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9 Cards in this Set

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  • Back

What happens when a molecule absorbs infrared radiation?

It makes the covalent bond vibrate more in a stretching or bending motion.

What factors affect the amount of vibration of a bond?

Bond strength, bond length, mass of each atom in the bond.

How does infrared spectroscopy work?

Every bond has a unique vibration frequency. Bonds absorb radiation that has the same frequency as their frequency of vibration. Infrared radiation emerged from a sample is missing the frequencies that have been absorbed.

2 peaks that must be present to identify a substance as carboxylic acid.

Very broad peak at 2500-3300 cm^-1 (OH group)


Sharp peak at 1680-1750 cm^-1 (C=O group)

m/z value of CH3^+

15

m/z value of OH^-

17

m/z value of C2H5^+

29

m/z value of C3H7^+

43

m/z value of C4H9^+

57