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24 Cards in this Set

  • Front
  • Back

Relative isotopic mass

Mass of an atom of an isotope relative to 1/12th the mass of an atom of carbon-12

Relative atomic mass

Weighted mean mass of an atom of element relative to 1/12th the mass of an atom of carbon-12Inc a

Zinc and silver ion formual

Zn2+, Ag+

Polyatomic ions

NH4+


OH- , NO2-(nitrite), NO3- (nitrate) , HCO3-, MnO4- (manganate) , ClO3-(chlorate)



CO3^2-, SO4^2-, SO3^2-, Cr2O7^2- ( dichromate VI )


PO4^3-

g/dm^3 to mol/dm^3

Divide by M

Trend in first ionisation energy down a group

Atomic radius increases


More inner shells so shielding increases


Nuclear attraction on outer electrons decreases


First ionisation energy decreases

Trend in first ionisation energy across a period

Nuclear charge increases


Similar shielding due to same number of shells


So nuclear attraction increases


And atomic radius decreases


First ionisation energy increases

First ionisation subshell trend

Decrease from Group 2 to Group 3 (Be to B)


Group 2 outer electron is in s orbital


Group 3 outer electron is in p orbital


P orbital is higher energy than s orbital so less energy required to remove electron


2) decrease form group 5 to 6 ( N to O)


Group 5, p electrons are unpaired while group 6, p electrons are paired


Paired electrons repel more so easier to remove

Na to Al all giant metabollic bonding but why does melting point changes?

Size of metal ion decreases


Charge on metal ion increases


More number of delocalised electrons so increasing attraction between delocalised electrons


So more energy required

Electron configurations order

1s^2, 2s^2, 2p^6, 3s^2, 3p^6, 4s^2, 3d^10, 4p^6

Melting point of ionic compounds increase when

Ionic charge increase


Ionic size decrease

Are ionic compounds soluble?

Soluble in polar solvent such as water


Polar water molecules are attracted to ions and become hydrated and break down lattice and surround each ion in solution

Dative bond

Covalent bond in which share pair of electrons has been supplied by one bonding atom only

Molecular shapes without lone pairs

Linear - 2 bonding regions (180•)


Trigonal planar - 3 bonding pairs (120•)


Tetrahedral - 4 bonding pairs (109.5•)


Trigonal bipyrimidial - 5 bonding pairs ( 90,120)


Octahedral- 6 bonding pairs (90)

Molecular shape with lone pairs

Bent - 2 bonding pairs and 1 lone pair 117.5


Non linear - 2 bonding pairs and 2 lone pairs 104.5


Pyrimidial - 3 bonding pairs and 1 lone pair 107

Across periodic table the electronegativity


Nuclear charge


Atomic radius


Down the periodic table the electronegativity

Increases


Increases


Decrease


Decrease

Hydrogen bonding

Bond between lone pair of electrons on an electronegative atom in one molecule and a hydrogen atom in another molecule

First ionisation energy definition

Energy required to remove one electron from each atom in one mole of gaseous atoms to form one mole of 1+ ions.

P to Ar the melting point depends on

Number of electrons

Units in ideal gas equation

p = Pa


V = m^3


T = K


pV = nRT

Disproportionate reaction

Same element is both reduced and oxidised

Disproportionate reaction

Sam element is both reduced and oxidised

Electronegativity increases as

You go up the group and across right the period

Oxidation number of


H in metal hydrides NaH


O in peroxide H2O2


O bonded to F F2O

-1


-1


+2