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15 Cards in this Set

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Thermodynamic product

More stable


Requires higher energy


Produced slow

Opp of kinetic

Kinetic product

Less stable


Formed rapidly


Lower required energy

Opp of thermo

Thermodynamics

The study of energy and its relationship to macroscopic properties of chemical systems.

What is systems

The section of universe under study

What is surroundings

The remainder of the universe outside of the system

Extensive properties

Proportional to the size of the system

Intensive properties

Independent of the size of the system

Work equation

w=-PΔV

First law of thermodynamics

ΔE=q+w

The reaction quotient

Q=prod.^coeff/react.^coeff

The average kinetic energy of a single molecule

K.E.avg= 3/2 kT

Gibbs free energy

ΔG=ΔH-TΔS


Or


ΔG=ΔG initial+RT ln(Q)

Temperature for absolute zero

-273*C

Rate

Rate f= kf[A]^α[B]^β

What is kf

The rate constant for the forward reaction