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236 Cards in this Set
- Front
- Back
Chemistry
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study of science that deals with matter
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matter
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has mass and takes up space
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chemical change
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AKA chemical reaction
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Chemical properties
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the chemical reaction a substance overgoes
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physical properties
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properties that do not involve chemical reactions
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scientific method
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tool, testing theories
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fact
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statement based on direct experience
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hypothesis
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statement proposed to explain facts and relationships
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theory
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the formulation of apparent relationships among certain observed phenomenon
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serendipity
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chance observations leading to discoveries
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significant figures
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see Appendix II
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Length
5280 ft |
one mile
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Length
1760 yds |
one mile
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Length
3 ft |
1 yd
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Length
12 " |
1 ft
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length
1 KM |
1000 M
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1 cm
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.01 M
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Metric prefixes
giga G |
10e9, 1 billion
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Metric prefixes
Mega M |
10e6, 1 million
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Metric prefixes
Kilo K |
10e3, 1000
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Metric prefixes
deci d |
10e-1, .1 or 1/10
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Metric prefixes
centi c |
10e-2, .01 or 1/100
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Metric prefixes
milli m |
10e-3, 001 1/1000
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Metric prefixes
micro |
10e-6, .000001 1/1 million
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Metric prefixes
nano, n |
10e-9, .000000001 1/1 billion
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Conversion factors
Length 1 in = |
2.54 cm
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Conversion factors
Length 1 meter |
39.37 in
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Conversion factors
Length 1 mile |
1,609 km
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Conversion factors
Mass 1 oz |
28.35 g
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Conversion factors
Mass 1 lb |
453.6 g
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Conversion factors
mass 1 kg |
2.206 lb
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Conversion factors
mass 1 g |
15.43 grains
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Conversion factors
Volume 1 qt |
0.946 L
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Conversion factors
Volume 1 gal |
3.785 L
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Conversion factors
Volume 1 L |
33.81 fl oz
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Conversion factors
Volume 1 fl oz |
29.57 ml
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Conversion factors
Volume 1 L |
1.057 quart
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1 ml
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.001 L
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100 ml
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1 L
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1 ml
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1 cc
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1000 cc
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1 L
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1 kg
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1000 g
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1 mg
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.001 g
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Temp
F |
9/5 degrees C + 32
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Temp
C |
5/9 (degrees F -32)
ex: 5/9 (98.6-32) = 5/9 (66.6)= 37.0 degrees C |
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Factor Label Method
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when multiplying/dividing numbers we also multiply/divide units
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denisity
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d = m/v
ex: 61.5 g/73.2 ml = .84 g/ml |
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specific gravity
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dimensionless - defined as conparison of the denisty of a substance with the density of H20
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energy
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capacity to do work
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kinetic energy
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energy of motion; any moving object
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potential energy
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stored energy
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Law of Conservation of energy
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energy can't be created or destroyed
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Heat
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form of energy (temperature is not); measured in calories
1 Kilocalorie = 1000 cal = 1 Kcal |
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1 cal =
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4.184 J
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specific heat
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amount of heat necessary to raise 1 g of any substance by 1 degree C
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element
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substance consisting of identical atoms; 116 known, 88 occur in nature
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compound
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pure substance made up of 2 or more elements in a fixed ratio by mass; 20 M known compounds
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mixture
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combination of 2 or more pure substances
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atoms
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make up all matter
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molecule
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combination of 2 or more atoms that act as a single unit
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Law of Conservation of Mass
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any compound is always made up of elements in the same proportion by mass
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monatomic elements
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single atoms not connected to each other
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diatomic elements
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H2, N2, F2, CL2, BR2, I2
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polyatomic elements
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diamonds; S8
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Proton
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subatomic particle with charge of +1 and a mass of approximately 1 amu, found in neucleus
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amu
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1 amu = 6.605 x 1-e-24 g; 1/2 the mass of a carbon atom containing 6 protons and 6 neutrons
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electron
