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103 Cards in this Set

  • Front
  • Back

Describe the structure of an atom:

Tiny nucleus in the middle containing protons and neutrons- positively charged nucleus




Sea of free electrons in shells

What are the charges and relative masses of the particles in an atom?

Particle Charge Mass




Proton +1 1


Neutron 0 1


Electron -1 1/2000

What is the relationship between protons and electrons?

No. of protons = No. of electrons

What is an element?

A substance with only one type of atom


All of one element have the same number of protons

What do all elements in one group have in common (in the periodic table) ?

They all have the same number of electrons in their outermost shell

What do all the elements in one period have in common?

They all the the same number of electron shells

What is the mass number?

The combined number of protons and neutrons

What is the atomic number?

The number of protons in an element ( and subsidently the number of electrons)

How do you work out the number of neutrons?

Mass number - atomic number

How are the electrons organised?

They are organised in shells and the lowest energy levels nearest the nucleus are filled first


1st shell - 2 electrons


2nd and 3rd- 8 electrons

Why do atoms want to react?

To gain a full outer shell of electrons so they re un-reactive

Why are the noble gases stable?

They are un-reactive as they have a full outer shell of electrons

Explain how ionic bonding works:

A non-metal and a metal bond as the metal atom loses electrons to form positive ions and the non-metal atom gains electrons to form negative ions - to fill their outer shells


These opposite charges are then attracted to each other

Explain how covalent bonding works:

Non-metals bond together by sharing electrons to fill up their outer shell


They then form molecules with shared pairs of electrons forming covalent bond

What does the law of conservation of mass mean?

That atoms aren't lost or gained in a chemical reaction


Therefore there must be the same number of atoms of both sides of the equation

What is limestone?

Limestone is quarried out of the ground and it used for building it is mainly calcium carbonate


( CaCO3)

What is the limecycle?

Limestone is thermally decomposed to form Calcium oxide and carbon dioxide


Water is then added to form calcium hydroxide


More carbon dioxide is then added to form calcium carbonate again and water

How do you make cement?

You use limestone and powdered clay

How do you make mortar?

You mix cement with water and sane

How do you make concrete ?

You mix cement with sand and aggregate

What are the advantages of using limestone as a product

It is widely available and cheap to buy


It is hardwearing but still looks attractive


It is quick and cheap to build with


It doesn't rot when wet


It sit ire resistant and can't be corroded

What are the advantages of quarrying limestone?

It can provide jobs for people and boost the local economy


It can also lead to improvements locally with transport, roads and recreation facilities


Afterwards it can be made into a lake for wildlife

What are the disadvantages of quarrying limestone

It can create noise pollution for the locals


It can create dust which can cause breathing problems


Energy needed comes from burning fossil fuels which realises carbon dioxide


Destroys habitats of animals


Permanently destroys land- visual pollution

What can limestone be used for?

Houses, roads


Chemicals in it can be used to make dyes, paint and medicines


Can neutralise acidic soil, and acidic lakes + river

What is an ore?

A rock which contains enough metal to make it worthwhile extracting.


In many places it is extracted as an oxide

Why are low grade ore now extracted?

As we are running out of high grade ores and the need for the metals is still very high

What are the stages of extraction of a metal?

Mine ---> Concentrate ---> extract ---> purify

When is reduction used to extract a metal?

When the metal is below carbon in reactivity


Carbon is added and this removes the oxygen from the ore and forms the pure metal and carbon dioxide

When is electrolysis used to extract a metal?

When the metal is more reactive than carbon


This is more expensive as energy is needed to make the ore molten and for the electricity

What is a native metal?

A metal which when quarried is not combined with anything else

How is copper extracted?

Copper is reduced with carbon and then smelted in a furnace


Electrolysis is then used to purify it


The copper ions near the cathode gain electrons and become copper atoms

How are load grade ores extracted (copper)?

Bio-leaching


or


Phytomining



What is bio-leaching?

When bacteria feed on copper compounds and this produces copper solution which cane then be displaced or electrolysed

What is phytomining?

When plants are grown on copper soil, the copper ions then absorb the ions and accumulate in the leaves

When the leaves are burnt copper oxide is produced


Then this is reacted with sulphuric acid which creates copper sulphate solution which can be purified using electrolysis or displacement

In displacement why is scrap iron sometimes used?

It is very cheap and is more reactive than copper

How is iron extracted?

In a blast furnace cast iron is formed which has some carbon in it and is very brittle.


The cast iron in then reacted with oxygen to produce sure iron

What is steel used for?

Stainless - cutlery and hospital instruments


Low carbon = car bodies


High carbon = blades for cutting tools and bridges

What are the types of steel?

