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26 Cards in this Set

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Standard Deviation

sigma = (Sum (xi-xave)^2 / (n-1))^1/2




sigfig to 1st significant number

% Error

= (Measured - True)/True

Precision v. Accuracy

Precision: closeness a set of measurements are to each other.




Accuracy: closeness of measurements to the true value.

Types of Errors

Systematic


Random


Personal

Systematic Errors

Causes error in same direction in each measurement and diminishes accuracy.




i.e. miscalibrated scale

Random Errors

Random error inherent in any measurement

Personal Error

Personal blunder due to carelessness or misreading of scale.

Element

Smallest component of matter that cannot be further broken down into subsidiary components

Compound

2 or more elements chemically bonded creating a substance that is different from the component elements

Mixture

2 or more substances that are physically mixed together.

Homogenous v. Hetergeneous Mixtures

Homogenous: mixture that is uniform throughout




Hetergeneous: mixture that is not uniform throughout

Compound v. Mixture

Compounds are chemically bonded and have fixed proportions of component atoms.




Mixtures are physically mixed and don't have fixed proportions

Isotope

Atoms of the same element but with different atomic weights due to a different number of neutrons.

Ions

Atoms of the same element but with different number of electrons

Relationship of speed of light, wavelength and frequency

c=lambda X freq


c=2.998X10^8m/s

Energy of a Photon

E = h X freq


h: Plank's constant = 6.626 X 10^-34 Js

Rydberg Equation

1/lambda = R (1/nf^2 - 1/ni^2)


R: Rydberg constant = 1.0974 X 10^7 m^-1

Electron Configuration Exceptions

Cr, Mo (half filled d)


Ru, Rh


Pd, Cu, Ag (full d)

Experiment 1 Details

Elements, Compounds and Mixtures


FeS, Fe, S, Fe + S


Physical properties: density, boil, melt, magnetism


Chemical properties: rxn w/ HCl


- evidence: odor, bubbling H2 and H2S gases

Experiment 2 Details

Line spectra:


H, He, N, Ne, Ar and CO2


Flame Test:


K, Na, Ba, Ca, Li, Sr chlorides

Experiment 2 Flame Test Colors

KCl: purple flame


NaCl: yellow/orange flame


BaCl2: green flame


CaCl2: orange flame


LiCl: red flame


SrCl2: red flame

Ionic Bonds

Bond between a metal and nonmetal w/ txfr of electron.


Electrostatic forces hold bond together

Covalent Bond

Bond between nonmetals w/ electron sharing


Held together by electrostatic forces.

Ionic Compound Properties

Hard and rigid but brittle


Conduct electricity when molten or dissolved in H2O


High melt temps

Covalent Compound Properties

Soft


Low melting temps


Do not conduct electricity

Binary Compounds


Type I, Type II, Type III

Type I: ionic (metal + anion -ide)


Type II: transition ionic (metal (chrg) + anion -ide)


Type III: covalent (#atom + #atom -ide)