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284 Cards in this Set

  • Front
  • Back
Absolute zero
zero on the Kelvin scale
accepted value
the correct value based on reliable references
accuracy
how close a measurement comes to the actual value
atom
the smallest particle of an element that retains the properties of the element
atomic number
equals the number of protons. never changes. on the bottom if you are writing the element.
Bohr model
the older model of the atom. Where the electrons travel in a definite orbit around the nucleus.
Celsius scale
a measure of temperature, where the freezing point is 0 and the boiling point is 100.
chemical change
implies that a substance has decomposed into a new substance or has been mixed with another chemical to form a new substance.
chemical property
the ability of a substance to undergo a chemical reaction and from new substances.
chemical reaction
one or more substances change into new substances.
chemistry
the study of the composition of matter and the changes it undergoes.
compound
substances that can be separated into simpler substances only by chemical means
density
the ratio of the mass of an object to its volume
electron
negatively charged subatomic particles, in clouds around the nucleus, mass is negligible compared to the nucleus.
element
the simplest forms of matter that can exist under normal laboratory conditions.
error
the difference between the accepted value and the experimental value.
experimental value
the value measured in lab.
temperture
the measure of the average kinetic energy of a substance
gas
a form of matter that takes both the shape and volume of its container.
group
each vertical column of elements in the periodic table.
heterogeneous
a mixture that is not uniform in composition. It doesn't have just one part, it would be easy to take it apart.
homogeneous
a mixture that has a completely uniform composition. It would be difficult to take apart.
hypothesis
a proposed explanation or reason for your observation.
isotope
atoms that have the same number of protons, but different number of neutrons.
Kelvin scale
the absolute scale for temperature. 0 is is absolute zero.
Law of Conservation of Mass
states that in any physical change or chemical reaction, mass is neither created nor destroyed.
liquid
a form of matter that flows, has a fixed volume, but not shape, and takes the shape of the container its in.
mass
the amount of matter in an object
mass number
protons + neutrons. on top if you are writing the element symbol. also called the atomic mass
mattter
anything that has mass and takes up space.
metal
have a high electrical conductivity and a high luster when clean, they are malleable and ductile
metalloid
elements with properties that are intermediate between those of metals and nonmetals
mixture
a physical blend of two or more substances
neutron
subatomic particles with no charge, in the nucleus
nonmetal
elements that are generally nonlusterous and poor conductors of electricity
observation
using senses to obtain information directly
percent error
the absolute value of the accepted value minus the experimental value, divided by the accepted value, times by 100. written as a percent. (|acc-exp|/acc)x100
period
the horizontal rows of the periodic table
physical change
implies that no new substance is formed
physical property
a quality or condition of a substance that can be observed or measured without changing the substances composition
precision
how close measurements are to one another
product
the substances formed from a chemical reaction.
proton
positively charged, located in the nucleus, have a mass of one amu.
qualitative measurement
results that are descriptive without using numbers.
quantitative measurement
results that use numbers and units to describe the measurement.
quantum model
new model of an atom that states the probability of finding an electron in certain spot.
reactant
the starting substances in a chemical reaction.
scientific notation
a number written as the product of two numbers, the second being 10 raised to a power because the number is so large.
significant figures
all the digits that can be known precisely in a measurement, plus a last estimated digit
solid
matter that has a definite shape and volume
strong force
when subatomic particles are so very close together that they start to attract. they override repulsion forces.
vapor
describes the gaseous state of a substance that is generally liquid at room temperature
weight
a force that measure the pull on a given mass by gravity
volume
the amount of matter an object takes up
nuclear reactions
when changes occur in the atom's nucleus. produce alpha, beta and gamma radiation
energy level
around the nucleus where the electron is found. 7 of them right now
quantum
the amount of energy required to move an electron from its present level of energy to the next higher one.
quantum mechanical model
the modern description of the electrons in atoms, which uses a mathematical equation to describe the location and energy of an electron.
atomic orbitals
the region in which electrons are likely to be found in an atom.
electron configurations
shows where and how electrons are located around the nucleus.
