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13 Cards in this Set

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Water is both _____ has has ____ charges.

polar; partial

Hydrophobic characteristics?


Hydrophilic characteristics?

Hydrophobic: non-polar, uncharged, lipid/fat soluble




Hydrophilic: polar, charged, water soluble


ex: glucose, fructose, galactose (H-bonding!)

Assisted solubility?

Molecules which are more hydrophobic than hydrophilic may be transported by other means:




chylomicroans: fats


albumin: FA's


Hemoglobin: O

The bigger the Keq means what?

The bigger the Keq the further to the right the reaction will occur.

Strength of ionization is by the constant:


Describe strong and weak electrolytes. Which way does the reaction want to go for each:




MX <--> M + X

Kd


Strong electrolytes dissociate: MX -->> M + X


Weak electrolytes do not dissociate as well:


MX <<-- M + X



BL acids are defined as proton ____


BL bases are defined as ____

BAPD


BBPA

Dissociation constant

Look at SG pg 6...has [H+] in equation.

If Ka = 2.4


and Ka = 1.89E-3




which is the stronger acid?

Bigger the Ka, stronger the acid.

____ are solutions containing "acid-base" pairs that resist changes in pH.

Buffers

For buffers, [H+] is proportional to ______ ratio.




Equation for dissociation constant? (Ka)


HA <--> H+ + A-

[acid]/[base]




Ka = [H+] [A-] / [HA]




**you can solve for H

Equations on SG page 8 and 9.




B. on page 9!! Look at it!

page 8 and 9.

Buffers: Where is the least change in pH?


Buffer range of a weak acid of a pKa of 4.76?

least change in pH is where the pH is close to the value of the pKa.


pH = 3.76-5.76

T/F buffer capacity is directly related to buffer concentration?




ex. .20M acetic acid has twice the buffer capacity of .10M acetic acid.

True!