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subatomic particle with charge of -1 and mass of approximately .0005 amu
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neutron
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subatomic particle with mass of approximately 1 amu and charge of 0; found in neucleus
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mass number
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number of protons and neutrons in the nucleus of an atom
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atomic number
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number of protons in the nucleus of an atom
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isotopes
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same number of protons but different numbers of neutrons; differ in radioactivity properties
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atomic weight
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weighted average of the masses (in amu) of its isotopes found on earth
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properties of metals
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solid (except mercury)
shiny conduct electricity malleable |
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alloys
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solutions of 1 or more metals dissolved in another metal
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non-metals
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don't conduct electricity
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mettaloids
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boron, silicon, germanium, arsenic, antimony and tellurium
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halogens
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melting/boiling points increase as we go down the column
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alkali
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group 1A; can be cut with a knife
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noble gases
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group 8A
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ground state electron configuration
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electron configuration of the lowest energy state of an atom
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Distribution of electrons in Shells
Shell 4 |
Shell can hold 32 electrons, subshell s
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Distribution of electrons in Shells
shell 3 |
can hold 18 electrons, subshell p
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Distribution of electrons in Shells
shell 2 |
can hold 8 electrons, subshell d
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Distribution of electrons in Shells
shell 1 |
can hold 2 electrons, subshell f
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electron configuration
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description of the orbitals of an atom or ion occupied by electrons
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valence electron
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an electron in the outermost occupied (valence) shell of an atom
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valence shell
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the outermost occupied shell of an atom
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Lewis Dot Structure
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the symbol of the element surrounded by a number of dots equal to the number of electrons in their outer shell
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He and Ne - (noble gases)
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have filled valence shells
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Electrons in Periodic Table
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elements in same column have the same configuration of electrons in their outer shell
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2 kinds of chemical bonds
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ionic and covalent
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octet rule
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groups 1A - 7A - gains/loses or shares electrons to have 8 in the valence shell in chemical reaction - doesn't apply to 1B - 7B
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anion
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negatively charged ion
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cation
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positively charged ion
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monatonic cations:
Cu+ |
Cuprous ion; Copper (I) ion
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monatonic cations:
Cu2+ |
Cupric ion; copper (II) ion
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monatonic cations:
Fe 2+ |
Ferrous ion; Iron (II) ion
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monatonic cations:
Fe 3+ |
Ferric ion; Iron (III) ion
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monatonic cations:
Hg+ |
Mercuric ion; Mercuey (II) ion
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monatonic cations:
Sn2+ |
Stannic ion; Tin (ii) ion
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Monatomic anions:
F- |
fluoride
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Monatomic anions:
Cl- |
Chloride
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Monatomic anions:
Br- |
Bromide
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Monatomic anions:
I- |
Iodide
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Monatomic anions:
O2- |
Oxide
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Monatomic anions:
S 2- |
Sulfide
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Polyatomic ions (Common):
NH+ |
ammonium
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Polyatomic ions (Common):OH4-
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Hydroxide
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Polyatomic ions (Common):NO2
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Nitrite
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Polyatomic ions (Common):N03 2-
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Nitrate
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Polyatomic ions (Common):
CH3 Coo- |
acetate
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Polyatomic ions (Common):
CN- |
cyanide
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Polyatomic ions (Common):MnO4-
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Permanganate
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Polyatomic ions (Common):CrO4 -2
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chromate
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Polyatomic ions (Common):
CO3 2- |
carbonate
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Polyatomic ions (Common):
HCO 3 - |
hydrogen carbonate
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Polyatomic ions (Common):
SO3 2- |
sulfite
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Polyatomic ions (Common):
HSO 3 - |
Hydrogen sulfite
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Polyatomic ions (Common):
SO4 2- |
Sulfate
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Polyatomic ions (Common):
HSO 4- |
hydrogen sulfate
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Polyatomic ions (Common):
PO4 2- |
phosphate
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Polyatomic ions (Common):
HPO4 2- |
hydrogen phosphate
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Polyatomic ions (Common):
H2 PO4 - |
dihydrogen phosphate
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ionic bond
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results from attraction between cation and anion
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covalent bond
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results from attraction between 2 atoms that share on or more pairs of electrons
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How to tell if ionic or covalent bond?
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ionic - usually forms between metal and non metal
covalent - usually forms between nonmetal/metalloid and nonmetal combine; compare electronegativity |
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electronegativity
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measure of an atom's attraction for the electrons it shares in a chemical bond with another atom
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How does ionic bond form?
