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14 Cards in this Set
- Front
- Back
1. Addition reactions of Alkenes.
(a). Addition of HCL, HBr, and HI. |
Markonikov regiochemistry occurs.
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1. Addition reactions of Alkenes.
(b). Additions of halogens Cl2 and Br2. |
Anti addition is observed through a halonium ion intermediate.
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1. Addition reactions of Alkenes.
(c). Halohydrin formation. |
Markonikov regiochemistry and anti stereochemistry occur.
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1. Addition reactions of Alkenes.
(d). Addition of water by oxymercuration-demercuration. |
Markonikov regiochemistry occurs.
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1. Addition reactions of Alkenes.
(e). Addition of water by hydroboration-oxidation. |
Non-Markonikov syn addition occurs.
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1. Addition reactions of Alkenes.
(f). Catalytic hydrogenation |
Syn addition occurs.
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1. Addition reactions of Alkenes.
(g). Epoxidation with a peroxyacid. |
Syn addition occurs.
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1. Addition reactions of Alkenes.
(h). Hydroxylation with OsO4. |
Syn addition occurs.
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1. Addition reactions of Alkenes.
(h). Hydroxylation with OsO4. (i). Addition of carbenes to yeild cyclopropanes. (1). Dichlorocarbene addition. |
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1. Addition reactions of Alkenes.
(h). Hydroxylation with OsO4. (i). Addition of carbenes to yeild cyclopropanes. (2). Simmons-Smith reaction. |
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2. Hydroxylation by acid-catalyzed epoxide hydrolysis.
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Anti stereochemistry occurs.
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3. Oxidative cleavage of alkenes.
(a). Reaction with ozone followed by zinc in acetic acid. |
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3. Oxidative cleavage of alkenes.
(b). Reaction with KMnO4 in acidic solution. |
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4. Cleavage of 1,2-diols.
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