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15 Cards in this Set

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What type of reaction gives a negative enthalpy change and what type gives a positive enthalpy change?

Negative- exothermic


Positive-endothermic

What is activation energy?

The minimum energy required for a reaction to take place

Where is activation energy shown on the enthalpy profile diagrams?

From the initial enthalpy to the top of the curve

What are the standard conditions?

Pressure- 100kPa


Temperature- 25°C (298 K)


Concentration- 1 mol dm-3

What is the standard state?

The physical state of a substance under standard conditions

What is the definition of the standard enthalpy change of reaction?

The enthalpy change that accompanies a reaction in the molar quantities shown in a chemical equation under standard conditions, with all reactants and products in their standard states

The definition of the standard enthalpy change of formation?

The enthalpy change that takes place when one mole of a compound is formed from its elements under standard conditions, with all reactants and products in their standard states

The definition of the standard enthalpy change of combustion

The enthalpy change that takes place when one mole of a substance reacts completely with oxygen under standard conditions, with all reactants and products in their standard states.

Definition of the standard enthalpy change of neutralisation

The energy change that accompanies the reaction of an acid by a base to form one mole of H2O under standard conditions, with all reactants and products in their standard states

Equation of calculating an energy change

q=mc T


q- heat energy


m- mass of surroundings


c - specific heat capacity


T- temperature change of surroundings

Definition of average bond enthalpy

Average enthalpy when one mole of bonds is broken

Definition of average bond enthalpy

Average enthalpy when one mole of bonds is broken

Does a positive bond enthalpy mean a bond is being broken or being formed?

Broken


Negative bond enthalpy is when a bond is being formed

Definition of Le Chatiliers principle

Equilibrium shifts to minimise any change

Exam tip: when calculating enthalpy change don’t but everything into the calculator at once

Cheers