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forms by transfer of 1 or mroe valence shell electrons from an atom of lower electr4onegativity to valence shell of an atom of higher electronegativity; more likely to occur if difference in electronegativity between 2 atoms is 1.9 or greater' covalent <1.9
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ionic compound
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formed by combination of + and - ions
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Predicting formulas of ionic compounds
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sum of ions and sum of + charges = sum of negative charges; subscripts represent ratio of the ions
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Naming Ionic compounds
binary compound - |
contains only 2 elements
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Naming Ionic compounds
binary ionic compound |
consists of name of metal (+ ion - cation) was formed, followed by name of anion (- ion; ignor subscripts in binary ionic compound naming
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How does covalent bond form?
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forms when electron bonds are shared between 2 atoms whose difference in electronegativity is < 1.9 (2 nonmetals or between nonmetal & metalloid)
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single bond
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sharing a pari of electrons (represented by a single line ex: H-H
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Chemical Bond Classification:
<.5 |
Non-polar covalent - 2 non metals or a metal and a nonmetal
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Chemical Bond Classification:
0.5 to 1.9 |
polar covalent; 2 non-metals or nonmetal & metalloid
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Chemical Bond Classification:
>1.9 |
Ionic; a metal and a nonmetal
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bonding electrons
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valence elctrons involved in forming a covalent bond (shared electrons)
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non-bonding electrons
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valence elctrons not involved in forming covalent bonds (unshared electrons)
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Lewis structure
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formula for a molecule or ion showing all pairs of bonding electrons as single, double or triple bonds and all nonbonded electtrons as pairs of Lewis dots
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Structural formula
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formula showing how atoms in a molecule or ion were bonded to each other; similar to Leis structure expect shows only bonding pairs of electrons
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naming binary covalent compounds
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2 element compound with all covalent bonds:
1) name the less electronegative element (1st in formula) 2) name the more elctronegative element and add ide to the stem name 3) use di, tri, tetra to show number of atoms of each element |
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How to predict bond angles (covalent molecules)
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use VSEPR; atoms spread out so eacfh is as far as possible from the others
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All H-C-H bond angles are
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109.5
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Methane bond angle
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tetrahedral
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water bond angle
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bent
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ammonia bond angle
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pyramidal
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ammonia molecule
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pyramidal
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formaldehyde & ethylene are
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120 degrees - trigonal planar
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carbon dioxide & acetylene
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linear and 180 degrees
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chemical reaction
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chemical change; reactants converted into products
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formula weight (FW)
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sum of atomic weights in amu of all atoms in compound's formula
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molecular weight
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strictly correct only when used for covalent compounds
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mole
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amount of substance that contains as many atoms, molecules or ions as there are atoms in exactly 12 g of Carbon -12
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Avogadro's number
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6.02 x 10e23 formula units per mole
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molar mass
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FW of substance expressed in grams
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combustion
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burning in air
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chemical equation
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a representation using chemical formulas of the process that occurs when reactants are convered to products
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balancing chemical equations
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1 - start with C or H
2 - balance free elements last 3 - change only coefficients in balancing equation |
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actual yield
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mass of product formed in chemical reaction
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theoretical yield
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mass of product that should form in a chemical reaction according to stoichimetry of the balanced equation
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percent yield
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actual yield divided by theoretical yield X 100
% yield = actual yield/theoretical yield X 100 |
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dissociation -
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dissolved in H2) and the + and - ions become separated by H20 molecules
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aqueous solution
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solution in which the solvent is H20
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spectator ion
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ion that appears unchanged on both sides of a chemical equation
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net ionic equation
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chemical equation that does not contain spectator ions (show only ions that react)
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ions react only when
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1 - 2 ions form a solid in soluble H20 (most common)
2 - 2 ions form a gas that escapes from the reaction mixture as bubbles 3 - one of the ions can oxidize another 4 - an acid neutralizes a base |
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most chlorides (Cl-) and sulfates (SO4 2-) are soluble in H20 (see back for exceptions)
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silver chloride (AgCl), lead (II) chloride (PbCl2)mercury (I) chloride (Hg2Cl2), barium sulfate (BaSO4) and lead sulfate (PbSO4) - NOT SOLUBLE IN H20
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Most carbonates (CO3 2-), phosphates (PO4 3-), sulfides (S 2-_and hydroxides (OH-_ are insoluble in H20
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exeptions LiOH, NaOHI, KOH, and aqueous NH3 ARE soluble in H20
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oxidation - reduction reaction
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AKA redox reaction; transfer of electrons from 2 species to another
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oxidizing agent
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an entity that accepts electrons in an oxidation-reduction reaction
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reducing agent
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an entity that donates electrons in an oxidation-reduction reaction
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oxidation
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gain of oxygen and/or loss of hydrogen
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reduction
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loss of oxygen and/or gain of hydrogen
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gas
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molecules far apart and disorganized; little interaction
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liquid
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intermediate situation
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solid
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molecules close together and ordered; strong interaction between molecules
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The number 12574.78 rounded to 3 significant figures will be
|
1.25 x 10e4
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Which of the following changes is an example of a chemical change?
