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284 Cards in this Set
- Front
- Back
Absolute zero
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zero on the Kelvin scale
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accepted value
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the correct value based on reliable references
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accuracy
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how close a measurement comes to the actual value
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atom
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the smallest particle of an element that retains the properties of the element
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atomic number
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equals the number of protons. never changes. on the bottom if you are writing the element.
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Bohr model
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the older model of the atom. Where the electrons travel in a definite orbit around the nucleus.
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Celsius scale
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a measure of temperature, where the freezing point is 0 and the boiling point is 100.
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chemical change
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implies that a substance has decomposed into a new substance or has been mixed with another chemical to form a new substance.
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chemical property
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the ability of a substance to undergo a chemical reaction and from new substances.
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chemical reaction
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one or more substances change into new substances.
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chemistry
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the study of the composition of matter and the changes it undergoes.
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compound
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substances that can be separated into simpler substances only by chemical means
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density
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the ratio of the mass of an object to its volume
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electron
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negatively charged subatomic particles, in clouds around the nucleus, mass is negligible compared to the nucleus.
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element
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the simplest forms of matter that can exist under normal laboratory conditions.
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error
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the difference between the accepted value and the experimental value.
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experimental value
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the value measured in lab.
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temperture
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the measure of the average kinetic energy of a substance
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gas
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a form of matter that takes both the shape and volume of its container.
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group
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each vertical column of elements in the periodic table.
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heterogeneous
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a mixture that is not uniform in composition. It doesn't have just one part, it would be easy to take it apart.
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homogeneous
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a mixture that has a completely uniform composition. It would be difficult to take apart.
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hypothesis
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a proposed explanation or reason for your observation.
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isotope
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atoms that have the same number of protons, but different number of neutrons.
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Kelvin scale
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the absolute scale for temperature. 0 is is absolute zero.
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Law of Conservation of Mass
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states that in any physical change or chemical reaction, mass is neither created nor destroyed.
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liquid
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a form of matter that flows, has a fixed volume, but not shape, and takes the shape of the container its in.
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mass
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the amount of matter in an object
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mass number
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protons + neutrons. on top if you are writing the element symbol. also called the atomic mass
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mattter
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anything that has mass and takes up space.
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metal
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have a high electrical conductivity and a high luster when clean, they are malleable and ductile
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metalloid
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elements with properties that are intermediate between those of metals and nonmetals
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mixture
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a physical blend of two or more substances
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neutron
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subatomic particles with no charge, in the nucleus
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nonmetal
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elements that are generally nonlusterous and poor conductors of electricity
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observation
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using senses to obtain information directly
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percent error
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the absolute value of the accepted value minus the experimental value, divided by the accepted value, times by 100. written as a percent. (|acc-exp|/acc)x100
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period
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the horizontal rows of the periodic table
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physical change
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implies that no new substance is formed
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physical property
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a quality or condition of a substance that can be observed or measured without changing the substances composition
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precision
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how close measurements are to one another
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product
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the substances formed from a chemical reaction.
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proton
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positively charged, located in the nucleus, have a mass of one amu.
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qualitative measurement
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results that are descriptive without using numbers.
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quantitative measurement
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results that use numbers and units to describe the measurement.
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quantum model
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new model of an atom that states the probability of finding an electron in certain spot.
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reactant
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the starting substances in a chemical reaction.
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scientific notation
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a number written as the product of two numbers, the second being 10 raised to a power because the number is so large.
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significant figures
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all the digits that can be known precisely in a measurement, plus a last estimated digit
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solid
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matter that has a definite shape and volume
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strong force
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when subatomic particles are so very close together that they start to attract. they override repulsion forces.
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vapor
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describes the gaseous state of a substance that is generally liquid at room temperature
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weight
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a force that measure the pull on a given mass by gravity
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volume
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the amount of matter an object takes up
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nuclear reactions
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when changes occur in the atom's nucleus. produce alpha, beta and gamma radiation
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energy level
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around the nucleus where the electron is found. 7 of them right now
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quantum
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the amount of energy required to move an electron from its present level of energy to the next higher one.
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quantum mechanical model
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the modern description of the electrons in atoms, which uses a mathematical equation to describe the location and energy of an electron.
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atomic orbitals
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the region in which electrons are likely to be found in an atom.
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electron configurations
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shows where and how electrons are located around the nucleus.
