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13 Cards in this Set

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Fractional Distillation:

Process of separating crude oil by heating it, and collecting the fractions that boil over different ranges of temperatures

Fraction:

a mixture of hydrocarbons collected over a particular range of boiling points during the fractional distillation of crude oil

The process of fractional distillation is done in a...

Fractionating tower

The steps of fractional distillation:


Step 1:

crude oil is heated in a furnace

The steps of fractional distillation:


Step 2:

A mixture of liquid and vapor passes into a fractionating tower that is cooler at the top than the bottom

The steps of fractional distillation:


Step 3:

Vapors pass up the tower until they condense to a liquid, when cooled to a temperature lower than their boiling point

The steps of fractional distillation:


Step 4:

Fractions are piped off

Fractionating tower and temperature:

Cooler at the TOP than the bottom


Temperature DECREASES going up the tower

Shorter hydrocarbon chains condense nearer...

the TOP of the fractionating tower where it's cooler as they have LOWER BPts

Vapors condense when...

they are cooled to a temperature LOWER than their boiling points

Bitumen

thick residue that collects at the base of the tower


(a.k.a tar)

Going ^UP^ the fractionating tower:

-Temperature decreases


-Viscosity (thickness) decreases

Viscosity decreases because:

Hydrocarbon chain-lengths decrease so fewer vdW forces so hydrocarbons get further apart