a - heating water b - ice melting c - cooking food d - alcohol evaporating e - condensing steam |
c - cooking of food
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When a strong magnet is brought near to a sample which is known to contain both iron and sulfur, the iron and sulfur are not separated from one another. Wha type of material is this sample?
a - a compound b - a homogeneous mixture c - a heterogeneous mixture d - an element |
a - a compound
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A statement that is made to explain an observation is called
a - a hypothesis b - a theory c - a fact d - a law e - an equation |
a hypothesis
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Gasline is immiscible in water. The density of gasoline is 0.025 g/mL at 20 degrees C. When gasoline is added to water (denisty of water is 1.0 g/mL):
a - it will float on top b - it will sink to the bottom c - it will mix so you can't see it d - the mixture will ijprove the running of the motor c - none of these things will happen |
it will float on top
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A block of a material of mass 25 grams and volume of 1 cm3 is dropped in water. How much water would it displace?
a - 15 cc b - 25 cc c - 40 cc d - 50 cc |
15 cc
|
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Which of the following elements is a halogen?
a - Ag B - Br c - B d - N e - Fe |
Br
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Which of the following postulates from Dalton's atomic theory are now known to be incorect?
i) matter is made up of atoms ii) atoms are individisible and indestructible iii) all atoms of a given element are identical |
(ii) and (iii)
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What is the name of the lement with a mass number 45 and 24 neutrons?
a - chromium b - Scandium c - Rhodium D - Titanium e - thulium |
b - Scandium
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The three common isotopes of hydrogen has
a - the same mass number and equal number of protons b - the same atomic number and equal number of protons c - the same atomic number and equal number of neutrons d - the same mass number and equal number of electrons e - the same mass number and equal number of protons |
the same atomic number and equal number of protons
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Which three elements are likely to have similar chemical and physical properties?
a nitrogen, oxygen, and neon b. sodium, magnesium and alumininum c. calcium, strontium and barium d. nickel, copper and zinc e. uranium, plutonium and americium |
calcium, strontium and barium
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Which of these is not a stable ion?
a. Ba+ b. Li+ c. Br- d Se 2- e. P3- |
Ba+
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Thelement aluminum is mostly likely to form which of these ions?
a. Al+ b. Al2+ c. Al3+ d. Al3- e. Al5- |
Al3+
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A nitride ion has ____ electrons?
|
10
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Vanadium (v) with 30 neutrons has an atomic number of ____ and _____ electrons. (V is a roman numeral)
|
23, 18
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Elemments in which group are most likely o form ions with -3 charge?
Group I Group II Group II Group IV Group V |
Group V
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Which of the following pairs have the same number of electrons?
