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33 Cards in this Set
- Front
- Back
Aqueous Solution
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Acids and Bases in Water
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Homogeneous Solutions
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can't see parts
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ACID
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Proton H+ Donor
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BASE
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Proton H+ Acceptor
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Strong Acid
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In water ionizes to 100%
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Weak Acid
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in water ionizes to less than 100%
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Acetic Acid
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about 4 or 5%
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Di and Tri Protic Acids
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weak acids
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Common Ion Effect
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System at Equilibrium is stressed with an ion that is common to the substance being ionized
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Buffer
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mix of a weak acid and the salt of a weak acid. Reduces stress of addition of acid or base to solution
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pKa
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must be within +/- ONE unit of the pH of the solution
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Titration
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Take volume of acid & add volumes of base until endpoint
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Phenalthaline
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turning pink indicates neutralization point
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Chemical Thermodynamics
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You can convert energy from one for to another, but it cannot be destroyed
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Spontaneous Process
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Happens without any outside help
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Non-Spontaneous
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Doesn't happen by itself
(ex: picking a ball up) |
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Reversible
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can go back under the same conditions
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Irreversible
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cannot go back
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Ice-O-Thermal
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Happens at a constant temperature
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Entropy
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-measures the disorder of a system
-"S" -2nd law of thermodynamics |
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System
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Any part of the universe that you describe as being part of the system
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Surroundings
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Everything outside of the system
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Fusion
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Process where something melts
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3 conditions for determining sign of delta S
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Temperature
Volume # of Particles |
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If the gases are formed from gasses or liquids,
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the values are POSITIVE
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If a liquid or solution is formed from a solid,
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there is a greater DISORDER
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If the # of gas molecules increases in a reaction,
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there is a greater DISORDER
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Pure crystalline substance at 0 degrees has an entropy value of
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zero
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Increase in temp
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causes increase in entropy pos. value, or an increase in disorder
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Free Energy
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the energy that is available to do work
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Delta G degrees (-)
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Reaction spontaneous in forward direction
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Delta G degrees (0)
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System at equilibrium
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Delta G degrees (+)
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non-spontaneous in forward direction, but spontaneous in reverse direction
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