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Aufbau principle
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electrons enter orbitals of lowest energy first
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Pauli Exclusion Principle
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an atomic orbital can have a maximum of 2 electrons
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Hund's Rule
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when electrons occupy orbitals of equal energy, one electron enters each orbital until all the orbitals contain one electron with parallel spins
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Eletromagnetc Radiation
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light
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amplitude
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from the midpoint to the crest of a wave
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wavelength
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from crest to crest
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Heisenberg's Uncertainty Principle
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states that its impossible to know exactly both the velocity and the position of a particle at the same time.
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frequency
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the number of wave cycles to pass a given point per unit of time.
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hertz
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the SI unit o f cycles per second. Hz. sec^-1 or 1/sec
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spectrum
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the different wavelengths of color when sunlight passes through a prism.
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atomic emission spectrum
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when an electric discharge goes through a gas or vapor, the element absorbs energy, then loses it as light. is unique to each element, consist of specific lines, which correspond to a different amount of energy, used to identify elements
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Planck's constant
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the constant (h) in the energy of a quantum (h*v)
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photons
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light quanta that behaves like particles
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photoelectric effect
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when the intensity of photons of the light is strong enough, electrons are ejected from the metal.
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ground state
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the lowest energy level of an element's atom.
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de Broglies equation
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predicts that all matter exhibits wavelike motions
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atomic radius
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one half the distance between the nuclei of two like atoms in a diatomic molecule
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ionization energy
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the energy required to overcome the attraction of the nuclear charge and remove an electron from a gaseous atoms
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electronegativity
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the tendency for the atoms of the element to attract electrons when they are chemically combined with atoms of another element.
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electron affinity
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the energy given off when a neutral atom in gas phase gains an extra electron to form a negatively charged ion.
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valence electron
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the electrons in the highest occupied energy level of an elements atom.
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periodic table
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an arrangement of the elements according to similarities in their properties
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periodic law
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when the elements are arranged in order of increasing atomic number, there is a periodic repetition of their physical and chemical properties
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groups
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columns on the periodic table
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families
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the columns that have certain names on the periodic table. ex: alkali metals
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periods
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rows on the periodic table
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Alkali metals
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1A elements
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alkaline earth metals
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2A elements
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halogens
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7A elements
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noble gases
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8A elements
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transition metals
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1B-10B elements
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inner transition metals
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lanthanides and actinides
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metals
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solid, high conductivity of heat and electricity, left side of the periodic table, malleable, ductile
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nonmetals
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solids, liquids, or gases; poor conductors, nonmalleable, nonductile, right side of periodic table.
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metalloids
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semi-conductors--Si based computer chips; right side of periodic table
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lanthanides
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inner transition metals, 6 period
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actinides
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inner transition metals, 7 period
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ductile
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the ability to be drawn into wires
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malleable
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the ability to be hammered or forced into shapes
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activity
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the ease with which a metal reacts
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solubility
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the amount that dissolves in a given quantity of a solvent at a given temperature to produce a saturated solution
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precipitate
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when a solid forms from a reaction
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acid
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a compound that produces hydrogen ions in solution, a hydrogen-ion donor, or an electron-pair acceptor
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alloy
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mixture composed of two or more elements, at least one of which is a metal
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anion
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any atom or gorup of atoms with negative charge
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binary compound
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compound composed of two different elements
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cation
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positive charged ions
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chemical formula
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shows the kinds and numbers of atoms in the smallest representative unit of the substance
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covalent bond
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a bond in which tow atoms share a pair of electrons
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diatomic molecule
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elements that are present in the gaseous state as molecules composed of tow atoms when they are by themselves
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double bond
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covalent bonds that share two pairs of electrons
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formula unit
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the lowest whole-number ratio of ions in an ionic compound
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ion
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atoms or groups of atoms that have a positive or negative charge
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ionic bond
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formed when there is a transfer of electrons to the more electronegative atom
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ionic compound
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compounds composed of cations and anions
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law of definite proportions
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states that in samples of any chemical compound, the masses of the elements are always in the same proportions
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law of multiple proportions
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whenever two elements form more than one compound, the different masses of one element that combine with the same mass of the other element are in the ratio of small whole numbers
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lewis dot structure
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diagrams that show valence electrons as dots
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metallic bond
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why metals conduct electricity, tend to form crystals, bonding in metals
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molecular compounds
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composed of two or more nonmetals. uses prefixes
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molecular formula
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shows the kinds and numbers of atoms present in a molecule of a compound
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molecule
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smallest electrically neutral unit of a substance that still has the properties of that substance
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monatomic ion
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ions consisting of only one element
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octet rule
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in forming compounds, atoms tend to achieve the electron configuration of a noble gas
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polarity
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when a covalent bond joins two atoms of different elements and the bonding electrons are shared unequally.