Cu2+ and Cu+ a2+ and Mg2+ Cl and Br- F- and O2- H+ and H- |
F- and O2-
|
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A good example of an ionic compound is
H20 C2H5OH Dry ice solid Co2) K2CO3 CH4 |
K2CO3
|
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Which of the following pairs will form a polar covalent bond?Ca - CL
Cl - Cl Mn - Cl N - Cl Ni - Cl |
N - Cl
|
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A battery stores chemical potential energy. Into what form of kinetic energy can this potntial energy be converted to play a radio?
a - thermal energy b - electrical energy c - radiant energy d - electrostatic energy e - mechanical energy |
electrical energy
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You an drive at a speed of 65 miles per hour whereas your spouse can drive at a speed of 35 meters per second. Explain with appropriate calculations who can drive faster.
|
65 mph = ? meters per second
65 mi/hr x 1.609 km/1 mi x 1000 mi/km x 1 hr/60 min x 1 min/60 sec = 29 meters/second Spouse can drive faster at a speed of 35 meters per second |
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The temperature of Monday is 88 degrees F and that of Tuesday is 25 degrees C. Which day is hotter? Show your work
|
C = 5/9 (F-32)
c = 5/9 (88-32) c = 5/9 (56) c = 31 degrees Tuesday is hotter |
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You can identify a metal by careful determining its density "d". An unknown piece of metal, wth a mass of 29.454 g, is 2.35 cm long, 1.34 cm wide, and 1.05 cm thick. Which of the following is the element?
Nickel, d = 8.91 g/cm3 Titanium, d = r.t0 g/cm3 Zinc, d = 7.14 g/cm3 Tin, d= 7.23 g/cm3 |
d = m/v
29.454 g/2.35 cm x 1.34 cm x 1.05 cm = 29.454/3.306.45 = 8.90804337 g/cm3 |
|
Complete the following. Show your work:
|
Protons = electrons
atomic # = # of protons mass # - protons = neutrons |
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Compelte the formulas for the compounds formed and name each compound:
Fe 2+ and Br- = |
FeBr2
|
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Compelte the formulas for the compounds formed and name each compound:
Li+ and Br- = |
LiBr
|
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Compelte the formulas for the compounds formed and name each compound:
Li+ and O2- = |
Li2O
|
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Compelte the formulas for the compounds formed and name each compound:
Li+ and PO4 3- = |
Li3PO4
|
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Compelte the formulas for the compounds formed and name each compound:
Fe2+ and Br- |
FeBr2
|
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Compelte the formulas for the compounds formed and name each compound:
Fe2+ and O2- |
FeO
|
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Compelte the formulas for the compounds formed and name each compound:
Fe2+ and Po4 3- |
Fe3 (PO4)2
Ferrous Phosphate |
|
Compelte the formulas for the compounds formed and name each compound:
Al3+ and Br - |
AlBr3
Aluminium bromide |
|
Al3+ and O2-
|
Al2O3
aluminium oxide |
|
Al3+ and PO4 3-
|
Al(PO4)
aluminum phosphate |
|
A house is made of wood and glass. Assuming an equal amount of sunshine falls on a wooden wall and a piece of clean glass (of equal mass), which warms more? The specific heats of wood and glass are 1.76 J/g.K and 0.84 J/g.K respectively. Explain briefly.
|
Wood is used i home bulding as insulation from heat and cold which would indicate it does nto doncut heat or cold as well as glass. The specific heat required to raise 1 g of wood is 1.87J/g.K whereas it only takes 0.84J/g.K to raise the temperature of 1 g of glass. This means that glass warms much easier than wood To raise the temperature of wood one degree requires more energy than the glass.
|
|
The number 5 X 10e3 written in exponential notation, can be written in full as
a - .005 b - 0.05 c - 500 d - 5000 |
0.005
|
|
An example of a pure subsance is:
a - blood b - salt c - milk d - air |
salt
|
|
Which is a chemical change?
a - melting of snow b - making tea from tea bag c - distilling ocean water d - dropping alka seltzer tablet in water |
dropping alka seltzer tablet in water
|
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The density of gsoline is 0.7025 g/mL at 20 degrees C. When gasoline is added to water denisty of water is 1.00 g/mL):
a - it will float on top b - it will sink to the bottom c - the mixture will improve the sunning of the motor d - none of these |
it will float on top
|
|
A battery operated power tool, such as cordless drill, converts
a - mechanical energy to thermal energy b - thermal energy to mechanical energy c - therman energy to chemical energy d - chemical energy to mechanical energy |
chemical energy to mechanical energy
|
|
1 kg = 2.205 lb; 1 lb = 16 oz. How many kilograms are prewsent in 125 ounces?
