperature remains constant

Isothermal


P is inversely proportional to V

How do pressure and volume vary for an isothermal reaction (Boyle's Law)?

The pressure for a fixed mass of gas is inversely proportional to its volume when kept at constant temperature

Explain Boyle's law

The pressure of a gas at constant temperature is increased if the volume is reduced because gas molecules travel less distance between impacts due to the reduced volume



There are more impacts per second so pressure is increased

What is a useful equation for Boyle's law?

P is the pressure acting on a gas of volume V

What does the pressure law explain?

How the temperature and pressure of a gas varies when the volume remains constant

P is proportional to T

Explain the Pressure law

For a fixed volume of gas increasing the temperature increases the kinetic energies of the particles



Due to the increased kinetic energies of the particles they hit the walls of their container more often causing the pressure to increase

How do pressure and temperature vary for an isochoric reaction (Pressure Law)?

The pressure for a fixed mass of gas is directly proportional to the absolute temperature of the gas for a fixed volume

What is a useful equation for the Pressure law?

How do volume and temperature vary for an isothermic reaction (Charles' Law)?

At constant pressure the volume of a fixed mass of an ideal gas is directly proportional to its absolute temperature

What does Charles's law explain?

How the volume and temperature of a gas vary when the pressure is constant

Isobaric

What is a useful equation for Charles' law?

Explain Charles's law

As temperature increases volume must increase as for constant pressure increase temperature = increased kinetic energy



So for the number of wall collisions per second (pressure) to remain constant the walls of the container need to move further apart

What is the equation used to describe the final pressure volume and temperature of a gas after changes have been applied to it?

What are the 7 assumptions made for an ideal gas?

There are a very large number of identical, small, hard spherical molecules



The molecules have negligible volume compared to the container



The molecules show random motion (ranges of speeds and directions) with distribution of velocities about a mean velocity



Newtons laws of motion can be applied to the molecules



Collisions are elastic and all motion is frictionless



The time spent between collisions is much larger than the time spent colliding



No intermolecular forces acting between molecules other than when they collide


What is absolute zero?

The temperature when all molecular motion ceases and the pressure of a gas drops to zero

What is the value of absolute zero in Kelvin and degrees Celsius?

0K


-273.15 °C

What is Avogadro's law?

Equal volumes of different gases at the same pressure and temperature will have the same number of particles

What is Avogadro's constant?

6.02x10^23 mol^-1

What equation links number of moles molecular mass and mass of substance?

n = M/Mr

What equation links number of moles number of particles and Avogadro's constant?

n = N/NA

How was the boltzmann constant calculated?

Molar gas constant/Avogadro's constant



R/NA

What is the value of the molar gas constant?

8.31 J K^-1 mol^-1

What is the value for the boltzmann constant?

1.38x10^-23 J K^-1

What are the two ideal gas equations?

pV = nRT


pV = NkT

How do you calculate the work done to move a gas?

Work Done = Force x Distance


p = Force/Area --> Force = Pressure x Area


Work Done = Pressure x Area x Volume -->


Work Done = Pressure x Change in Volume