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15 Cards in this Set

  • Front
  • Back
Draw the aldehyde functional group
Draw the ketone functional group
Draw the carboxylic acid functional group
Draw the ether functional group
Explain the term elimination reaction
A reaction in which a small molecule is removed from a larger molecule leaving an unsaturated molecule
What are the products in the dehydration of alcohol?
An unsaturated (alkene) molecule and water
What conditions are needed for the dehydration of an alcohol?
Alcohol vapour passed over alumina catalyst at 300ºC

OR


heating under reflux with concentrated sulfuric acid

Define an addition reaction
A reaction where two or more molecules react to form a single larger molecule
Define an electrophile
A positive ion or molecule with a partial positive charge that will be attracted to a negatively charged region and react by accepting a lone pair of electrons to form a covalent bond
State the colour change that occurs when bromine reacts with an alkene
orange-brown to colourless
Draw the electrophilic reaction between bromine and ethene and explain in clear steps what has occurred
-electrons in bromine repelled by alkene bond-bromine = polarised
-δ+ bromine acts as electrophile and accepts lone pair of electrons to form covalent bond w. carbon
-carbocation forms bc. lost electrons
-lone pair of Br- electrons given to carbo...
-electrons in bromine repelled by alkene bond

-bromine = polarised


-δ+ bromine acts as electrophile and accepts lone pair of electrons to form covalent bond w. carbon


-carbocation forms bc. lost electrons


-lone pair of Br- electrons given to carbocation to form new Br-C covalent bond



Draw the electrophilic reaction between hydrogen bromide and an ethene and state what conditions are needed
-room temperature with HBr solution in a polar solvent
-room temperature with HBr solution in a polar solvent
Draw the reaction of ethene and hydrogen and state the conditions needed
-Platinum catalyst at room temperature and pressureOR
-Nickel catalyst, finely milled, reactants heated to 150ºC
-Platinum catalyst at room temperature and pressure

OR


-Nickel catalyst, finely milled, reactants heated to 150ºC

How is ethanol made in the industry? Draw an equation for the addition reaction.
-Catalyst = phosphoric acid adsorbed onto solid silica-300 degrees, 60 atm
-water = steam
-Catalyst = phosphoric acid adsorbed onto solid silica

-300 degrees, 60 atm


-water = steam

How is ethanol made in the lab? Draw an equation for this addition reaction
-first add concentrated sulfuric acid-then dilute it with water
-water + alkene is e.g. of hydration reaction
-first add concentrated sulfuric acid

-then dilute it with water


-water + alkene is e.g. of hydration reaction