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88 Cards in this Set

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Atomic Structure


Describe the charges of protons, neutrons and electrons.

Protons: Positively charged


Neutrons: No charge


Electrons: Negatively charged

Atomic Structure


Describe the basic composition of an atom.

- Electron shells: negative charge, negligible mass


- Nucleus: protons (positive charge, mass of 1 a.m.u), neutrons (no charge, mass of 1 a.m.u)

Atomic Structure


What is the maximum number of electrons per electron shell?

- In the first, there can be a maximum of 2


- The others have a maximum of 8



Atomic Structure


What is the number shown at the top of an element on the periodic table?

- R.A.M: Relative Atomic Mass


- Mass number

Atomic Structure


What is the number shown at the bottom of an element on the periodic table?

- Atomic number


- Proton number

Atomic Structure


Which out of the atomic number and R.A.M has the higher value?

- R.A.M: larger value


- Atomic number: smaller value



Atomic Structure


What does the R.A.M/mass number tell us?

The number of protons and neutrons

Atomic Structure


What does the atomic number tell us?

The number of protons (and electrons)

Atomic Structure


How would you find out the number of neutrons in an atom?

Subtract the atomic number (the number of PROTONS) from the R.A.M (leaving only the number of NEUTRONS)

Periodic Table


What are groups and periods?

- Groups: Columns


- Periods: Rows

Periodic Table


What things are in Group 1?

Alkali metals

Periodic Table


What things are in Group 2?

Alkaline earth metals

Periodic Table


What things are in Group 7?

Halogens

Periodic Table


What things are in Group 8/0?

Noble Gases

Periodic Table


How do you determine the group of an element?

It's the number of electrons on its outer shell

Periodic Table


How do you determine the period of an element?

It's the number of electron shells


Atomic Structure


How can you determine an element's 'number' (e.g. 2.8.1)?

The numbers must add to the atomic number, and these numbers represent the number of electrons. There can be a maximum of 2 in the first electron shell and a maximum of 8 in the other shells.

Relative Atomic Mass


What is everything measured relative to?

Carbon -12

Isotopes


Give an example of an element that exists as 2 isotopes.

Chlorine

Isotopes


The R.A.M of chlorine is 35.5. Why is this?

- 75% of Chlorine on Earth is Cl 35


- 25% of Chlorine on Earth is Cl 37

Isotopes


How is the atomic mass of Chlorine calculated? (Words)

- Multiply the % by the R.A.M


- Add it with the % of the other multiplied by the other R.A.M


- Divide by the %s added together

Isotopes


How is the atomic mass of Chlorine calculated? (Numbers)

[(75x35) + (25x37)] / (75+25)


= 35.5


R.A.M = 35.5

Ions and Ionic Bonding


What is an ion?

An electrically charged particle

Ions and Ionic Bonding


How are ions formed?

Electron Transfer: the addition or removal of electrons

Ions and Ionic Bonding


Why do atoms bond together to form compounds?

To make an outer shell to make it more stable

Ions and Ionic Bonding


What is one way for atoms to bond?

Forming an ionic particle.

Ions and Ionic Bonding


What are cations?

Positively charged ions

Ions and Ionic Bonding


What are anions?

Negatively charged ions

Ions and Ionic Bonding


Let's say A transfers an electron to B. What happens to the two of them?

- A gains a positive charge as there are now more protons than electrons, so it's a cation.




- B gains a negative charge as there are now more electrons than protons, so it's an anion.

Ions and Ionic Bonding


What is an ionic bond?

When metal cations are electrostatically attracted to non-metal anions

Ions and Ionic Bonding


How is it determined as to whether or not an atom gains or loses electrons?

It does whatever is easiest - it's easier to gain 1 than lose 7 (to form 8 electrons).

Ions and Ionic Bonding


What do metals become when they lose electrons?

Metal cations

Ions and Ionic Bonding


What do non-metals become when they lose electrons?

Non-metal anions

Naming Compounds


What does the suffix -ide mean?