Steel is an alloy


Stainless- easy to clean, doesn't corrode


Low carbon - easily shaped


High carbon - very hard

What are the pros and cons on metal extraction?

Pros


Useful products made


Boosts local economy and creates jobs


Cons


Causes noise and visual pollution


Can be dangerous is abandoned

Why is recycling metal important?

Fossil fuels are running out - need to conserve them- burning also leads to acid rain, global dimming and climate change


Less stages so less energy than to extract again


Landfills takes up space and pollute the area

What are the properties of transition metals?

They are the typical metals they are good conductors of heat and electricity


They are malleable and strong

Use of titanium?

It is un-reactive, strong, has a high melting point, low density and is resistant to corrosion


Therefore it can be used as artificial hips

Why is titanium expensive?

Once reacted with carbon it is too brittle so it has to be reacted with chlorine and then magnesium and sodium.


The electrolysis of these metals is expensive and there are also lots of stages

Use of aluminium?

It is light weight, strong, resistant to corrosion, low density, un-reactive,good conductor of heat and electricity, ductile and malleable


It is used in planes

Use of copper?

It is a good conductor of heat and electricity, it is malleable and un-reactive


Used as water pipes and electricity wires

What is an alloy?

A mixture of different metals

Why are alloys stronger than pure metals?

They include different sized atoms so the layers are distorted an they can't as easily slide over each other

Give some example of alloys

Bronze- copper + tin (medals and statues)


Gold alloys - used to make jewellery


Aluminium alloys - used to make aircraft

What is crude oil?

A picture of hydrocarbons


Hydrocarbons are compounds made of just carbon and hydrogen

How does a fractionating column work?

Crude oil is pumped in the bottom and the vaporised oil rises up the column and it tapped off at different levels when it condenses.

What is an alkane?

A saturated hydrocarbon with chains of carbon atoms surrounded by hydrogen atoms

What is the formula for an alkane?

CnH2n+2

What are the trends for molecules from crude oil?

The shorter the molecule - the less viscous


II - the more flammable


II - the more volatile


volatile = turns into a gas at a lower temperature

What are the different uses of hydrocarbons?

The refinery gas is used as bottled gas as it has the lowest boiling point


The petrol fraction has a high boiling point so it easily stood in a car and ignited


Viscous hydrocarbons are used for covering road

Pros of using crude oil as a fuel?

Often cheapest and easiest fuel to use


More reliable as doesn't rely on earth conditions

Cons of using crude oil as a fuel?

Non-renewable so will run out


Oil spills cause poison organisms such as birds and other marine organisms


Burning oil causes global warming, acid rain and global dimming

How is sulphur dioxide produced?

When the fuel is burnt such as crude oil, if the fuel has sulphur impurities sulphur dioxide is released.

What is produced when fuel is burnt if it incomplete combustion occurs?

Carbon monoxide which is a poisonous gas

What affect does sulphur dioxide have on the environment?

It reacts with the clouds to form dilute sulphuric acid which falls as acid rain


This causes lakes to become acidic and kills trees, as well as damaging buildings

How to rescue acid rain?

Use low sulphur fuels


Reduce use of fossil fuels

What are the effects of global warming?

Carbon dioxide leads to global warming which leads to the ice caps melting and flooding and many other problems

What are the effects of global dimming?

Global dimming is caused by particles of soot and ash from burning fossil fuels


Global dimming reflects sunlight back into space

What are alternative duels which are renewable?

Ethanol


Biodiesel


Hydrogen gas

What are the pros and cons to ethanol

Ethanol is produced from plant material and the fermentation of plants


Pro


It is carbon neutral as the plants photo synth..


Cons


It isn't widely available


Increase food prices- land is used


Engines have to be converted

What are the pros and cons to biodiesel?

Produced from vegetable oils


Pros


It is carbon neutral Less sulphur dioxide made


Engines don't have to be converted


Cons


Expensive to make and could also increase food prices, also hard to make

What are the pros and cons to hydrogen gas?

It is made form he electrolysis of water


Pros


It is very clean only produces water


Cons


Need special expensive engine


Hard to store

What is cracking?

= Breaking down long hydrocarbon chains into smaller more useful chains

How does cracking occur?

Cracking is thermal decomposition


The hydrocarbon chain is vaporised with heat


Then the vapour is passed over a powdered catalyst of aluminium oxide at around 400-700 oC

What are the products of cracking?

Most of the product are alkanes and some alkenes this is used to form products such as ethene

What is an alkene?

= An unsaturated hydrocarbon with a double bond

What is the formula for an alkene?

CnH2n

How do you test for an alkene?

Use bromine water and alkene will make the water go colourless and the double bond will open and bond with the bromine

How is ethanol produced?

Ethene is reacted with steam with a catalyst to make ethanol


It is cheap, however ethene is from crude oil so is non-renewable so it will become very expensive

How does fermentation occur?

