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29 Cards in this Set

  • Front
  • Back

Rate of reaction

The speed in which a reaction occurs

What is required for a chemical reaction to occur

-particles of reactants must collide


-colliding particles must have sufficient energy to overcome activation energy


-when colliding particles have less energy than the activation energy, a non productive collision occurs

What is a chemical reaction dependent on?

-magnitude of activation energy


-frequencies of collisions between reactant particles


-energy of commission particles relative to activation energy


-orientation of colliding particles

Exothermic reaction

Energy released during reaction

Endothermic reaction

Energy absorbed during reaction

High reactants, low products

Exothermic

Low reactants, high products

Endothermic

Factors that affect reaction rate

-Concentration (number of reactants)


-pressure (concentration and frequency)


-temperature of reaction mixture (kinetic energy)


-surface area of solid reactants (more reactions)


-catalyst

Chemical equilibrium

When reactants and products reach constant values after a forward and back reaction occur at the same time

State two conditions required for a reversible reaction to come to equilibrium

The reaction must be carried:


-in a close system


-at a constant temperature

How can the equilibrium position of a reaction be shifted?

Altering:


-concentration


-pressure


-temperature

How does altering concentration affect a system in equilibrium

-Increasing the concentration of the reactants results results in the consumption of the added reactant, shifting the reaction to the products


-decreasing the concentration results in the replacement of the removed reactants and shifts the reaction to the formation of reactants

How does altering pressure affect a system in equilibrium?

-can only be applied to systems involving gas.


-increasing the pressure of a system in equilibrium by decreasing the volume of the reactant vessels allows the reaction to produce less gas molecules


-decreasing the pressure results in a greater number of gas molecules

What is a decomposition reaction

The breaking up of a single compound into simpler substances

Decomposition reaction

AB ➡ A + B

What is a dissociation reaction

A reaction where ions from an ionic lattice are set free.


When an ionic solid dissolves in water:


-positive and negative ions in the ionic lattice are separated


-an attraction between the ions and polar water molecules occurs

Dissociation reaction

NaCl (s) + aq ➡ Na^+(aq) + Cl^-(aq)

What is an ionisation reaction

The formation of ions where there were none before


-only applied to covalent molecules (polar molecules in particular)

Ionisation reaction

-covalent bond is broken in the dissolved molecule


HCl(g) + H2O(l)➡H3O^+(aq) + Cl^-(aq)



-covalent bond is broken in the covalent molecule


NH3(aq) + H2O(l)➡NH4^+(aq) + OH(aq)

What is a Single displacement reaction

Involves one element replacing the other in a compound . An element will only replace another if it is more reactive

Single displacement reaction

A + BC ➡ B + AC

What is a double displacement reaction

Involves reaction of two compounds to form two new compounds

Double displacement reaction

AB + CD ➡ AD + CB

What is a precipitate

An insoluble product formed from a reaction taking place in an aqueous solution where the ions are more attracted to each other than the water.

What is an acid

Proton hydrogen donor


pH below 7

What is a base

Proton hydrogen acceptors


pH above 7

What is an alkali

A base that Is soluble in water

What is pH scale

Describes the strength of an acidic or basic solution

What is an indicator

A chemical that changes colour in the presence of an acid or an alkali