O. Chem - Ch. 16

Front 1

What is the IUPAC name for the following compound?

Back 1

3-methylpentanoic acid

Front 2

What is the IUPAC name for the following compound?

Back 2

benzyl acetate

Front 3

Which of the following compounds is N,N-dimethylbenzamide?

Back 3

Front 4

What is the hybridization and geometry of the carbonyl carbon in carboxylic acids and their derivatives?

Back 4

sp2, trigonal planar

Front 5

In which of the following compounds does the carbonyl stretch in the IR spectrum occur at the lowest wavenumber?

Back 5

pentanamide

Front 6

Which reaction coordinate diagram best represents the reaction that occurs when NaNH2 reacts with CH3COCl to form acetamide?

Back 6

Front 7

Which of the following compounds is most reactive toward nucleophilic acyl substitution?

Back 7

Front 8

Which of the following compounds is the least reactive toward nucleophilic acyl substitution?

Back 8

Front 9

Which of the following is the best method for preparing

Back 9

Front 10

Which of the following compounds would yield acetic acid when hydrolyzed under heat?

Back 10

all the above

Front 11

Which of the following is the best method for preparing aspirin,

Back 11

Front 12

Which of the following is (are) formed in the reaction between ethyl butanoate and ethyl amine?

Back 12

both A and C

Front 13

Which of the following is one of the steps in the mechanism of the following reaction?

Back 13

Front 14

Which of the following intermediates is present in the acid-catalyzed hydrolysis of t-butylacetate but not in the acid-catalyzed hydrolysis of methyl acetate?

Back 14

a carbocation

Front 15

What is the major organic product of the following reaction?

Back 15

Front 16

Which of the following conditions will drive the equilibrium of the Fischer esterification towards ester formation?

Back 16

both B and D

Front 17

Predict the major organic product of the reaction between N-methylbenzamide and sodium propanoate.

Back 17

no reaction

Front 18

What is the major organic product obtained from the following sequence of reactions?

Back 18

Front 19

What is the major product of the following reaction?

Back 19

Front 20

Give the product of the reaction.

Back 20

Front 21

Give the product of the reaction.

Back 21

Front 22

Give the product of the reaction.

Back 22