Aufbau principle
electrons enter orbitals of lowest energy first
Pauli Exclusion Principle
an atomic orbital can have a maximum of 2 electrons
Hund's Rule
when electrons occupy orbitals of equal energy, one electron enters each orbital until all the orbitals contain one electron with parallel spins
Eletromagnetc Radiation
light
amplitude
from the midpoint to the crest of a wave
wavelength
from crest to crest
Heisenberg's Uncertainty Principle
states that its impossible to know exactly both the velocity and the position of a particle at the same time.
frequency
the number of wave cycles to pass a given point per unit of time.
hertz
the SI unit o f cycles per second. Hz. sec^-1 or 1/sec
spectrum
the different wavelengths of color when sunlight passes through a prism.
atomic emission spectrum
when an electric discharge goes through a gas or vapor, the element absorbs energy, then loses it as light. is unique to each element, consist of specific lines, which correspond to a different amount of energy, used to identify elements
Planck's constant
the constant (h) in the energy of a quantum (h*v)
photons
light quanta that behaves like particles
photoelectric effect
when the intensity of photons of the light is strong enough, electrons are ejected from the metal.
ground state
the lowest energy level of an element's atom.
de Broglies equation
predicts that all matter exhibits wavelike motions
atomic radius
one half the distance between the nuclei of two like atoms in a diatomic molecule
ionization energy
the energy required to overcome the attraction of the nuclear charge and remove an electron from a gaseous atoms
electronegativity
the tendency for the atoms of the element to attract electrons when they are chemically combined with atoms of another element.
electron affinity
the energy given off when a neutral atom in gas phase gains an extra electron to form a negatively charged ion.
valence electron
the electrons in the highest occupied energy level of an elements atom.
periodic table
an arrangement of the elements according to similarities in their properties
periodic law
when the elements are arranged in order of increasing atomic number, there is a periodic repetition of their physical and chemical properties
groups
columns on the periodic table
families
the columns that have certain names on the periodic table. ex: alkali metals
periods
rows on the periodic table
Alkali metals
1A elements
alkaline earth metals
2A elements
halogens
7A elements
noble gases
8A elements
transition metals
1B-10B elements
inner transition metals
lanthanides and actinides
metals
solid, high conductivity of heat and electricity, left side of the periodic table, malleable, ductile
nonmetals
solids, liquids, or gases; poor conductors, nonmalleable, nonductile, right side of periodic table.
metalloids
semi-conductors--Si based computer chips; right side of periodic table
lanthanides
inner transition metals, 6 period
actinides
inner transition metals, 7 period
ductile
the ability to be drawn into wires
malleable
the ability to be hammered or forced into shapes
activity
the ease with which a metal reacts
solubility
the amount that dissolves in a given quantity of a solvent at a given temperature to produce a saturated solution
precipitate
when a solid forms from a reaction
acid
a compound that produces hydrogen ions in solution, a hydrogen-ion donor, or an electron-pair acceptor
alloy
mixture composed of two or more elements, at least one of which is a metal
anion
any atom or gorup of atoms with negative charge
binary compound
compound composed of two different elements
cation
positive charged ions
chemical formula
shows the kinds and numbers of atoms in the smallest representative unit of the substance
covalent bond
a bond in which tow atoms share a pair of electrons
diatomic molecule
elements that are present in the gaseous state as molecules composed of tow atoms when they are by themselves
double bond
covalent bonds that share two pairs of electrons
formula unit
the lowest whole-number ratio of ions in an ionic compound
ion
atoms or groups of atoms that have a positive or negative charge
ionic bond
formed when there is a transfer of electrons to the more electronegative atom
ionic compound
compounds composed of cations and anions
law of definite proportions
states that in samples of any chemical compound, the masses of the elements are always in the same proportions
law of multiple proportions
whenever two elements form more than one compound, the different masses of one element that combine with the same mass of the other element are in the ratio of small whole numbers
lewis dot structure
diagrams that show valence electrons as dots
metallic bond
why metals conduct electricity, tend to form crystals, bonding in metals
molecular compounds
composed of two or more nonmetals. uses prefixes
molecular formula
shows the kinds and numbers of atoms present in a molecule of a compound
molecule
smallest electrically neutral unit of a substance that still has the properties of that substance
monatomic ion
ions consisting of only one element
octet rule
in forming compounds, atoms tend to achieve the electron configuration of a noble gas
polarity
when a covalent bond joins two atoms of different elements and the bonding electrons are shared unequally.