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polyatomic ion
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element composed of many atoms
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resonance
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when electron pairs rapidly flip back and forth
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ternary compound
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compounds of 3 elements
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triple bond
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covalent bonds that involve three shared pairs of electrons
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VSEPR
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states that because electron pairs repel, molecular shape adjusts so the valence electron pairs are as far apart as possible
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empirical formula
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the lowest whole-number ratio of the atoms of the elements in a compound
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molecular formula
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shows the kinds and numbers of atoms present in a molecule of a compound
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activity series of metals
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lists metals in order of decreasing activity. determines whether one metal will replace another metal in a single replacement reaction
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aqueous
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dissolved in water
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balanced equation
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each side of the equation has the same number of atoms of each element
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catalyst
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a substance that increases the rate of a reaction without being used up itself during the reaction
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chemical equation
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an equation that represents a chemical reaction, where the reactants and products are connected with an arrow
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coefficient
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numbers placed in front of the symbols for the respective parts of a balanced equation
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combination reaction
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2 or more reactants combine to form one product.
A+B=AB |
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combustion reaction
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burning in the presence of oxygen
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complete ionic equation
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represent soluble ionic compounds as separated ions
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covalent bond
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a bond in which tow atoms share a pair of electrons
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decomposition reaction
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one reactant breaks down into two ore more products.
can be explosive. |
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dissociate
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the breaking down of a compound into its components
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double replacement reaction
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exchange of cations.
AB+CD=CB+AD |
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ionic bond
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the forces of attraction that bind cations and anions
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metallic bond
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the attraction of valence electrons towards positively charged meal ions
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net ionic equation
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the equation that indicates only those particles that actually take part in the reaction
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octet rule
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in the formation of compounds atoms tend to achieve the configuration of a noble gas.
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precipitate
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when a solid forms from a reaction
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spectator ion
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ions that are not directly involved in a reaction
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single replacement reaction
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one element replaces another element in a compound.
A+BC=AC+B |
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mole (mol)
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equals 6.02x(10^24)
we use this because atoms are so small, we need a way to quantize large quantities |
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Avagadro's number
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6.02*10^24
the number of representative particles contained in one mole. |
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representative particles
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the species present in a substance, usually atoms, molecules, or formula units (ions)
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gram atomic mass
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the atomic mass of an element expressed in grams (gam)
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gram molecular mass
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mass of 1 mole of that compound (gmm)
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gram formula mass
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the mass of one mole of an ionic compound (gfm)
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molar mass
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the mass in grams of any one mole of the substance.
use the periodic table to find this with the atomic mass |
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STP
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standard temperature and pressure.
the condition at which the volume of a gas is measured. T=0 C P=1 atm |
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molar volume
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1 mole of gas' volume at STP
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percent composition
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the relative amounts of each element in a compound.
percent by mass of each element in the compound |
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thermochemistry
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concerned with the heat changes that occur during chemical reactions
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energy
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the capacity for doing work or supplying heat
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chemical potential energy
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energy stored within the structural units of chemical substances
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heat
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the flow of energy from a warmer object to a colder one (q)
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system
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is the reaction in a calorimeter. the part of the universe on which you focus your attention
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surroundings
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is the water in a calorimeter. the remainder of the universe that is outside the system.
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law of conservation of energy
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states that in any chemical or physical process, energy is neither created or destroyed
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endothermic process
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absorbs heat. feels cold.
change in enthalpy is positive |
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exothermic process
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releasing heat. feels warm. change in enthalpy is negative
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calorie
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the amount of heat required to raise the temperature of 1 gram of pure water 1 degree C
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Joule
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the SI unit of heat and energy. 4.184= 1 cal.
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heat capacity
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amount of heat needed to raise the temperature of an object exactly 1 degree C. depends on mass and chemical composition of an object
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specific heat capacity
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the amount of heat it takes to raise the temperature of 1 gram of the substance 1 degree C.
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specific heat
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the amount of heat needed to raise the temperature of 1 gram of a substance 1 degree C.
