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46 Cards in this Set
- Front
- Back
Kinetic Molecular Theory |
1) gases consist of large numbers of molecules that are in continuous random motion 2)Combined volume of all the molecules of the gas is negligible relative to the total volume in which the gas is contained 3)Attractive and repulsive forces between gas molecules are negligible 4)Energy can be transferred between molecules during collisions but the average kinetic energy doesn't change with time as long as the temperature of the gas stays constant 5) Average kinetic energy of the molecules is proportional to the absolute temperature Ave |
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Average |
temperature is related to their _______ kinetic |
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different |
individual molecules can have ________ speeds of motion |
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Ump |
most probable speed (most molecules are this fast) |
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Uav |
average speed of the molecules |
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Urms |
the root mean square speed, the one associated with their average kinetic energy |
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Average Kinetic Energy |
At any given temperature, the ______ _____ _____ of molecules is the same |
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same temperature |
1/2 m(Urms)^2 is the same for 2 gases at the ____ ____ |
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Greater |
if a gas has low mass, it's speed will be ________ than for a heavier molecule |
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Effusion |
the escape of gas molecules through a tiny hole into an evacuated space |
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Diffusion |
the speed of one substance throughout a space or a second substance |
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Ideal- Gas equation |
in the real world, the behavior of gases only conforms to the _______ at relatively high temperature and low pressure |
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same different same |
even the ___ gas will show wildly ______ behavior under high pressure at _____ temperatures |
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high low |
the assumptions made in the kinetic molecular model break down at _____ pressure and/ or _______ temperature |
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ideal gas equation |
can be adjusted to take these deviations from ideal behavior into account |
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van der waals equation |
corrected ideal gas equation |
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pressure |
the _______ adjustment is due to the fact that molecules attract and repel each other |
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volume |
the _________ adjustment is due to the fact that molecules occupy some space on their own |
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Van der waals equation |
(p+ n^2a/v^2)(v-nb)=nrt |
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Mendeleev and Meyer |
independently came to the same conclusion about how elements should be grouped |
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chemical properties |
chemists mostly credit mendeleev because he also used __________ _______ to organize the table and predicted some missing elements and their expected properties including germanium |
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Atomic Masses |
mendeleev's table was based on ________ ______; it was the most fundamental property of elements known at the time |
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earnest rutherford |
about 35 years later, the nuclear atom was discovered by ____________ |
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Atomic Number experimentally |
mosley developed the concept of _________ _______ ______. the number of protons was considered the basis for the periodic property of elements |
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periodicity |
the repetitive pattern of a property for elements based on atomic number |
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periodicity |
the repetitive pattern of a property for elements based on atomic number |
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valence electrons nucleus |
many properties depend on attractions between ________ and ________ |
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attracted repelled |
electrons are both ______ to the nucleus and ______ by other electrons |
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electron |
the forces an ______ experiences depend on both factors |
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effective nuclear charge |
Zeff= Z-S Z=atomic number s= core electrons around nucleus |
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increases decreases |
effective nuclear charge _____ across a period and _____ down a group |
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nonbonding atomic radius or van der waals radius |
half of the shortest distance separating two nuclei during a collision of atoms |
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decrease increase |
bonding atomic radius tends to _______ from left to right across a period and _______ from top to bottom of a group |
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nuclear charge # of electrons orbitals in which electrons reside |
ionic size depends on |
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nuclear charge # of electrons orbitals in which electrons reside |
ionic size depends on |
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smaller |
cations are ______ than their parent ions |
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nuclear charge # of electrons orbitals in which electrons reside |
ionic size depends on |
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smaller |
cations are ______ than their parent ions |
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removed reduced |
outermost electron is _______ and repulsiones between electrons are _______ |
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nuclear charge # of electrons orbitals in which electrons reside |
ionic size depends on |
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smaller |
cations are ______ than their parent ions |
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removed reduced |
outermost electron is _______ and repulsiones between electrons are _______ |
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larger |
anions are _________ than their parent ions |
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added increased |
electrons are _____ and repulsiones between electrons are __________ |
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isoelectronic series |
in an _____________ ______ ions have the same number of electrons |
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decreases |
iconic size _____ with an increasing nuclear charge |