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51 Cards in this Set

  • Front
  • Back
van der Waals forces
collectively forces between molecules, everything has them
Dipole-Dipole interaction
Polar molecule encounters polar molecule
Hydrogen Bonding
O, N, F that have a lone pair bond to a Hydrogen
Dipole-Induced Dipole Interactions
When a dipole pushes a molecule into a induced dipole (water and O2)
polarization
process of inducing a dipole
polarizability
the degree to which the electron cloud of an atom or a molecule can be distorted
Induced-Dipole/Induced-Dipoloe---London Dispersion Factors
nonpolar, everything has them pretty much
vaporization
evaporation the process from liquid to gas
molar enthalpy of vaporization
the energy required to vaporize a sample
condensation
gas to liquid by losing energy
dynamic equilibrium
when the masses of liquid and vapor in the flask remain constant
equilibrium vapor pressure
is the pressure exerted by the vapor in equilibrium with the liquid phase
volatility
the measure of the tendency of the liquid molecules to escape from the liquid phase and enter the vapor pressure at a given temperature
Clausius-Clapeyron equation
provides a method for determining the delta vaporization H not
normal boiling point
the temperature when the substance boils at 1 atm or 760 mmHg
critical point
liquid/vapor exist at the same time
supercritical fluid
gas and a liquid properties and the critical point
surface tension
the energy required to break through the surface or to disrupt a liquid drop and spread out the material
capillary action
climbing of the water in a thin tube
adhesive forces
water to wall
cohesive forces
water to water
viscosity
resistance to flow
solution
homogenous mixture of two or more substances in a single phase
solvent
water usually large quantity
solute
usually solid, what is mixed into something
colligative properties
properies of solution that depend only on the number of solute particles per solvent molecule and not on the identity of the solute
molality
moles of solute/mass of solvent in kg
mole fraction
mole of n/moles total
weight percent
mass of n/mass of total
parts per million
dilution of a solution
saturated
no more particles can dissolve in it
solubility
the concentration of solute in equilibrium with undissolves solute in a saturated solution
miscible
mix
immiscible
don't mix
hydration
water is solvent, exothermic, when ions dissolve in water
Henry's Law
solubility of a gas in a liquid is directly proportional to the gas pressure
Le Chatelier's Principle
states that a change in a any of the factors determining an equlibirum cases the system to adjust by shifting in the direction that reduces or coutneracts the effects of the change
Raoult's Law
vapor pressure of a solvent over a solution is some fraction of the pure solven tequilibirum vapor pressure......P solvent=Xsolvent*Pnotsolvent
osmosis
movement of solvent molecules through a semipermeable membrane from a region of lower solute concentration to a region of higher solute concentration
osmotic pressure equation
Pi=cRT
osmotic pressure
pressure counterbalancing from atmosphere and the water in a tube
van't Hoff factor
i=usually 1 unless ion, then count them
colloidal dispersion (Colloids)
represent a state intermediate between a solution and a suspension
Tyndall effect
colloids scatter visible light when dispersed in a solvent, making the mixture appear cloudy
sol
colloidal dispersion of a solid substance in a fluid medium
gel
colloidal dispersion that has a structure that prevents it from being mobile
hydrophobid/hydrophyllic
water hating/water loving
emulsions
colloidal dispersion of one liquid in another, such as oil in water
emulsifying agent
soap that allows for milk (water and oil) to form
surfactants
substances such as soaps that affect the properties of surfaces
detergent
special sufactant