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32 Cards in this Set

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What is the Rydberg equation for the spectral lines of hydrogen?

1/y = 𝑅∞ (1 /𝑛^ 2 −1/𝑚^2)

What is the equation to be able to calculate the energy of a single photon?

𝐸 = ℎv


Einstein’s equation

How do you calculate the energy of a mole of photons? Why is this needed?

By using Avogadro’s constant. (6.022 x 10^23) This is needed because chemists most often report energies in kJ/mol.

What is Schrodinger waveequation?

It is an equation for the orbits of the electrons. There are four quantum numbers that obey specific rules.

What is the Principal quantum number, its value, and meaning?

Principal quantum number = n


Value = Any positive integer


Meaning = Energy level in Hydrogen atom

What is the Angular momentumquantum number, its value, and meaning?

Angular momentumquantum number = l


Value = l = 0 … N-1 in steps of 1


Meaning = Roughly determines number of lobes(actually nodes) in an orbital. 0 = S1 = P2 = D3= F4 = G5 = H… and so on

Give the number of lobes/nodes in an orbital.

0 = S


1 = P


2 = D


3= F


4 = G


5 = H


… and so on

What is the Azimuthal quantum number, its value, and meaning?

Azimuthal quantum number = ml


Value = ml =-l … l in steps of 1


Meaning = Determines the orientation of theorbitals in space such as Px, Py and Pzfor L=1

What is the Spin quantum number, its value, and meaning?

Spin quantum number = ms


Value = +½ or -½


Meaning = Spin on the electron

What is the Pauli-Exclusion principle?

It states that no two electrons may have the same set of quantum numbers. This basically limits each orbital to holding just two electrons.

What is Hund’s rule?

It states that if several orbitals are degenerate (have the same energy) then nature will first put one electron in each orbital before it total fills any one of them.

How many different types of bonds are there? Name them.

1. Ionic


2. Covalent


3. Polar Covalent

Define ionic bonds.

the electronegativity difference is so great that one atom rips the electron off theother to form ions. These ions are then held together in a crystal lattice by electrostaticforces

Define covalent bonds.

the electronegativity difference is slight and the atoms share the electrons

Define polar covalent bonds.

the electronegativity difference is enough that the electrons are not shared equally and they tend to spend more time near the more electronegative atom

Ammonium

=

Acetate

=

Cyanide

=

Phosphite

=

Phosphate

=

Hydrogen Phosphate

=

Dihydrogen Phosphate

=

Sulfite

=

Sulfate

=

Thiosulfate

=

Peroxide

=

Hydroxide

=

Permanganate

=

Carbonate

=

Hydrogen Carbonate

=

Nitrite

=

Nitrate

=