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58 Cards in this Set

  • Front
  • Back
Metals
-arranged in very orderly manner
-relatively dense
-stiff, strong, ductile, resistant to fracture
-good conductors of heat, electricity
Ceramics
-compounds between metallic and nonmetallic elements
-most frequently oxides, nitrides, and carbides
-relatively stiff and strong
-extremely brittle, highly susceptible to failure
-insulative to heat and electricity
Polymers
-low densities
-not stiff and strong
-extremely ductile and pliable
-tendency to soften/decompose at modest temps
Composites
-composed of two or more individual materials
-naturally occurring also: wood, bone
-
Bohr Atomic Model
-electrons assumed to revolve around atomic nucleus in discrete orbitals
Quantum-Mechanical Principle
-energies of electrons are quantized (only allowed to have specific values of energy)
-electrons have energy levels or states
Electropositive Elements
-elements capable of giving up their few valence electrons to become positive ions
-farther left and to the bottom of periodic table
Electronegative Elements
-elements on right-hand side of table
-readily accept electrons to form negatively-charged ions
Ionic Bonding
-always found in elements composed of both metallic and non-metallic elements
-metallic elements give up electrons to nonmetallic atoms
-all elements become ions
-coulombic bonding force
-non-directional
-high bonding energy
-materials w/ this bond tend to be hard, brittle, electrically, and thermally insulative
Nondirectional Bond
-magnitude of the bond is equal in all directions
Covalent Bonding
-sharing of electrons between adjacent atoms
-directional
Directional Bond
-bond only exists between specific atoms and only in the direction between one atom and another that participates in electron sharing
Metallic Bonding
-nondirectional
-free electrons: explains conductivity of metals
Crystalline Material
-atoms are situated in repeating or periodic array over large atomic distances
-"long range order"
Crystal Structure
-the manner in which atoms, ions, or molecules are spatially arranged
Unit Cell
-small repeat entities
-basic structural unit or building block of a crystal structure
-defines crystal structure
Face-Centered Cubic Crystal Structure
-atoms located at each of the corners and the centers of the cube faces
-total of four atoms in each cell
-coordination number = 12
-APF = .74
Body-Centered Cubic Crystal Structure
-atoms located at all 8 corners and a single atom at the cube center
-total of 2 atoms in each cell
-coordination number = 8
-APF = .68
Hexagonal Close-Packed Crystal Structure
-coordination number = 12
-APF = .74
Atomic Packing Factor
-(volume of atoms in unit cell)/(total unit cell volume)
Single Crystal
-when the periodic and repeated arrangement of atoms is perfect or extends throughout the entirety of the specimen w/out interruption
Grains
-small crystals
Anisotropy
-when the properties (ie, conductivity) depends on the orientation of the crystal and the direction
Isotropic
-measured properties are independent of the direction of the measurement
Vacancy
-point defect
-a normally occupied lattice site where the atom is missing
-number increases w/ temperature
Self-Interstitial
-an atom from the crystal is crowded into a small void space that under ordinary circumstances is not occupied
-introduces relatively large distortions in metals so is not highly probably in metals
Alloys
-metals in which impurity atoms have been added intentionally to impart specific characteristics to the material
-impurities count as point defects
Substitutional Solid Solutions
-solute or impurity atoms replace the host atoms
-likely if atomic size is comparable
-if crystal structure is the same
-if electronegativity is similar
-if valences are similar
Interstitial Solid Solution
-impurity atoms fill the voids among the host atoms
-unlikely if high packing factor
-atomic diameter needs to be substantially smaller than that of the host atoms
Edge Dislocation
-an extra portion of a plane of atoms, or half-plane, the edge of which terminates w/in the crystal
-linear defect, centers on the line that is defined along the end of the extra half-plane of atoms
Dislocation Line
-line running along the extra half-plane of atoms in an edge dislocations
-atoms above are squeezed together, below are pulled apart
Screw Dislocation
-dislocation occurs in twisting fashion
Interdiffusion/Impurity Diffusion
-process by which atoms of one metal diffuse into another
-can be observed by changes in composition and/or characteristics (ie, with an alloy)
Self-Diffusion
-occurs in pure metals
-all atoms exchanging positions are of the same type
-can't be observed by changes in composition and/or characteristics
Vacancy Diffusion
-the interchange of an atom from a normal lattice position to an adjacent empty lattice site
-necessitates the presence of vacancies
Interstitial Diffusion
-involves atoms that migrate from an interstitial position to a neighboring empty one
-typical w/ smaller atoms (ie, hydrogen, oxygen, etc)
-typically more rapid b/c atoms are smaller and therefore more mobile, also b/c probability of movement is more likely than for vacancies
Diffusion Flux
-the rate of mass transfer
-J
Fick's First Law
J = -D (dC/dx)

-direction of diffusion is down the concentration gradient (from high to low concentration)
-true for steady-state diffusion
Elastic Deformation
-deformation in which strain and stress are proportional
-nonpermanent--when load is removed, specimen returns to original shape
Plastic Deformation
-permanent, nonrecoverable deformation
-corresponds to the breaking of bonds and then re-forming of new bonds
-accomplished through slip (movement of dislocations)
Yield Strength
-stress value where plastic deformation begins to occur
Tensile Strength
-maximum stress on the engineering stress-strain curve
Ductility
-measure of the degree of plastic deformation that has been sustained at fracture
-percent elongation
-indicates the degree to which a structure will deform plastically b/f fracture
Resilience
-capacity of a material to absorb energy when it is deformed elastically and then, upon unloading, to have this energy recovered
-area under the elastic portion of the curve
Toughness
-ability of a material to absorb energy and plastically deform before fracturing
-total area under the curve
Hardness
-measure of a material's resistance to localized plastic deformation (indent or scratch)
Slip
-the process by which plastic deformation is produced by dislocation motion
Slip System
-the combination of the preferred plane and preferred direction along which dislocation motion occurs
-plane will have the most dense atomic packing
-several may exist for a particular structure
-more = more ductile material
Strengthening Techniques
-rely on the principle that restricting or hindering dislocation motion renders a material harder and stronger
Strengthening by Grain Size Reduction
-smaller grain size = less movement of dislocations
-much harder for dislocations to travel across grain boundaries
Solid-Solution Strengthening
-strengthening and hardening metals by alloying them with impurity atoms
-increases tensile and yield strengths b/c alloys typically less soft than pure metals
-works by imposing lattice strains on surrounding host atoms, and prevents dislocations from moving
Strain Hardening/Cold Working
-process by which ductile metal becomes harder and stronger as it is plastically deformed
-defined as percent change in area
-will lose ductility, but will strengthen and harden
Recrystallization
-formation of a new set of strain-free and equiaxed grains
-restores mechanical properties that were changed during cold-working --> becomes more ductile, less strong
Ductile Fracture
-substantial plastic deformation w/ high energy absorption b/f failure
-process proceeds slowly as crack grows
-necking b/f failure; cup-and-cone fracture
Brittle Fracture
-little or no plastic deformation b/f failure
-cracks spread extremely rapidly
-no necking; crack is perpendicular to direction of applied stress
Transgranular
-fracture crack that goes through grain boundaries
-typical w/ brittle fractures
Intergranular
-fracture crack that goes along grain boundaries
Fatigue
-form of failure that occurs in structures subjected to dynamic and fluctuating stresses
-failure can occur at a lower stress level than tensile or yield stress
-usually brittle-like, even in ductile metals