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15 Cards in this Set

  • Front
  • Back

Energy conversion is required for these three types of work

Osmotic, chemical, mechanical

What is governed by thermodynamics

Whether a reaction will occur, what direction will it occur, what extent the reaction will occur

Energy

The capacity of a system to do work or exchange heat

Isolated system

Exchanges neither matter nor energy with its surroundings

Closed system

Exchanges only energy and not matter with its surroundings

Open system

Exchanges both energy and matter with its surroundings

1st law of thermodynamics

Conservation of energy

4 storage locations of energy within a molecule

Covalent bonds, non covalent interactions, levels of freedom in its structure, makeup of subatomic parts

Enthalpy

Heat content of the system

Heat of formation definition

The energy difference between a molecule and its individual unbonded atoms

Heat of formation is negative because

Energy is given off

Delta H is negative in

Exothermic reactions

Second law of thermodynamics(general)

Energy transferred between the system and its surroundings become unusable

Entropy

Quantitative measure of disorder

6 factors affecting entropy

Volume change, temperature change, molar mass, concentration gradient, chemical reactivity, molecular complexity