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46 Cards in this Set

  • Front
  • Back

Kinetic Molecular Theory

1) gases consist of large numbers of molecules that are in continuous random motion


2)Combined volume of all the molecules of the gas is negligible relative to the total volume in which the gas is contained


3)Attractive and repulsive forces between gas molecules are negligible


4)Energy can be transferred between molecules during collisions but the average kinetic energy doesn't change with time as long as the temperature of the gas stays constant


5) Average kinetic energy of the molecules is proportional to the absolute temperature Ave

Average

temperature is related to their _______ kinetic

different

individual molecules can have ________ speeds of motion

Ump

most probable speed (most molecules are this fast)

Uav

average speed of the molecules

Urms

the root mean square speed, the one associated with their average kinetic energy

Average Kinetic Energy

At any given temperature, the ______ _____ _____ of molecules is the same

same temperature

1/2 m(Urms)^2 is the same for 2 gases at the ____ ____

Greater

if a gas has low mass, it's speed will be ________ than for a heavier molecule

Effusion

the escape of gas molecules through a tiny hole into an evacuated space

Diffusion

the speed of one substance throughout a space or a second substance

Ideal- Gas equation

in the real world, the behavior of gases only conforms to the _______ at relatively high temperature and low pressure

same


different


same

even the ___ gas will show wildly ______ behavior under high pressure at _____ temperatures

high


low

the assumptions made in the kinetic molecular model break down at _____ pressure and/ or _______ temperature

ideal gas equation

can be adjusted to take these deviations from ideal behavior into account

van der waals equation

corrected ideal gas equation

pressure

the _______ adjustment is due to the fact that molecules attract and repel each other

volume

the _________ adjustment is due to the fact that molecules occupy some space on their own

Van der waals equation

(p+ n^2a/v^2)(v-nb)=nrt

Mendeleev and Meyer

independently came to the same conclusion about how elements should be grouped

chemical properties

chemists mostly credit mendeleev because he also used __________ _______ to organize the table and predicted some missing elements and their expected properties including germanium

Atomic Masses

mendeleev's table was based on ________ ______; it was the most fundamental property of elements known at the time

earnest rutherford

about 35 years later, the nuclear atom was discovered by ____________

Atomic Number experimentally

mosley developed the concept of _________ _______ ______. the number of protons was considered the basis for the periodic property of elements

periodicity

the repetitive pattern of a property for elements based on atomic number

periodicity

the repetitive pattern of a property for elements based on atomic number

valence electrons


nucleus

many properties depend on attractions between ________ and ________

attracted


repelled

electrons are both ______ to the nucleus and ______ by other electrons

electron

the forces an ______ experiences depend on both factors

effective nuclear charge

Zeff= Z-S


Z=atomic number


s= core electrons around nucleus

increases


decreases

effective nuclear charge _____ across a period and _____ down a group

nonbonding atomic radius or van der waals radius

half of the shortest distance separating two nuclei during a collision of atoms

decrease


increase

bonding atomic radius tends to _______ from left to right across a period and _______ from top to bottom of a group

nuclear charge


# of electrons


orbitals in which electrons reside

ionic size depends on

nuclear charge


# of electrons


orbitals in which electrons reside

ionic size depends on

smaller

cations are ______ than their parent ions

nuclear charge


# of electrons


orbitals in which electrons reside

ionic size depends on

smaller

cations are ______ than their parent ions

removed


reduced

outermost electron is _______ and repulsiones between electrons are _______

nuclear charge


# of electrons


orbitals in which electrons reside

ionic size depends on

smaller

cations are ______ than their parent ions

removed


reduced

outermost electron is _______ and repulsiones between electrons are _______

larger

anions are _________ than their parent ions

added


increased

electrons are _____ and repulsiones between electrons are __________

isoelectronic series

in an _____________ ______ ions have the same number of electrons

decreases

iconic size _____ with an increasing nuclear charge