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43 Cards in this Set

  • Front
  • Back

Biochemistry

The study of chemical substances found in living organisms and the chemical interactions of these substances with each other.

Biochemcal substances

A chemical substance found within the living organism

Bioinorganic and bioorganic substances.

Biochemical substances

Bioinorganic substances

70% water and 5% inorganic salts

Bioorganic substances

15% proteins, 8% lipids, 2% Carbohydrates and 25% nucleic acids

Carbohydrates

The most abundant class of bioorganic molecules on planet earth. Constiute about 75% by mass of dry plant materials.

Cellulose

Serves as structural elements

Starch

Provide energy reserves for plants

2/3rds carbohydrates by mass

Average human diet

Carbohydrate oxidation

Provides energy

Glycogen

Provides short term energy reserve

Carbos linked to lipids

Structural components of a call membranes

Carbos linked to protiens

Function in a variety of cell-cell and cell-molecule recognition processes.

Polyhydrocxy aldehydes or polyhydroxy ketones

What carbohydrates yields upon hydrolysis

Monosaccharides

A carbohydrate that contains a single polyhydroxy aldehyde or ketone unit.

Oligosaccharides

A carbohydrate that contains two to ten monosaccharide units covalently bonded to each other.

Disaccharides

A carbohydrate that contains two monosaccharide units covalently bonded to each other.

Polysaccharides

A polymeric carbohydrate that contains many monosaccharide units covalently bonded to each other.

Handedness

An important general structural property which most monosaccharides exhibit.

Mirror image

Is the reflection of an object in a mirror.

Superimposable mirror images

Are images that coincide at all points when the images are laid upon each other.

Nonsuperimposable images

Are images where not all pints coincide when the images are laid upon each other.

Cheir means hand

Greek word for chiral.

Chiral center.

Is an atom in a molecule that has your different groups tetrahedraly bonded to it.

Chiral molecule

Is a molecule whose mirror images are not superimposable.

Achiral molecules

A molecule whose mirror images are superimposable.

Right handed

Naturally occuring monosaccharides are almost always .....

Right handed monosaccharides

Plants, our dietary source of carbohydrates, produces only ....

Left handed molecules

Amino acids, biding blocks of protein, are always ...

Sterioisomers

Are isomers that have the same molecular and structural formulas but differ in the orientation of atoms in space.

Structural rigidity

Is caused by restricted rotation about chemical bonds.

Enantiomers

Are sterioisomers whose molecules are nonsuoerimposable mirror images of each other.

Enantios which means opposite

Greek word of enantiomer

Diastereomers

Are sterioisomers whose molecules are not mirror images of each other.

Fischer projection formula

A two dimensional structural notation for showing the spatial arrangement of groups about chiral centres in molecules.

Herman Emil Fischer

A German chemist that developed the two dimensional system for specyfiying chirality.

Glyceraldehyde

The smallest monosaccharide that has a chiral centre.

Epimers

Are diastereomers whose molecules differ only in the configuration at one chiral centers.

Aldose

A monosaccharide that contains an aldehyde functional group

Ketose

A monosaccharide that contains a ketone functional group.

1. D and L isomerism


2. Epimerism


3. Aldo-keto isomerism


4. Anomerism

Four common types of isomerism in carbohydrates.

Haworth projection formula

A two dimensional structural notation that specifies the three dimensional structure of a cyclic form of a monosaccharide.

Walter Norman Haworth

A british carbohydrate chemist who developed Haworth projection formulas.