Sugar is converted into carbon dioxide and ethanol with a low temperature


The raw material is renewable, and it is cheap


Although it isn't very concentrated and needs to be purified

What is polymerisation?

Joining together lots of small alkene molecules to form long chain molecules (polymers)

How do you change the physical properties of a polymer?

Change what monomers it is made of


Change the conditions used to make it the temperature and the pressure

What are the different uses of polymers?

Light stretchable polymers are used to make plastic bags and tights


Dental polymers- used in resin in fillings


Polymer- used as smart material with memory foam mattresses

Why are polymers hard to recycle?

They aren't biodegradable so they aren't broken down by micro-organisms

How is oil extracted from a plant?

The material is crushed


Then it is pressed between metal plates


Then it is distilled to remove impurities

Why re vegetable oils used in food?

They have very high energy


They have nutrients such as vitamins


They have essential fatty acids

Why are vegetable oils good for cooking?

They have high boiling points than water


They give food a different flavour


They increase the energy content of the food

How can vegetable oils be used to make fuels?

They can be processed to make fuels such as biodiesel as they have a lot of energy so are suitable as fuels

What are the characteristics of unsaturated oils?

They contain long-chain molecules with double bonds


They de-colourise bromine water- alkenes


Liquid at room temperature

What is hydrogenation?

When hydrogen is reacted with unsaturated oils with a nickel catalyst at 60oC.

What are the properties of hydrogenated oils?

They have higher melting points- spreadable


They are cheaper and keep longer


Partially hydrogenated have lots of trans fats which are bad for you.

Which are healthier saturated or unsaturated fats?

Unsaturated fats are healthier as saturated fats increase cholesterol in you blood blocking up arteries and increasing the risk of heart disease


Natural unsaturatedjfats reduce blood cholesterol

Why are emulsifiers used?

So that two miscible liquids can be mixed as the emulsifier molecule has a hydrophilic head and a hydrophobic tail


Therefore the emulsifier surrounds the oil droplets so the emulsion won't separate

What re the properties of emulsions?

Thicker, and better at coating foods


They have a softer texture, they can also be used in moisturising lotions to make it easier to rub well into skin.

What are the pros and cons on emulsions?

Pros


Gives emulsions a long shelf life


Lower in fat with a good texture


Con


Many people are allergic to emulsifiers

How did people used to think mountains were formed?

They believed as the earth sued to be very hot, that when it cooled down the wrinkles formed mountains


However the negatives of this are that if it were true the earth would still be shrinking and there would be mountains everywhere.

What is Wegner's theory of continental drift?

He said that 300 million years ago there was one supercontinent Pangea and that eventually the contents drifted apart to form our world today

What proof did Wegner have?

Similar fossils were found on different continent


South America and Africa seem to fit together like a jigsaw


Similar animals were found on different continents

Why didn't people accept Wegner's theory?

There were simpler explanations such as land bridges that don't still occur


He didn't have an explanation as to why it happened


There wasn't enough proof (only a few cm move each year)

What is the structure of the earth?

The crust is the top and thinnest layer- solid


The mantle is solid but moves like a liquid


The outer and inner core combined are the thickest layer

What are the tectonic plates?

Slabs of earth made up of the crust and upper mantle

Why do the tectonic plates move?

Convection currents in the mantle are caused by radioactive processes releasing heat


These convection currents move the tectonic plates a few cm each year


Volcanoes and earthquakes occur at plate boundaries

Why can't scientists predict earthquakes and volcanic eruptions?

They can't see what is happening in the mantle


Don't want to evacuate people for no reason


Don't know their strength


They are sometimes wrong

How are gases separated from the air?

Filtered- to remove impurities


Cooled to - 200 and water and carbon dioxide is removes as a solid so not to block the pipes


All liquids going into fractionating column


Nitrogen goes first and then argon and oxygen are further distilled

What gases were there in the early atmosphere?

Carbon dioxide


Methane trace


Ammonia trace


Water vapour


However as the earth cooled the water vapour condensed and fell as rain forming oceans

How was Carbon dioxide removed from the early atmosphere?

Absorbed into eh ocean


Formed rocks


Fossil duels


Photosynthesis - oxygen increased


Sea creatures shells

How was nitrogen introduced into the atmosphere?

Ammonia and Oxygen reacted to form nitrogen gas

What is the Muller-Urey Primordial Soup theory?

As amino acid are the building blocks of proteins they must have been created uses the gases and conditions int eh early atmosphere


So some scientists uses specific gases and lightening and after a few weeks formed amino acids

What were the problems with the Muller-Urey experiment?

No-one can be sure the gases were all present


Could have been extra gases- not specifically chosen


Might not have had continuous lightening