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Phase Equilibria definition


Equilibrium definition


Phase

Phase equilibrium is the study of the equilibrium which exists between or within different states of matter, namely solid, liquid and gas.


Equilibrium is defined as a stage when the chemical potential of any component present in the system stays steady with time.


Phase is a region where the intermolecular interaction is spatially uniform.

Phase Equilibria

Phase equilibria is the application of the principles of thermodynamics to the study of equilibrium relationships within homogenous phase or between heterogenous phases.


key tool in exploring phase equilibria is a phase diagram which is used to show conditions (pressure, temperature, volume, etc.) at which thermodynamically distinct phases (such as solid, liquid or gaseous states) occur and coexist at equilibrium.

Phase diagram

used to understand the relationship between different phases and are usually represented as the change in the phase of a system as function of temperature, pressure, or composition of the components in a system. The system exists in a phase where the Gibbs free energy of the system is least.


Phase diagram is a graphical representation of the physical states of a substance under different conditions of temperature and pressure.


A typical phase diagram has pressure on the y-axis and temperature on the x-axis.


As we cross the lines or curves on the phase diagram, a phase change occurs