polyatomic ion
element composed of many atoms
resonance
when electron pairs rapidly flip back and forth
ternary compound
compounds of 3 elements
triple bond
covalent bonds that involve three shared pairs of electrons
VSEPR
states that because electron pairs repel, molecular shape adjusts so the valence electron pairs are as far apart as possible
empirical formula
the lowest whole-number ratio of the atoms of the elements in a compound
molecular formula
shows the kinds and numbers of atoms present in a molecule of a compound
activity series of metals
lists metals in order of decreasing activity. determines whether one metal will replace another metal in a single replacement reaction
aqueous
dissolved in water
balanced equation
each side of the equation has the same number of atoms of each element
catalyst
a substance that increases the rate of a reaction without being used up itself during the reaction
chemical equation
an equation that represents a chemical reaction, where the reactants and products are connected with an arrow
coefficient
numbers placed in front of the symbols for the respective parts of a balanced equation
combination reaction
2 or more reactants combine to form one product.
A+B=AB
combustion reaction
burning in the presence of oxygen
complete ionic equation
represent soluble ionic compounds as separated ions
covalent bond
a bond in which tow atoms share a pair of electrons
decomposition reaction
one reactant breaks down into two ore more products.
can be explosive.
dissociate
the breaking down of a compound into its components
double replacement reaction
exchange of cations.
AB+CD=CB+AD
ionic bond
the forces of attraction that bind cations and anions
metallic bond
the attraction of valence electrons towards positively charged meal ions
net ionic equation
the equation that indicates only those particles that actually take part in the reaction
octet rule
in the formation of compounds atoms tend to achieve the configuration of a noble gas.
precipitate
when a solid forms from a reaction
spectator ion
ions that are not directly involved in a reaction
single replacement reaction
one element replaces another element in a compound.
A+BC=AC+B
mole (mol)
equals 6.02x(10^24)
we use this because atoms are so small, we need a way to quantize large quantities
Avagadro's number
6.02*10^24
the number of representative particles contained in one mole.
representative particles
the species present in a substance, usually atoms, molecules, or formula units (ions)
gram atomic mass
the atomic mass of an element expressed in grams (gam)
gram molecular mass
mass of 1 mole of that compound (gmm)
gram formula mass
the mass of one mole of an ionic compound (gfm)
molar mass
the mass in grams of any one mole of the substance.
use the periodic table to find this with the atomic mass
STP
standard temperature and pressure.
the condition at which the volume of a gas is measured.
T=0 C
P=1 atm
molar volume
1 mole of gas' volume at STP
percent composition
the relative amounts of each element in a compound.
percent by mass of each element in the compound
thermochemistry
concerned with the heat changes that occur during chemical reactions
energy
the capacity for doing work or supplying heat
chemical potential energy
energy stored within the structural units of chemical substances
heat
the flow of energy from a warmer object to a colder one (q)
system
is the reaction in a calorimeter. the part of the universe on which you focus your attention
surroundings
is the water in a calorimeter. the remainder of the universe that is outside the system.
law of conservation of energy
states that in any chemical or physical process, energy is neither created or destroyed
endothermic process
absorbs heat. feels cold.
change in enthalpy is positive
exothermic process
releasing heat. feels warm. change in enthalpy is negative
calorie
the amount of heat required to raise the temperature of 1 gram of pure water 1 degree C
Joule
the SI unit of heat and energy. 4.184= 1 cal.
heat capacity
amount of heat needed to raise the temperature of an object exactly 1 degree C. depends on mass and chemical composition of an object
specific heat capacity
the amount of heat it takes to raise the temperature of 1 gram of the substance 1 degree C.
specific heat
the amount of heat needed to raise the temperature of 1 gram of a substance 1 degree C.
