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16 Cards in this Set
- Front
- Back
Enthalpy
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the heat content that is stored ina chemical system
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Exothermic
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a reaction in which the enthalpy of the products is smaller than that of the reactants, resulting in heat loss to the surroundings.
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Endothermic
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a reaction in which the enthalpy of the products is grater than that of the reactants, resulting in heat being taken in from the surroundings.
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Activation Energy
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the minimum energy required to start a reaction by the breaking of bonds.
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Standard Conditions
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Pressure- 101 kPa
Temperature- 25 degrees celsius Concentration- 1.0 mol dm -3 |
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Standard enthalpy change of reaction
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the enthalpy change that accompanies a reaction in the molar quantities expressed in a chemical equation under standard conditions, all reactant and products being in their standard states.
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Standard enthaply change of combustion
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the enthalpy change that takes place when one mole of a substance reacts completely with oxygen under standard conditions, all reactants and products being in their standard states.
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Standard enthalpy change of formation
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the enthalpy change that takes place when one mole of a compound is formed from its constituent elements in their standard states under standard conditions.
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Specific heat capacity
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the energy required to raise the temperature of 1g of a substance by 1 degree celsius.
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Bond Enthalpy
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the enthalpy change that takes place when breaking by homolytic fission, 1 mole of a given bond in the molecules of a gaseous species.
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Average bond enthalpy
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the average enthalpy change that takes place when breaking by homolytic fisson, 1 mole of a given bond on the molecules of a gaseous species.
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Hess' Law
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If a reaction can take place by more than one route and the initial and final conditions are the same, the total enthalpy change is the same for each route.
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Rate of reaction
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the change in concentration of a reactant or a product in a given time.
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Boltzmann Distribution
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the distribution of energies of molecules at a particular temperature, often shown as a graph.
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le Chatelier's principle
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states that when a system in dynamic equilibrium is subjected to a change, the position of equilibrium will shift to minimise the change.
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Dynamic Equilibrium
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the equilibrium that exists in a closed system when the rate of the forward reaction is equal to the rate of the reverse reaction.
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