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21 Cards in this Set
- Front
- Back
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Primary alcohol oxidizes to... |
Aldehydes |
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Secondary alcohol oxidizes to.. |
Ketone |
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Tertiary alcohol oxidizes to... |
They don’t. |
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Oxidize secondary alcohol into ketone |
Sodium dichromate and sulfuric acid (Na2Cr2O7 and H2SO4, H2O)
Or Jones |
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Oxidize primary alcohols into aldehyde.. |
PCC |
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Ozonolysis |
1.) O3 2.) DMS |
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Primary alcohol to carboxylic acid |
Na2Cr2O7 H2SO4, H2O |
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Naming priorityre |
Carboxylic acids -oic acid Aldehyde -al oxo- Ketone -one oxo- Alcohol -ol hydroxy- Amino -amine amino- Sulfhydryl -thiol Mercapto- |
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Reduction of ester |
DIBAL-H H2O |
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Hydro notation oxidation of alkynes |
R2BH H2O2, OH- |
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Ketone to Alkane (Clemmensen reduction) |
Zn/Hg Conc. HCl |
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Make alcohol from ketone |
1.) LAH 2.) H2O
Or
NaBH4, MeOH |
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Ketone with alcohol |
ACETAL REACTION!!!! |
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Acetal removal |
In water, acidic conditions |
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Primary amine attack |
DB on N |
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Secondary amine attack |
DB adjacent to N |
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Hydrazone |
DB N-NH2 |
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Hydrazone |
DB N-NH2 |
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Removal of hydrazone |
KOH/H2O |
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Ketone to alkane (Wolff-Kishner) |
[H+], H2N-NH2, (-H2O)
KOH: H2O 100-200°C |
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Ketone to alkane (Rainey nickel) |
BF3, S\_/S Rainey Nickel |
