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24 Cards in this Set

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Define a redox reaction.

A réaction in which both oxidation and reduction occur.

c'mon man it's in the name.

Define Oxidation in all ways possible

-Addition of Oxygen


-Removal of Hydrogen


-Loss of electrons


-Increase in oxidation number/state

Define Reduction

-Removal of Oxygen


-Addition of Hydrogen


-Gain of electrons


-Decrease in oxidation state

Give one common example of oxidation.

Rusting or combustion

What is the oxidation number of Oxygen in O2?

0, all few elements have an oxidation number of 0.

What is the oxidation number of Na in NaOH?

+1, all Group I and Group II elements have oxidation numbers equal to their group number.

What's the oxidation state of H in NaH?

-1, Hydrogen always has an oxidation number of +1 except in metal hydrides like NaH

What is the oxidation number of O in H²O²?

-1, Oxygen also has an oxidation number of -2 except in peroxide compounds

What is the oxidation number rule for Group VII elements?

Always -1, except in compounds with more electronegative elements

What is the oxidation number of NaOH?

0, the oxidation number of a molecule is equal to the overall charge on the molecule

What's a reducing agent? (Give examples)

A species that reduces another species in a reaction and is therefore oxidised. Ex, NaBH⁴, LiAlH⁴

What's a oxidising agent? (Give examples)

A species that oxidises another species in a reaction and is therefore reduced. Ex, K²Cr²O⁴

List the steps to balancing a redox reaction.

-Split into reduction and Oxidation halves.


-Balance the oxidised and reduced species.


-Balance oxygen by adding H²O to the appropriate side.


-Balance hydrogen by adding H+ to the appropriate side.


.


-Balance charge by adding electrons.


-Manipulate coefficients to make electrons cancel out.


-Add the two halves together.

What is disproportionation?

A reaction in which one compound is both reduced and oxidised into two products.

What is the activity series?

A ranking of elements based on the ease of oxidation.

Give two types of electrochemical cross and what they do.

Voltaic cell: converts spontaneous chemical energy into electrical energy.



Electrolytic cell: uses electrical energy to start non-spontaneous chemical reactions.

What is an electrode?

A conducting material used to make contact with the non-metallic parts of the cell.

What are the two types of electrode (and what do they do)?

Anode: Oxidation


Cathode: Reduction

What is a metal/metal ion electrode?

A bar of metal dipped in a solution of its ions.

Describe a voltaic cell.

-Two half cells where oxidation and reduction occur separately.


-An external circuit/wire for the exchange of electrons.


-A salt bridge (usually made of agar) to prevent charge build-up


Give examples of salt bridges.

KCl and KNO³

Describe an electrolytic cell.

-An electrolyte to be electrolysed.


-A battery.


-Two (inert) electrodes connected to a battery and dipped in the electrolyte.


-A porous membrane.

Give two examples of electrode materials.

Graphite and platinum

What is electrolysis?

The decomposition of a compound by passing electric current through is molten or aqueous form.