calorimetry
accurate and precise measurement of heat change for chemical and physical processes.
calorimeter
the insulated device used to measure the absorption or release of heat in chemical or physical properties
enthalpy (H)
heat content at constant pressure
thermochemical equation
a chemical equation that includes the amount of heat produced or absorbed during the reaction.
heat of reaction
the heat change from the reaction exactly as it is written
heat of combustion
the heat of reaction for the complete burning of one mole of a substance
molar heat of fusion
the heat absorbed by one mole of a substance in melting from a solid to a liquid at a constant temperature
molar heat of solidification
the heat lost when one mole of a liquid solidifies at a constant temperature
molar heat of vaporization
the amount of heat necessary to vaporize one mole of a given liquid
molar heat of condensation
the amount of heat released when one mole of vapor condenses
molar heat of solution
the heat change caused by dissolution of one mole of substance
Hess's law of heat summation
if a series of reactions are added together the enthalpy change for the net reaction will be the sum of the enthalpy changes for the individual steps.
standard heat of formation
the change in enthalpy that accompanies the formation of one mole of a compound from its elements with all substances in their standard states at 25 degrees C.
universe
the totality of all existing things. the system and the surroundings
Avagadro's hypothesis
the number of mols of a gas is directly related to the volume of the gas
Dalton's Law of Partial Pressures
at constant volume and temperature, the total pressure exerted by a mixture of gases is equal to the sum of the partial pressures of the component gases
gases
take the volume of their container, compressible, diffusion occurs quickly, flows readily, few intermolecular forces
liquids
diffusion occurs slowly, strong intermolecular forces, take the form of their container,flow, fixed volume, and no definite shape
solids
definite shape and volume, virtually incompressible, doesn't flow, diffusion occurs slowly, strong intermolecular forces.
condenses states of matter
the liquid and solid phases, in which the particles interact strongly
intermolecular forces
forces between individual molecules of a substance
boiling point
the temperature at which the vapor pressure of a liquid is equal to the applied external pressure
melting point
the temperature at which a substance changes from a solid to a liquid.
ion-dipole force
intermolecular forces exist between an ion and the partial charge on the end of a polar molecule
dipole-dipole force
a separation of charge on a molecule- think electronegativity
London dispersion force
the weakest of all molecular interactions, are caused by electron motion
Hydrogen bonding
strongest intermolecular force, only occurs when H is bonded to F,O, or N. weaker than chemical bonds.
viscosity
an internal ability of a fluid that has resistance to flow.
surface tension
the imbalance of forces at the surface of a liquid
cohesive force
all the forces of attraction among particles of a liquid
adhesive force
attractions between a liquid and another surface.
capillary action
when adhesive forces overcome cohesive forces, a liquid is drawn up inside a small-bore tube
condensation
vapor or gas to liquid
sublimation
solid to gas
melting
solid to liquid
evaporation
vaporization that occurs at the surface of a liquid.
deposition
gas to solid
freezing
liquid to solid
critical temperature
the temperature of a pure element or compound at a critical point
critical pressure
the pressure of a pure element or compound at a critical point
vapor pressure
force due to the gas above the liquid
volatile
rapid evaporation. passing off readily in the form of vapor
normal boiling point
the boiling point of a liquid at a pressure of 101.3 kPa
phase diagram
a graphical way to summarize the conditions under which equilbria exist between the different states of matter.
normal melting point
the melting point of a substance at 1.0 atm.
triple point
where 3 curves on a phase diagram meet.
crystalline solid
have an orderly arrangement of their component ions
unit cell
the smallest group of particles within a crystal that retains the geometric shape of the crystal.
crystal lattice
a repeating array of any one of fourteen kinds of unit cells
amorphous solid
solids that lack an ordered internal structure.
randomly arranged
metallic solids
good conductors, malleable, ductile.
a solid that has properties of a metal. positive ions surrounded by many mobile valence electrons
molecular solids
a substance that consists of individual molecules held together in the solid by relatively weak intermolecular bonds. low melting points, don't conduct well
ionic solids
have high melting points because strong forces hold them together. oppositely charged ions attract each other.
