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23 Cards in this Set

  • Front
  • Back
Define a redox reaction
One species is oxidised whilst another is reduced



OIL


RIG

Define Oxidation
Oxidation is the loss of electrons
Define Reduction
Reduction is the gain of electrons
Where does cell glycolysis take place?
In the cytoplasm of prokaryotes and eukaryotes
What is ATP
The main energy currency of the cell
Name one electron carrier and identify its two forms
Nicotinamide adenine dinucleotide (NAD).





Oxidised it is NAD+




Reduced it is NADH




NAD+ + 2e- + H+ = NADH

Name another electron carrier and identify its two forms
Flavin Adenine Dinucleotide (FAD)



Oxidised it is FAD




Reduced it is FADH2




FAD + 2e + 2H+ = FADH2

Formula & Structure of glucose
C6



H12




O6

Definition of phosphorylation
Phosphate group is added
Definition of isomerisation
Molecule is transformed by rearranging
Definition of oxidation
The loss of electrons and thus increase in oxidation state
Formula and Structure of Pyruvate
CH3
CO
COO
H
The first step of glycolysis
Glucose is phosphorylated by ATP



Catalyzed by hexokinase




Glucose 6-phosphate is formed

The second step of glycolysis
Glucose 6-phosphate isomerised



Catalysed by phosphoglucose isomerase






Fructose 6-phosphate is formed

A conversion of which molecules occurs during the second step of glycolysis
Conversion of Glucose 6 phosphate (aldose)



To Fructose 6- phosphate (ketose)

The third step of glycolysis
Fructose 6- phosphate is phosphorylated by ATP



Catalyzed by phosphofructokinase (PFK)




Fructose 1 - 6 biphosphate formed and ADP

The fourth step of glycolysis
Fructose 1 6 biphosphate split



Catalyzed by Aldolase




Glyceraldehyde 3 phosphate formed




Dihydroxyacetone phosphate formed

The fifth step of glycolysis
Dihydroxyacetone phophate isomerized



Catalyzed by triose phopshate isomerase




Glyceraldehyde 3 phosphate formed

The sixth step of glycolysis
Glyceraldehyde 3 phosphate converted to 1, 3 biophosphoglycerate.



Catalyzed by glyceraldehyde 3 phosphate dehydrogenase




(Aldehyde group of glyceraldehyde 3 phosphate is oxidised)




Inorganic phosphate and NAD+ is used.









The seventh step of glycolysis
1 3 biophosphoglycerate transfer phosphoryl group to ADP



Catalyzed by phosphoglycerate kinase




ATP formed




3 - Phosphoglycerate formed

The eight step of glycolysis
3 - phopshoglyerate converted



Catalyzed by phosphoglycerate mutase




2 phosphoglycerate formed

The ninth step of glycolysis
2 phopshoglycerate dehydrated



Phosphophoenolpyruvate (PEP) formed




Catalyzed by enolase




Low energy phopshate ester bond converted into high energy phosphate bond of PEP

The tenth step of glycolysis
Phosphoenolpyruvate transfers phosphoryl group



to ADP




Catalyzed by pyruvate kinase




ATP Formed




Pyruvate formed