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calorimetry
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accurate and precise measurement of heat change for chemical and physical processes.
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calorimeter
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the insulated device used to measure the absorption or release of heat in chemical or physical properties
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enthalpy (H)
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heat content at constant pressure
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thermochemical equation
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a chemical equation that includes the amount of heat produced or absorbed during the reaction.
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heat of reaction
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the heat change from the reaction exactly as it is written
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heat of combustion
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the heat of reaction for the complete burning of one mole of a substance
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molar heat of fusion
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the heat absorbed by one mole of a substance in melting from a solid to a liquid at a constant temperature
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molar heat of solidification
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the heat lost when one mole of a liquid solidifies at a constant temperature
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molar heat of vaporization
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the amount of heat necessary to vaporize one mole of a given liquid
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molar heat of condensation
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the amount of heat released when one mole of vapor condenses
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molar heat of solution
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the heat change caused by dissolution of one mole of substance
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Hess's law of heat summation
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if a series of reactions are added together the enthalpy change for the net reaction will be the sum of the enthalpy changes for the individual steps.
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standard heat of formation
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the change in enthalpy that accompanies the formation of one mole of a compound from its elements with all substances in their standard states at 25 degrees C.
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universe
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the totality of all existing things. the system and the surroundings
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Avagadro's hypothesis
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the number of mols of a gas is directly related to the volume of the gas
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Dalton's Law of Partial Pressures
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at constant volume and temperature, the total pressure exerted by a mixture of gases is equal to the sum of the partial pressures of the component gases
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gases
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take the volume of their container, compressible, diffusion occurs quickly, flows readily, few intermolecular forces
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liquids
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diffusion occurs slowly, strong intermolecular forces, take the form of their container,flow, fixed volume, and no definite shape
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solids
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definite shape and volume, virtually incompressible, doesn't flow, diffusion occurs slowly, strong intermolecular forces.
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condenses states of matter
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the liquid and solid phases, in which the particles interact strongly
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intermolecular forces
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forces between individual molecules of a substance
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boiling point
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the temperature at which the vapor pressure of a liquid is equal to the applied external pressure
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melting point
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the temperature at which a substance changes from a solid to a liquid.
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ion-dipole force
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intermolecular forces exist between an ion and the partial charge on the end of a polar molecule
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dipole-dipole force
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a separation of charge on a molecule- think electronegativity
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London dispersion force
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the weakest of all molecular interactions, are caused by electron motion
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Hydrogen bonding
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strongest intermolecular force, only occurs when H is bonded to F,O, or N. weaker than chemical bonds.
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viscosity
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an internal ability of a fluid that has resistance to flow.
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surface tension
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the imbalance of forces at the surface of a liquid
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cohesive force
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all the forces of attraction among particles of a liquid
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adhesive force
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attractions between a liquid and another surface.
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capillary action
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when adhesive forces overcome cohesive forces, a liquid is drawn up inside a small-bore tube
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condensation
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vapor or gas to liquid
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sublimation
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solid to gas
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melting
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solid to liquid
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evaporation
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vaporization that occurs at the surface of a liquid.
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deposition
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gas to solid
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freezing
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liquid to solid
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critical temperature
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the temperature of a pure element or compound at a critical point
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critical pressure
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the pressure of a pure element or compound at a critical point
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vapor pressure
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force due to the gas above the liquid
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volatile
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rapid evaporation. passing off readily in the form of vapor
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normal boiling point
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the boiling point of a liquid at a pressure of 101.3 kPa
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phase diagram
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a graphical way to summarize the conditions under which equilbria exist between the different states of matter.
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normal melting point
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the melting point of a substance at 1.0 atm.
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triple point
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where 3 curves on a phase diagram meet.
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crystalline solid
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have an orderly arrangement of their component ions
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unit cell
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the smallest group of particles within a crystal that retains the geometric shape of the crystal.
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crystal lattice
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a repeating array of any one of fourteen kinds of unit cells
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amorphous solid
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solids that lack an ordered internal structure.
randomly arranged |
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metallic solids
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good conductors, malleable, ductile.
a solid that has properties of a metal. positive ions surrounded by many mobile valence electrons |
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molecular solids
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a substance that consists of individual molecules held together in the solid by relatively weak intermolecular bonds. low melting points, don't conduct well
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ionic solids
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have high melting points because strong forces hold them together. oppositely charged ions attract each other.
