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49 Cards in this Set

  • Front
  • Back

Types of Energy

Mechanical - an object's motion or position (bowling ball).


Electromagnetic - Light energy (UV, gamma rays).


Electric - energy caused by the movement of electrons (through power lines).


Chemical - Energy available for release from chemical reactions (when match is struck).


Thermal - Heat energy.


Nuclear - Energy stored in the nucleus of an atom from fission or fusion (sun, stars).

Where do we get our current energy?

Oil, coal, natural gas, hydroelectric, and nuclear.

Largest oil reserves

Middle East

What sector uses the most energy?

Industrial

Energy demand is also influenced by:

World population development.

Sources of renewable energy:

Solar Thermal


Biomass


Geo Thermal


Hydroelectric


Wind

MCL

Maximum Contaminant Limit

MCLG

Maximum Contaminant Limit Goal

How much US wastewater is reused?

5-6%

Acute risks

Viruses, bacteria, parasites.

Chronic Risks

Metals and salts, inorganic and organic chemicals.

TSCA

Toxic Substance Control Act (ensure chemicals don't pose a risk to health).

EDSP

Endocrine Disruptor Screening Program

CCL

Contaminant Candidate List

UCMR

Unregulated Contaminant Monitoring Rule

Why coagulation?

When pollutants are in colloidal form, they cannot be separated unless by coagulation.


Benefits: removal of larger particles and the precipitation of soluble compounds.

Destabilization methods

Repression of double layer, entrapment of colloidal particles by sweeping floc., bridging of colloidal particles.

Characteristics of good coagulant?

Electric charge and size.

Florida Ocean Outfall Act

Prohibits construction or expansion of ocean outfalls.

Primary removal mechanisms for CECS

separation, biological and oxidation

Membrane processes

Microfiltration - particle removal(not salt)


Ultrafiltration - particle and pathogen removal(not salt)


Nanofiltration - softening


Reverse Osmosis - desalination

Coagulation VS. Flocculation

Coagulation: colloidal particles and fine solids are destabilized so they can begin to agglomerate if appropriate.


Flocculation: destabilized particles conglomerate into larger aggregated to separate from raw water.

Adsorption VS. Absorption

AD - Outside (Chemical and Physical)


AB - Inside

Colloids

Hydrophilic - proteins


Hydrophobic - clays and metal oxides

Water softening

precipitative softening

reverse osmosis





Brackish water

salty but less salty than seawater

Two major ways to desalinate

thermal and membrane - roughly boiling and reverse osmosis

Reverse VS. Forward Osmosis

Reverse - changing the natural order by applying pressure.


Forward - way things would naturally move.

Types of fouling

scaling - calcium carbonate


particulate (silt) - algae


biofouling (bacteria)


organic fouling

SWDA

Safe Water Drinking Act - 1974


Drinking water quality

CWA

Clean Water Act - 1972


discharge of wastewater

Nitrification VS. denitrification

Nitrification - ammonia to nitrate


denitrification - nitrate to nitrogen gas

basic components in a water treatment system


PRIMARY: screens, SECONDARY: activated sludge /clarifier, then tertiary: filtration, disinfection


Chemisorption
If the adsorbate attaches to the absorbent through a chemical reaction (example – covalent bonding).
Physisorption
Attaches through physical attraction (example – Van Der Waals forces).
Three Major Adsorbents
Activated Carbon – absorbs both larger organics and smaller synthetic organic compounds.


Synthetic Polymeric Adsorbents – does not absorb large molecular weight organics (good for removing smaller organic)



Zeolites – mainly for arsenic removal

Activated Carbon
It is cheap, made from coal, peat and coconuts, the two major types are: Powdered Activated Carbon (PAC) which removes taste and odor compounds in water, and Granular Activated Carbon (GAC) which removes trace compounds in water.
Carbonate Hardness
TEMPORARY – caused by the presence of dissolved bicarbonate minerals: calcium bicarbonate, calcium chloride.
Non–Carbonate Hardness
PERMANENT – present of calcium sulfate and/or magnesium sulfates in water, which don't precipitate out.
Double Layer Theory
If a colloidal particle is electrically charged it attracts ions and other colloidal particles of opposite sign.
Interaction Forces
Van Der Waals – always attractive.
Electrostatic – attractive or repulsive.
Short range, Nuclear, or Electronic – always repulsive.
Common Coagulants
Aluminum salts, ferric and ferrous salts, lime, cationic polymers, and anionic and non–ionic polymers.
Using Al or Fe Salts as Coagulants and Dosage
Depends on pH of water, alkalinity of water, and concentration of colloids.
Potable Water Reuse
Types: direct (from factory pipe to place) or indirect (through nature first) potable water reuse.
US Public Health Service
1914
US EPA
1970
90 contaminants – 52 are organic
SDWA Standards
Primary – recognize contaminants, determine MCLG, establish MCL.
Secondary – aesthetics: taste, color and odor, and cosmetics: skin and teeth discoloration
Desalination
separates dissolved minerals and impurities from seawater or salty water

Chick Watson Law

Between concentration of disinfectant and contact time.


100 parts/min = 100CL for 1 min or 10 CL for 10 min or 1 CL for 100 min.