Only two elements are present


e.g. sodium chloride

Naming Compounds


What does the suffix -ate mean?

Two elements AND oxygen are present

Ions and Ionic Bonding


True or false: Ionic compounds are neutral overall

TRUE

Ions and Ionic Bonding


How is the charge (shown as subscript) determined?

The group determines it.


e.g. Aluminium is in Group 3 and forms a 3[+] charge.

Naming Compounds


Which compounds have the ending -ite and what does it mean?

- Iron suplhite and nitrogen oxite


- It means they have one less oxygen than the previous one - there are only two and they're anions (?)

Properties of Ionic Compounds


What is an ionic compound?

When you have an ionic lattice

Properties of Ionic Compounds


What is a lattice?

A regular cuboid arrangement of billions of ions

Properties of Ionic Compounds


When something becomes an ion, what suffix does it get?

-ide


e.g. Chlorine ---> Chloride

Properties of Ionic Compounds


What is the melting point of a lattice and why is it like this?

- It has a very HIGH melting point




- There are too many strong ionic bonds for it to be low

Properties of Ionic Compounds


In order for an ionic compound to conduct electricity, what type of charges must it have?

Mobile charges (charged particles that are free to flow and therefore can move)

Properties of Ionic Compounds


Why can't ionic solids conduct?

While they do contain ions, they can't move and therefore can't conduct.

Properties of Ionic Compounds


What properties must an ionic compound have to conduct electricity and how can these properties be attained?

- Aqueous: dissolve them in water


OR


- Molten: melt them

Properties of Ionic Compounds


Define electricity.

The flow of electrons

Soluble and Insoluble Salts


Which salts are soluble?

- All common sodium, potassium and ammonium salts


- Nitrates


- Most chlorides


- Most sulphates


- Sodium, potassium and ammonium carbonate


- Sodium, potassium and ammonium hydroxide

Soluble and Insoluble Salts


Which salts are insoluble?

- Silver and lead chloride


- Lead, barium and calcium suplhate


- Most carbonates


- Most hyrdroxidesq

Soluble and Insoluble Salts


What can Barium Sulphate be used in?

X-Ray machines

Covalent Bonding


What is a single covalent bond?

A shared pair of electrons between two non-metals

Covalent Bonding


What is a double covalent bond?

Two shared pairs of electrons between two non-metals

Covalent Bonding


What is the outcome of double and single covalent bonds?

Both elements have a full outer shell

Covalent Bonding


How is the number of shared electrons determined?

The numbers of electrons in the outer shell in the atom of an element


e.g. Carbon: Group 4 -> 4e[-] in the outer shell (needs to share 4e[-] to make 8e[-] in total)

Covalent Bonding


What must each individual element's outer shell add up to? What is the exception to this?

- 8e[-]


- Hydrogen: only 2e[-] on the outer shell

Properties of Covalent Substances


Why can't covalent substances conduct electricity?

They have no charged particles.

Properties of Covalent Substances


What are SMCS?

Simple Molecular Covalent Substances

Properties of Covalent Substances


List the properties of SMCS.

- Usually gas at room temp.


- Include molecules e.g. CO(2), NH(3), O(2), CO...


- Low boiling and melting points


- Exist as discreet molecules (e.g. a carbon atom joined to two oxygen atoms), i.e. individual molecules


- Strong bonds in the intramolecular covalent bonds


- Weak forces of attraction between molecules (intermolecular)

Properties of Covalent Substances


Describe the strength of the bonds in intramolecular and intermolecular forces.

- Intermolecular forces: Weak forces of attraction between molecules




- Intramolecular forces: Strong covalent bonds within the molecule

Properties of Covalent Substances


Define intramolecular forces.

Bonds within the molecule

Properties of Covalent Substances


Define intermolecular forces.

Forces of attraction between molecules

Properties of Covalent Substances


What are GMCs?

- Giant Molecular Covalent




- Structures with thousands of covalent bonds




- Solid at room temp.




- High boiling/melting points

Properties of Covalent Substances


Give three examples of GMCs.

