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19 Cards in this Set

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Thermochemistry

Relationship between chemicals (matter) and energy (heat)

Energy

Capacity to do work (units of Joules)

Heat

The flow of energy caused by a temperature difference between particles

Thermal energy

Energy associated with the temperature of an object (depends on mass)

Temperature

A measure of thermal energy

Kinetic energy

Energy of motion

Potential energy

Energy associated with the position of an object

Chemical energy

Energy stored in the bonds and intermolecular forces (position of electrons and nuclei)

System

The chemical reaction/process being studied

Surroundings

Everything else/that isn't the system

Enthalpy

Internal energy of a system

Stored in bonds, IMF, rotation/movement

Calorimetry

Measuring the heat/enthalpy of a system

Specific heat

Amount of heat required to raise the temp of 1 gram of a substance by 1 degree (Celcius or Kelvin)

Heat capacity

Heat required to raise the temp of a given quantity of a substance by 1 degree (Celcius or Kelvin)

Enthalpy of Formation

Heat that results when 1 mol of a compound is formed from its elements

Hess's Law

Another method for calculating change in enthalpy of rxn, it says that chemical reactions and thermodynamic properties are additive

Entropy (S)

Measure of disorder

Gibbs free energy: the return

◇G=◇G°+RTlnKc

Gibbs free energy

◇G=◇H-T◇S