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covalent-network solid
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substance which consists of an array of atoms held together by an array of covalent bonds without forming molecules
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dipole moment
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a separating of charge on a molecule
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polar molecule
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a molecule with a nonzero dipole moment
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pressure
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the force exerted per unit area
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ideal gas law
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PV=nRT
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kinetic molecular theory
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6 postulates that describe how an ideal gas behaves. 3 are assumptions that technically aren't true about real pressures. most behave like ideal gases at normal temp. and pressure
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real gas
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don't follow the kinetic molecular theory at certain temperatures and pressures
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charle's law
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states that the volume of a fixed mass of a gas is directly proportional to its temperature if the pressure is kept constant and the number of mols are held constant.
V/T=V/T |
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boyle's law
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states that for a given mass of gas a constant temperature, the volume of the gas varies inversely with pressure, when the number of moles is held constant.
PV=PV |
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vapor
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describes the gaseous state of a substance that is generally a liquid or solid at room temperature
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partial pressure
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the pressure exerted by each gas in a gaseous mixture.
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monometer
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device used to determine the vapor pressure of a liquid.
can be closed or open ended |
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gas constant
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8.134 joules per degree Kelvin. equal to the product of the pressure and the volume of one gram molecule of an ideal gas divided by the absolute temperature.
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boiling point elevation
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the difference in temperature between the boiling point of a solution and of the pure solution
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colligative property
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depends not on the kind, but the amount of solute particles
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concentrated solution
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a solution containing a large amount of solute
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concentration
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a measurement of the amount of solute that is dissolved in a gram quantity of solvent; usually expressed in mol/L
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dilute solution
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solution that contains a small amount of solute
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freezing point depression
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the difference in temperature between the freezing point of a solution and of the pure solvent
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Henry's Law
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solubility of a gas is proportional to the partial pressure of the gas above the liquids.
ex: soda pop |
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immiscible
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liquids that can't mix in any proportion
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miscible
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liquid solutions that can mix in any solution
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molar boiling point elevation constant
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the change in boiling point for a 1 molol solution of a nonvolatile molecular solute.
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molar freezing point depression constant
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the change in freezing point for a 1 molol solution of a nonvolatile molecular solute
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molality
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moles of solute dived by kg of solvent
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molarity
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moles of solute dived by L of solution
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mole fraction
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moles of component divided by the total moles of the solution
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saturated solution
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when no more solute can be dissolved in a solution
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solubility
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how much of a solute will dissolve in a solvent at a certain temperature
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solute
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the substance that is dissolved
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solution
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a homogeneous mixture of tow or more substances in a single physical state
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solvent
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the substance that does the dissolving
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supersaturated solution
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solution that contains more solute than can be dissolved
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unsaturated
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solution that has less solute than can be dissolved
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acid
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a compound that produces hydrogen ions in solution, a hydrogen-ion donor, or electron-pair acceptor
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base
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a compound that produces hydroxide ions in solution, hydrogen-ion acceptor, or electron-pair donor
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hydroxide ion
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(OH^-) the negative ion formed when a water molecule loses a hydrogen ion.
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hydranium ion
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(H30^+) the positive ion formed when a water molecule gains a hydrogen ion
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neutral solution
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an aqueous solution in which the concentrations of hydrogen and hydroxide ions are equal.
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acidic solution
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any solution in which the hydrogen ion concentration is greater than the hydroxide-ion concentration
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basic solution
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any solution in which the hydroxide-ion concentration is greater than the hydrogen-ion concentration
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alkaline solutions
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another name for basic solutions
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pH
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measures the acidity of a solution
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monoprotic
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any acid that contains one ionizable proton
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diprotic
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any acid that contains two ionizable protons
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triprotic
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any acid that contains three ionizable protons
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conjugate acid
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the particle formed when a base gains a hydrogen ion
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conjugate base
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the particle that remains when an acid has donated a hydrogen ion
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lewis acid
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any substance that can accept a pair of electrons to form a covalent bond.
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lewis base
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any substance that can donate a pair of electrons to form a covalent bond
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amphoteric
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a substance that can act as both acid and base
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strong acid
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an acid that is completely ionized in aqueous solutions
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weak acid
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an acid that is only slightly ionized in aqueous solution.
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strong base
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a bas that completely dissociates into metal ions and hydroxide ions in aqueous solution.
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weak base
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a base that does not dissociate completely in aqueous solution
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