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16 Cards in this Set

  • Front
  • Back
Enthalpy
the heat content that is stored ina chemical system
Exothermic
a reaction in which the enthalpy of the products is smaller than that of the reactants, resulting in heat loss to the surroundings.
Endothermic
a reaction in which the enthalpy of the products is grater than that of the reactants, resulting in heat being taken in from the surroundings.
Activation Energy
the minimum energy required to start a reaction by the breaking of bonds.
Standard Conditions
Pressure- 101 kPa
Temperature- 25 degrees celsius
Concentration- 1.0 mol dm -3
Standard enthalpy change of reaction
the enthalpy change that accompanies a reaction in the molar quantities expressed in a chemical equation under standard conditions, all reactant and products being in their standard states.
Standard enthaply change of combustion
the enthalpy change that takes place when one mole of a substance reacts completely with oxygen under standard conditions, all reactants and products being in their standard states.
Standard enthalpy change of formation
the enthalpy change that takes place when one mole of a compound is formed from its constituent elements in their standard states under standard conditions.
Specific heat capacity
the energy required to raise the temperature of 1g of a substance by 1 degree celsius.
Bond Enthalpy
the enthalpy change that takes place when breaking by homolytic fission, 1 mole of a given bond in the molecules of a gaseous species.
Average bond enthalpy
the average enthalpy change that takes place when breaking by homolytic fisson, 1 mole of a given bond on the molecules of a gaseous species.
Hess' Law
If a reaction can take place by more than one route and the initial and final conditions are the same, the total enthalpy change is the same for each route.
Rate of reaction
the change in concentration of a reactant or a product in a given time.
Boltzmann Distribution
the distribution of energies of molecules at a particular temperature, often shown as a graph.
le Chatelier's principle
states that when a system in dynamic equilibrium is subjected to a change, the position of equilibrium will shift to minimise the change.
Dynamic Equilibrium
the equilibrium that exists in a closed system when the rate of the forward reaction is equal to the rate of the reverse reaction.