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12 Cards in this Set

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Enthalpy of Formation

Enthalpy change when one mole of a compound is formed from its constituent elements (with all substances in their standard states).



Exothermic

Bond dissociation enthalpy

Enthalpy change when one mole of a covalent bond is broken in the gaseous state (with all substances in their standard states)



Endothermic

Lattice enthalpy of formation

Enthalpy change when one mole of a solid ionic compound is formed from its constituent ions in the gas phase.



Exothermic

lattice = giant ionic lattice

Lattice enthalpy of dissociation

Enthalpy change when one mole of a solid ionic compound is broken up into its constituent ions in the gas phase.



Endothermic

lattice = giant ionic lattice

Ionisation enthalpy (1st)

The enthalpy change when one mole of gaseous atoms loses one electron per atom to produce gaseous 1+ ions.

Ionisation enthalpy (2nd)

When one mole of gaseous 2+ ions is produced from one mole of 1+ ions



Endothermic

Enthalpy of combustion

Enthalpy change when one mole of a substance undergoes complete combustion in oxygen (with all substances in their standard states)



Exothermic

Enthalpy of atomisation/vaporisaton

Enthalpy change when one mole of gaseous atoms is produced from an element in its normal state.



Endothermic

Hydration enthalpy

Enthalpy change when one mole of gaseous ions become hydrated (dissolved in water)



Exothermic

Enthalpy of solution

Enthalpy change when one mole of an ionic solid dissolves in solvent. If the solvent is water, the ionic lattice finishes up surrounded with water molecules as aqueous ions.



Reactions very between exothermic/endothermic

Electron affinity (1st)

The enthalpy change when one mole of gaseous atoms gains one electron per atom to produce gaseous 1- ions.



Exothermic

Reverse ionisaton enthalpy

Electron affinity (2nd)

The enthalpy chnave when one mole of gaseous 1- ions gains one electron per ion to produce gaseous 2- ions.



Endothermic

Reverse ionisation enthalpy