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45 Cards in this Set

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  • Back

What is nanotechnology?

The use of technology that manipulates and investigate the properties of materials on nanoscale

Nanoscale

Objects between 1-100nm

Steps to convert

1. Convert to metres


2. Convert to scientific notation


3. X by 10^-9

Uses of nanotech

Drug delivery: nanoworms, too small for the immune system to attack them


Fabrics: waterproof properties

What is the bottom up and top down methods?

Bottom up: uses atoms to gradually build up the nano particles



Top down: breaks down a bulk material to form the nano particle

3 ways nanoparticle size is good:

1. Absorption of molecules - removes unwanted chemicals


2. Transportation of molecules


3. Catalysts - SA can be used to increase the rate of chemical reaction. It's small enough that it isn't used up in the reaction but can speed it up

When and what did john dalton propose

1802, the atomic theory of matter. All matter is made up of tiny spherical particles which are indivisible and indestructible

Define elements

Elements contain one type of atom

Define compound

Different types of atoms in fixed ratios. Can be broken down into individual elements

What can carbon form

Giant molecules and lattices. Eg) diamond and graphite

Define monatomic

Exists only as a single atom. Noble gases

How is the symbol of elements set out

A - mass no


X - element symbol


Z - atomic no

Nucleons

Protons and neautrons found in the nucleus

Electron weight compared protons

1/1800

Isotopes

Same number of protons, different number of neutrons

Isotopes have the same what?

the same chemical properties, but different physical properties as their original element

Electromagnetic radiation

The light given off when electrons are excited

Emission spectra

Coloured lines that appear on black paper when the light from an excited atom is put through a prism

Violet light has what energy level?

High energy

What information is gathered from the emission spectra?

1. Atoms of the same element produce the same lines on the spectra


2. Each atom has a unique line spectra, therefore a unique electronic structure

What did Bohr propose?

1. Electrons revolve around the nucleus


2. Electrons orbit in corresponding energy levels


3. Electrons only occupy fixed energy levels, they can't float between


4. Orbits of a larger radii = higher energy levels

When was the Bohr model developed and what did it entail

1913. Neil Bohr developed a new model of a hydrogen atom that described the emission spectra

Electron shells are

Different energy levels of an atom

Define ground state and excited state

Ground state: the lowest energy level of an atom


Excited state: when an electron absorbs energy and jumps to a higher energy kevel

Define electron configurstion

The arrangement of electrons around the nucleus

Ionisation emergy

The energy needed to remove an electron from an atom

Define electron configurstion

The arrangement of electrons around the nucleus

Formula for the number of electrons a shell can homd

2n^2

Define valence electron

The electrons found on the outer most shell of an atom. It is involved in chemical reactions

What can't the Bohr model explain?

1. Can't accurately predict emission spectra of atom with more than one electron


2. Unable to explain why shells only hold 2n^2


3. Why the fourth shell takes 2 electrons before the 3rd shell can fill

What did schrodinger propose and when

1926, proposed that electrons behave in waves around the nucleus. Developed model of atom called quantum mechanics

Difference between the Bohr and schrodinger model

Bohr viewed electrons as hard particles that revolve in orbits. Schrodinger viewed them as wave like properties. They occupy a 3D space around the nucleus called an orbital

What are the subshells

S, p, d and f. S holds 2, p holds 6, d holds 10 and f holds 14

Who created one of the first periodic tsbles

Mendeleev

What are the main group elements

1-2, 13-18

What do groups 3-12 hold

Transition metals

What do the blocks of subshells tell us

The blocks of subshells tell us which subshells has the highest energy for that atom

What do periods of a PT signify

The period is how many electron shells there are. Runs horizontal

What is core charge/how is it calculated. What is it's trend on the PT

Core charge is the measure of attraction between valence electrons and the nucleus. Core charge = number of protons - inner electrons. Increases left to right, remains constant down a group

Electronegativity trend/definition

Electronegativity is the ability of an atom to attract electrons towards itself. Increases across a period as the core charge does, decreases down a period as shells are added. Greater core charge = greater electronegativity

Atomic radius trend/definition

Decreases left to right. Increases down a group. The measurement for the size of an atom

First ionisation energy

The amount of energy required to remove an electron from an atom. Increases across a period, decreases down a period

Metallic character

Decreases left to right. Increases down a group

Reactivity trend/definition

How easily an atom loses or gains an electron. For metals: increases down a group. For non-metals: increases across a period, decreases down a group

Timeline of atom development

1804: dalton- atoms


1897: Thomson - electrons


1911: Rutherford - nuclear atom


1913: Bohr - shell model


1926: schrodinger - quantum mechanics


1932: Chadwick- neutrons