- Diamonds - allotropes of carbon




- Graphite - allotropes of carbon




- Sand - silicon oxide



Properties of Covalent Substances


What arrangement does a diamond have?

Tetrahedral arrangement

Properties of Covalent Substances


Why is the maximum number of bonds carbon make to other carbon atoms 4?

Carbon is in Group 4 and therefore can make a maximum of 4 bonds.

Properties of Covalent Substances


Why can't carbon conduct electricity?

Because it can make a maximum of 4 bonds, there are no free electrons as they're all in covalent bonds.




No electrons, no conduction of electricity.

Properties of Covalent Substances


Describe the structure of graphite.

Flat sheets of hexagons.

Properties of Covalent Substances


How can graphite, unlike other carbon substances, conduct electricity?

- There's one free electron (localised electron) per carbon atom, meaning that the electrons can move between the layers




- Potential difference, or voltage, is applied




- This allows graphite to conduct electricity

Properties of Covalent Substances


Why does graphite have one free electron?

Because it's carbon, it's in Group 4 and therefore has four electrons.




Graphite only uses three for covalent bonding, so there's one left over.

Properties of Covalent Substances


How can graphite be used as a lubricant?

- There are weak forces of attraction between the layers




- So the layers can easily slide over each other




- Graphite can be used as a lubricant

Ion Tests


What can metal cations be tested with?

Flame tests

Ion Tests


What colours will sodium, calcium, potassium and copper go in the flame tests?

- Sodium: Yellow


- Calcium: Red


- Potassium: Lilac


- Copper: Green-blue or blue-green

Ion Tests


What are halide ions?

Ions of halogens

Ion Tests


Give three examples of halide ions.

- Silver Chloride (AgCl)




- Silver Bromide (AgBr)




- Silver Iodide (AgI)

Ion Tests


To test non-metal anions, which in this case are halide ions, what do you add to the halide ion? What does this create?

1) Add HNO(3) (Nitric Acid)




2) Add AgNO(3) (Silver Nitrate)




This creates a silver halide precipitate.

Ion Tests


After adding the substances to the halide ions, what colour precipitates will be formed with AgCl, AgBr and AgI?

- AgCl: White precipitate




- AgBr: Cream precipitate




- AgI: Yellow precipitate

Ion Tests


What do you do to find suplhate ions?

1) Add HCl




2) Add BaCl(2) (Barium Chloride)




This forms a white precipitate of barium chloride

Classifying Substances


True or false: Ionic compounds dissolve in water

TRUE

Miscible and Immiscible


What do miscible and immiscible mean?

- Miscible: Completely mixes




- Immiscible: Doesn't completely mix

Miscible and Immiscible


Give an example of a miscible substance.

Ethanol

Miscible and Immiscible


Give an example of an immiscible substance and explain why it is immiscible in water.

- Oil




- Water is electronegative, so it attracts ions and electrons. Oil isn't attracted to it so it doesn't mix

Miscible and Immiscible


List 7 ways of separating mixtures

- Distillation


- Fractional distillation


- Filtering


- Centrifuge


- Evaporation


- Chromatography


- Separating funnel

Miscible and Immiscible


True or false: distillation and separating funnels both separate miscible substances.

FALSE




Distillation separates miscible substances




Separating funnels separate immiscible substances

Miscible and Immiscible


What do anti-bumping granules do and when might they be used?

- They'd be used in distillation




- There are imperfections in the glass of the round bottom flask, which creates bubbles, so the anti-bumping granules reduce pressure

Miscible and Immiscible


Why does the water separate from the oil in a separation funnel?

The water is denser than the water so it goes to the bottom.

Chromatography


What does chromatography do?

It separates compounds from a mixture

Chromatography


When is chromatography used?



- To separate paint


- Food testing


- To use in criminal investigations e.g. car paint

Chromatography


Which things affect how far the compounds move on the chromatography paper?

- The size/mass of particles




- Solubility

Chromatography


What is the Rf value?

The distance a compound has risen divided by the distance the solvent has risen