covalent-network solid
substance which consists of an array of atoms held together by an array of covalent bonds without forming molecules
dipole moment
a separating of charge on a molecule
polar molecule
a molecule with a nonzero dipole moment
pressure
the force exerted per unit area
ideal gas law
PV=nRT
kinetic molecular theory
6 postulates that describe how an ideal gas behaves. 3 are assumptions that technically aren't true about real pressures. most behave like ideal gases at normal temp. and pressure
real gas
don't follow the kinetic molecular theory at certain temperatures and pressures
charle's law
states that the volume of a fixed mass of a gas is directly proportional to its temperature if the pressure is kept constant and the number of mols are held constant.
V/T=V/T
boyle's law
states that for a given mass of gas a constant temperature, the volume of the gas varies inversely with pressure, when the number of moles is held constant.
PV=PV
vapor
describes the gaseous state of a substance that is generally a liquid or solid at room temperature
partial pressure
the pressure exerted by each gas in a gaseous mixture.
monometer
device used to determine the vapor pressure of a liquid.
can be closed or open ended
gas constant
8.134 joules per degree Kelvin. equal to the product of the pressure and the volume of one gram molecule of an ideal gas divided by the absolute temperature.
boiling point elevation
the difference in temperature between the boiling point of a solution and of the pure solution
colligative property
depends not on the kind, but the amount of solute particles
concentrated solution
a solution containing a large amount of solute
concentration
a measurement of the amount of solute that is dissolved in a gram quantity of solvent; usually expressed in mol/L
dilute solution
solution that contains a small amount of solute
freezing point depression
the difference in temperature between the freezing point of a solution and of the pure solvent
Henry's Law
solubility of a gas is proportional to the partial pressure of the gas above the liquids.
ex: soda pop
immiscible
liquids that can't mix in any proportion
miscible
liquid solutions that can mix in any solution
molar boiling point elevation constant
the change in boiling point for a 1 molol solution of a nonvolatile molecular solute.
molar freezing point depression constant
the change in freezing point for a 1 molol solution of a nonvolatile molecular solute
molality
moles of solute dived by kg of solvent
molarity
moles of solute dived by L of solution
mole fraction
moles of component divided by the total moles of the solution
saturated solution
when no more solute can be dissolved in a solution
solubility
how much of a solute will dissolve in a solvent at a certain temperature
solute
the substance that is dissolved
solution
a homogeneous mixture of tow or more substances in a single physical state
solvent
the substance that does the dissolving
supersaturated solution
solution that contains more solute than can be dissolved
unsaturated
solution that has less solute than can be dissolved
acid
a compound that produces hydrogen ions in solution, a hydrogen-ion donor, or electron-pair acceptor
base
a compound that produces hydroxide ions in solution, hydrogen-ion acceptor, or electron-pair donor
hydroxide ion
(OH^-) the negative ion formed when a water molecule loses a hydrogen ion.
hydranium ion
(H30^+) the positive ion formed when a water molecule gains a hydrogen ion
neutral solution
an aqueous solution in which the concentrations of hydrogen and hydroxide ions are equal.
acidic solution
any solution in which the hydrogen ion concentration is greater than the hydroxide-ion concentration
basic solution
any solution in which the hydroxide-ion concentration is greater than the hydrogen-ion concentration
alkaline solutions
another name for basic solutions
pH
measures the acidity of a solution
monoprotic
any acid that contains one ionizable proton
diprotic
any acid that contains two ionizable protons
triprotic
any acid that contains three ionizable protons
conjugate acid
the particle formed when a base gains a hydrogen ion
conjugate base
the particle that remains when an acid has donated a hydrogen ion
lewis acid
any substance that can accept a pair of electrons to form a covalent bond.
lewis base
any substance that can donate a pair of electrons to form a covalent bond
amphoteric
a substance that can act as both acid and base
strong acid
an acid that is completely ionized in aqueous solutions
weak acid
an acid that is only slightly ionized in aqueous solution.
strong base
a bas that completely dissociates into metal ions and hydroxide ions in aqueous solution.
weak base
a base that does not dissociate completely in aqueous solution