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27 Cards in this Set

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____ a complex biological material primarily composes of cellulose, hemicellulose, lignin, and small amounts of extractives and inorganic materials.


Woods

• Understanding these basic components crucial for various applications, Including ___, ____, and the ___

construction, paper manufacturing and production of bio based materials.

Primary components of wood

a. Total Polysaccharide fraction-Haincel ulice 160-70%)



b. lignin 15-355

Secondary components

a. Tannins


b. Volatile oils and resins


Gums, Latex, alkaloids, dyes etc.


d. Ash 1

a. Total Polysaccharide fraction-Haincel ulice 160-70%)

1. Cellulose (40-50%)2. Hemicellulose (20-35%)

Most abundant macro molecule (and carbohydrate)


Cellulose

The primary structural component of wood


Cellulose

It is a polysaccharide consisting of long chains of glucose Units Inked by B-14-glycosidic bonds.


Cellulose

• Vields glucose upon complete hydrolysis. Partisi hydrolysis yields cellobiose.


Cellulose

•These chains alion parallel to each other to form microfibrils, which are the fundamental structural elements of cellulose


Cellulose

___ imparts strength, rigidity, and high tensile strength to wood, making it resistant to breaking under tension

Cellulose

Cotton fiax: about ___% cellulose


97-99

Wood: about ___ cellulose

50%

Vegetable: about __ percent

33

Nandigestible by humans


cellulose

• food for herbivorous animals (e.g., cows, horses): termites also digest cellulose


cellulose

Of great economic importance, ___ is processed to produce papers and fibres

cellulose

• Functions as supporting material in the cell wall.•


Hemicellulose

A complex and high molecular weight polymer built upon phenylpropane units.


Lignin

Functions of Lignin


1. Serves as a cementing substance that binds wood cells together.


2. Imparts stiffness and rigidity to the cell wall.


3. Increases toxicity of wood to microbiological agents of decay.

Types of Lignin:


Guaiacyl - one methoxyl group (conifers or softwood)


Syringyl - two methoxyl group (hardwood)


para-hydroxylphenyl - without methoxyl group

Often seen as tethering molecules that cross link cellulose microfibrils.•

Hemicellulose

Usually account for up to 20 and 30% of dry weight of wood.•

Hemicellulose

Heterogeneous polysaccharides that have beta-(1-- >4)-linked backbones of glucose, mannose, or xylose linked in equatorial configuration.

Hemicellulose

- one methoxyl group (conifers or softwood)


Guaiacyl

- two methoxyl group (hardwood)


Syringyl

- without methoxyl group

para-hydroxylphenyl