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10 Cards in this Set

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N = ?

Principal number and Orbital energy(size) (1, 2, 3, ...)

l = ?

Orbital shape (0 to n-1). Also corresponds to s, p, d, and f orbitals respectively.

Mi = ?

Orbital orientation (-l to 0 to +l)

Ms=?

Spin (+1/2 or -1/2)

Exclusion principle

No two electrons in the same atom can have the same four quantum numbers.

Shielding

Reduces the full nuclear charge to an effective nuclear charge, the nuclear charge an electron actually experiences, and this lower nuclear charge makes the electron easier to remove.

Effects of penetration

It increases the nuclear attraction for a 2s electron over that of for a 2p electron. It decreases the shielding of a 2s electron by the 1s electron.

Electron configuration vs orbital diagram.

Electron configuration involves n, l, ml, ms. Orbital diagram involves boxes with arrows drawn in.

Special rule for 3d orbitals.

Best examples are chromium and copper, though this applies to other elements too.

Valence electrons

For main-group elements, the valence electrons are the outer electrons. For transition elements, in addition to the outer ns electron, the (n-1)d electrons are also valence electrons.