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8 Cards in this Set

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Alkenes C=C

Bromine water will turn colourless, from brown, in the presence of the C=C double bond

Chloroalkanes R-Cl

1. Warm sample up with NaOH (this will hydrolyse the chloroalkane and produce Cl- ions)


2. Add nitric acid (this removes any impurities)


3. Add ammoniacal silver nitrate (Tollen’s reagent)


Result: white ppt of AgCl will form

Bromoalkane R-Br

1. Warm with NaOH (this will hydrolyse the bromoalkane to form Br- ions)


2. Add nitric acid (this will remove all impurities)


3. Add ammoniacal silver nitrate (Tollen’s reagent)


Result: a cream ppt of AgBr will form

Iodoalkane R-I

1. Warm with NaOH (to hydrolyse the iodoalkane and form I- ions)


2. Add nitric acid (to remove any impurities)


3. Add ammoniacal silver nitrate (Tollen’s reagent)


Result: a yellow ppt of AgI will form

Alcohol R-OH

Add K2Cr2O7 to the sample and warm it up.


If the mixture changes colours from orange to green, a primary or secondary alcohol is present and was oxidised.

Aldehyde R-CHO

Add Tollen’s reagent.


If a silver mirror forms then it is an aldehyde. If not, it’s a ketone.


Alternatively add Fehling’s solution and get a brick red ppt with an aldehyde.

Carboxylic Acid R-COOH

Add an aqueous solution of NaHCO3. Carbon dioxide gas is produced and bubbles are seen.

Carbon dioxide CO2

Bubble it through limewater, it will turn cloudy.