|
125 oz/1 x 1 lb/16 oz x 1/kg/2.205 lb = 125/35.28 = 3.54 kg
|
|
A rectangle block has dimensions 2.9 cm x 3.5 cm x 10.0 cm. The density of the block is 3.51 g/cm3. What is the mass of the block? (d=m/v)
|
d = 3.5 g/cm3 =
m?/v+2.9 cm x 3.5 cm x 10.0 cm = 3.56265 m = 3.6 x 10e7 g |
|
Which of the following groups of the periodic table contains no metallic elements?
a - 4A b - 5A c - 6A d - 7A |
7A
|
|
An alkaline earth metal, a halogen, a transition metal and a noble gas are in the order:
a - Na, Cl, Fe, Ar b - Ba, Br, Mn, Ar c - Ba, N, Fe, He d - Ba Br, Pb, Ne |
Ba, Br, Mn Ar
|
|
Which three elements are likely to have similar cheical and physical properties?
a - nitrogen, oxygen, and neon b - sodium, magnesium and aluminum c - nickel, copper and zinc d - oxygen, sulfur and selenium |
oxygen, sulfur, selenium
|
|
How many electrons can be accommodated in the 3rd shell?
a - 8 b - 10 c - 18 d - 32 |
18
|
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How many valence electrons are in the sulfur atom?
a 2 b 4 c 6 d 16 |
6
|
|
A student is preparing a sugar water solution to make rock candy. When the student continues to add sugar to the solution no additional sugar dissolves. Which kind of solution does the student have?
|
saturated solution
|
|
Which of the following solute will not dissolve in water?
a - KCl b - MgCl2 c - HCl d - CCl4 |
CCl4
|
|
A cucumber is placed in a concentrated salt solution. What will most likely happen?
a - wter will flow from the cucumber to the solution b - water will flow from the solution to the cucumber c - salt will flow into the cucumber d - salt will precipitate out |
Water will flow from the cucumber
|
|
Which of the following is the conjugate acid of NH3?
a. H+ b. H3O+ c NH2- d. NH4+ |
NH4+
|
|
Which of the following solutions has the highest pH? a 0.1 M HCl
b 0.2 M HCl c. pure H20 d 0.1 M NaOH e. 0.2 M NaOH |
0.2 M NaOH
|
|
What is the mass of salt in a 400 gram sample of salt water which is 2.50% (w/W)?
|
400 g x 015/1 g = 6.00 g salt
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How many mL of pur alcohol are in 200 ml glass of wine that is 12% alcohol by volume. How much watrre is added?
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12% (v/v)
volume of solution = 200mL 12% = X mL solute (alcohol)/200 L wine X 100 x = 12/200/100 x 100 x = 24 mL alcohol 200 -24 = 176 mL H20 |
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a 50.0 g sample of a saline solution contains 1.75 g of NaCl. What is the % by weight concentration? (w/w)
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1.75 grams solute/50.0 grams solution x 100 = 3.50% w/w
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What is the mass of hydrogen peroxide in 250 grams of a 3.0% by weight solution? w/w
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grams of solute/grams of solution x 100
3.0% = x grams of hydrogen peroxide / 250 grms solution x 100 x = 3.0x250/100 = 750/100 = 7.5 grms hydrogen peroxide |
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Calculate the molarity of a solution prepared by dissolving 5.844 g of NaCl in enough water to make a 200.0 mL solution.
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molarity = moles solute/volume of solution
5.844 g x 1 mol/58.44 (molar mass)g = 0.100 mol 0.1000 ol/.200 L - .500 mol/L or .50 M |
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Calculate the moles of NaOH present in 500.0 mL of 0.25 M NaOH.
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.25 M NaOH = x moles solute/.50 L = 0.13 mol NaOH
0.25 mol x .5000 L = 0.13 mol |
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Calculate the volume of 0.5 m HCl that would contain 2.0 mol HCl
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0.5 mol/L = 2.0 mol HCl/X = 2.0 ol/.5 mol/L = 4L
2.0 mol HCl/5 ol HCl vol (L) = 4.L |