Reading...
Play button
Play button
Use LEFT and RIGHT arrow keys to navigate between flashcards;
Use UP and DOWN arrow keys to flip the card;
H to show hint;
A reads text to speech;
61 Cards in this Set
- Front
- Back
|
A reaction has ___ when two new bonds are on opposite sides
|
Anti-stereoselectivity
|
|
|
A reaction has ___ when the more electronegative atom ends up on the more substituted carbon
|
Regioselectivity
or Markovnikov |
|
|
A reaction has ___ when two new bonds are on the same side
|
Syn-stereoselectivity
|
|
|
A reaction has ___ when the more electronegative atom ends up on the less substituted carbon
|
Anti-regioselectivity
or Anti-Markovnikov |
|
|
Alkane pKa
|
50
|
|
|
Alkene pKa
|
45
|
|
|
Amine pKa
|
40
|
|
|
Hydrogen pKa
|
35
|
|
|
Alkyne pKa
|
25
|
|
|
Alcohol pKa
|
17-18
|
|
|
Water pKa
|
16
|
|
|
Bicarbonate pKa
|
11
|
|
|
Ammonium pKa
|
10
|
|
|
Carbonic pKa
|
6
|
|
|
Carboxylic pKa
|
5
|
|
|
Oxonium 1/2 H pKa
|
-2
|
|
|
Oxonium 3 H pKa
|
-3
|
|
|
HBr pKa
|
-5
|
|
|
HCl pKa
|
-5
|
|
|
HI pKa
|
-5
|
|
|
H2SO4 pKa
|
-5
|
|
|
HOTs pKa
|
-5
|
|
|
HNO3 pKa
|
-5
|
|
|
HClO4 pKa
|
-5
|
|
|
Oxonium 1/2 H pKa
|
-2
|
|
|
Oxonium 3 H pKa
|
-3
|
|
|
HBr pKa
|
-5
|
|
|
HCl pKa
|
-5
|
|
|
HI pKa
|
-5
|
|
|
H2SO4 pKa
|
-5
|
|
|
HOTs pKa
|
-5
|
|
|
HNO3 pKa
|
-5
|
|
|
HClO4 pKa
|
-5
|
|
|
F- Nomenclature
|
Fluoro
|
|
|
Cl- Nomenclature
|
Chloro
|
|
|
Br- Nomenclature
|
Bromo
|
|
|
I- Nomenclature
|
Iodo
|
|
|
Nomenclature:
Methyl group on second to last carbon of a branch |
iso-number of TOTAL carbons
|
|
|
Nomenclature:
Methyl group on first carbon of a branch |
sec-Number of TOTAL carbons
|
|
|
Nomenclature:
3* carbon as first of a branch |
tert-Number of TOTAL carbons
|
|
|
Nomenclature:
3* carbon as second of a branch |
neo-Number of TOTAL carbons
|
|
|
Nomenclature:
Suffix -ol |
Alcohol
|
|
|
Nomenclature:
Suffix -al |
Aldehyde
|
|
|
Nomenclature:
Suffix -one |
Ketone
|
|
|
Nomenclature:
Suffix -amine |
Amine
|
|
|
Nomenclature:
Suffix -amide |
Amide
|
|
|
Nomenclature:
Suffix -oic acid |
Carboxylic Acid
|
|
|
Nomenclature:
Suffix -oate |
Esters
|
|
|
Nomenclature:
Suffix -ether |
Ether
|
|
|
Nomenclature:
Infix -an- |
Alkane
|
|
|
Nomenclature:
Infix -enC- |
Alkene
|
|
|
Nomenclature:
Infix -yn- |
Alkyne
|
|
|
Nomenclature:
Carbons not numbered in a chain end in |
-yl
|
|
|
Functional Group Carbonyl:
RCHO R=C or H |
Aldehyde
|
|
|
Functional Group Carbonyl:
RCOR' R,R"=C |
Ketone
|
|
|
Functional Group Carbonyl:
RCOOH/RCO2H R=C or H |
Carboxyllic Acids
|
|
|
Functional Group Carbonyl:
RCO2R' R=C or H, R'=C |
Ester
|
|
|
Functional Group:
ROH R=C |
Alcohol
|
|
|
Functional Group:
ROR' R, R'=C |
Ether
|
|
|
Functional Group:
RNR'R" R=C R',R"=C or H |
Amine
|
|
|
Functional Group Carbonyl:
RCONR'R" R,R',R"=C or H |
Amide
|
