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43 Cards in this Set
- Front
- Back
Biochemistry |
The study of chemical substances found in living organisms and the chemical interactions of these substances with each other. |
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Biochemcal substances |
A chemical substance found within the living organism |
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Bioinorganic and bioorganic substances. |
Biochemical substances |
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Bioinorganic substances |
70% water and 5% inorganic salts |
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Bioorganic substances |
15% proteins, 8% lipids, 2% Carbohydrates and 25% nucleic acids |
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Carbohydrates |
The most abundant class of bioorganic molecules on planet earth. Constiute about 75% by mass of dry plant materials. |
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Cellulose |
Serves as structural elements |
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Starch |
Provide energy reserves for plants |
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2/3rds carbohydrates by mass |
Average human diet |
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Carbohydrate oxidation |
Provides energy |
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Glycogen |
Provides short term energy reserve |
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Carbos linked to lipids |
Structural components of a call membranes |
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Carbos linked to protiens |
Function in a variety of cell-cell and cell-molecule recognition processes. |
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Polyhydrocxy aldehydes or polyhydroxy ketones |
What carbohydrates yields upon hydrolysis |
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Monosaccharides |
A carbohydrate that contains a single polyhydroxy aldehyde or ketone unit. |
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Oligosaccharides |
A carbohydrate that contains two to ten monosaccharide units covalently bonded to each other. |
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Disaccharides |
A carbohydrate that contains two monosaccharide units covalently bonded to each other. |
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Polysaccharides |
A polymeric carbohydrate that contains many monosaccharide units covalently bonded to each other. |
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Handedness |
An important general structural property which most monosaccharides exhibit. |
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Mirror image |
Is the reflection of an object in a mirror. |
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Superimposable mirror images |
Are images that coincide at all points when the images are laid upon each other. |
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Nonsuperimposable images |
Are images where not all pints coincide when the images are laid upon each other. |
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Cheir means hand |
Greek word for chiral. |
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Chiral center. |
Is an atom in a molecule that has your different groups tetrahedraly bonded to it. |
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Chiral molecule |
Is a molecule whose mirror images are not superimposable. |
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Achiral molecules |
A molecule whose mirror images are superimposable. |
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Right handed |
Naturally occuring monosaccharides are almost always ..... |
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Right handed monosaccharides |
Plants, our dietary source of carbohydrates, produces only .... |
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Left handed molecules |
Amino acids, biding blocks of protein, are always ... |
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Sterioisomers |
Are isomers that have the same molecular and structural formulas but differ in the orientation of atoms in space. |
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Structural rigidity |
Is caused by restricted rotation about chemical bonds. |
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Enantiomers |
Are sterioisomers whose molecules are nonsuoerimposable mirror images of each other. |
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Enantios which means opposite |
Greek word of enantiomer |
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Diastereomers |
Are sterioisomers whose molecules are not mirror images of each other. |
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Fischer projection formula |
A two dimensional structural notation for showing the spatial arrangement of groups about chiral centres in molecules. |
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Herman Emil Fischer |
A German chemist that developed the two dimensional system for specyfiying chirality. |
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Glyceraldehyde |
The smallest monosaccharide that has a chiral centre. |
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Epimers |
Are diastereomers whose molecules differ only in the configuration at one chiral centers. |
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Aldose |
A monosaccharide that contains an aldehyde functional group |
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Ketose |
A monosaccharide that contains a ketone functional group. |
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1. D and L isomerism 2. Epimerism 3. Aldo-keto isomerism 4. Anomerism |
Four common types of isomerism in carbohydrates. |
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Haworth projection formula |
A two dimensional structural notation that specifies the three dimensional structure of a cyclic form of a monosaccharide. |
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Walter Norman Haworth |
A british carbohydrate chemist who developed Haworth projection formulas. |