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88 Cards in this Set
- Front
- Back
number of naturally occuring elements
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90
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number of elements found in living organisms in substantial amounts
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12
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four elements that make up 96.3% of humans
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carbon
hydrogen oxygen nitrogen |
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Ions
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lost or gained electrons
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isotopes
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different number of neutrons
*unstable isotopes emit radiation=radioactiveisotopes |
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key to chemical behavior of atom
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number and arrangemnet of its electrons in their orbitals
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Bohr Model
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electrons in discrete orbits
*models you use to draw on paper and show electron activity |
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orbital limit
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no orbital can contain more than two electrons
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how is electrons potential energy determined?
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electrons farther from nucleus have more energy.
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redox reactions
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when one molecule is oxidized and while another is reduced in the same reaction
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ionic bonds
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formed by the attraction of oppositely charged ions
*gain or loss of electrons forms ions |
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covalent bonds
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when atoms share 2 or more valence electrons
*results in no net charge, no unpaired electrons, satisfies octet rule. |
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single covalent bond
double covalent bond |
shared pair of electrons
i.e. H--H 2 shared pairs (total 4 electrons) i.e. O--O |
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octet rule
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tend to fill valence shells
2 electrons in first level 8 alllowed in rest of levels |
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electronegativity
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an atoms tendency to attract electrons and form thus form negative ions
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nonpolar coval. bond
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equal sharing of electrons (equal electronegativity)
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polar coval bond
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unequal sharing of electrons(unequal electronegativity)
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chemical reactions
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formation or breaking of chemical bonds
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importance of water
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life is inextricably(complexy tangled) tied to water
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most outstanding chemical property of water
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ability to form hydrogen bonds
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hydrogen bonds
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bond between partially negative O atoms and the partially postitive H atoms of two water molecules.
http://1.bp.blogspot.com/-2GhcoI0scaQ/TbmEeRWuYoI/AAAAAAAAAOk/ki1-Y2IS17Y/s1600/3D_model_hydrogen_bonds_in_water.jpg |
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polarity of water
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bond between oxygen and hydrogen are highly polar.
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cohesion
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water molecules stick to other molecules
*hydrogen bonding |
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adhesion
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water molecules stick to other polar molecules
*hydrogen bonding |
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properties of water
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-high specific heat
-high heat of vaporization -ice=less dense than liquid H2O -good solvent -organizes nonpolar molecules(i.e. oil) -can form ions |
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acid
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substance that dissociates in water to increase the H+ (lower pH)
i.e.hydrochloric acid |
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base
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substance that combines with H+ dissolved in water and lowers H+
i.e. sodium hydroxide |
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buffers
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-substance that resist changes in pH
-release hydrogen ions when base added -absorbs hydrogen ions when acid added *bicarbonate ion + hydrogen ion |
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framework of biological molecules consists primarily of carbon bonded to:
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-other carbons
-O,N,S,P,or H *can form up to 4 covalent bonds |
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hydrocarbons
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molecules consisting of only carbon and hydrogen
*store energy, good for fuel *nonpolar *functional groups attach and add chemical properties (polarity, pH) |
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isomers
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molecules with the same molecular or empirical formula
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monomer
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small, similar chemical subunits
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polymer
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built by linking monomers.
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4 organic macromolecules
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-carb
-nucleic acids -proteins -lipids |
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dehydration synthesis
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-formation of large molecules by removal of water
-monomers join to form polymers |
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hydrolysis
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*opposite of dehydration.
-breakdown of large molecules by addition of water -polymers broken down to monomers |
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carbohydrates
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-molecules with 1:2:1 ration carbon, hydrogen oxygen.
-good for storing energy |
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simple sugar
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can have as little as three carbons, but those that are key to energy storage have six
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polysaccharides
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-formed by dehydration synthesis
-plants use starch -animals use glycogen *plants=cellulose *anthropods/fungi+chitin |
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Nucleic acids
-polymer -monomer |
-polymer=nucleic acid
-monomer=nucleotide |
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nucleotide structure
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sugar+phosphate+nitrogenous base=
purines and pyrimidines |
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DNA
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-encodes info for amino acid sequence of proteins
-double helix (2 polynucleotide strands connected by hydrogen bonds) -A&T -C&G |
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RNA
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-ribose, not deoxyribose
-A&U -single polynucleotide strand -uses info in DNA sequence amino acids in protein |
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NAD+ & FAD+
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electron carriers for many cellular reactions
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Amino acid structure
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-amino group
-side chain/R group -carboxyl group -single hydrogen |
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protein function
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-enzyme cataylsis
-defense -transport -support -motion -regulation -storage |
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formation of peptide bond
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- amino acids joined by dehydration synthesis=peptide bond
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how to determine protein function
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shape determines function
-primary structure -secondary -tertiary -quaternary |
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chaperones
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-proteins that help proteins fold correctly
-deficiencies in chaperones=cystic fibrosis |
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denaturation
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-protein loses structure and function
due to change in -pH -temp -ionic concentration |
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lipids
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-insoluble in water
-high proportion of nonpolar c-h bonds=hydrophobic |
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fats
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triglycerides
-composed 1 glycerol and 3 fatty acids saturated -no double bonds, high melt. unsat -1 or more double bonds,low melt |
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phospholipids
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-glycerol
-2 fatty acids -phosphate group |
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micelles
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lipid molecules with polar head and nonpolar tail
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who discovered cells
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robert hooke
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cell thoery
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-all organisms are composed of cells
-cells are the smallest living things -cells arise only from pre existing cells |
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prok and euk similarities
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-nucleus where DNA is located
-cytoplasm -ribosomes -plama membrane |
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prokaryotic
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-simplest organisms
-lack membbrane-bound nucleus -cell wall outside of plasma membrane two domains -archaea & bacteria |
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bacteria cell walls
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-protect cell, maintain shape, prevent excessice intake or loss of water
-archaea lack peptidoglycan |
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flagella
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present in some prok cells and used for motion
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eukaryotic
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-posses membrane-bound nucleus
-compartmentalization via endomembrane system -possess cytoskeleton for support |
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ribosomes
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-cells protein synthesis machine
-free in cytoplasm or associated with intrnal membranes |
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endomembrane system
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Rough ER
-Smooth ER -Golgi apparatus -Vesicles *fundamental distinctions between euks and proks |
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Rough endoplasmic reticulum
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-ribosomes attached;give rough look
-synthesis of proteins to be secreted |
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Smooth endoplasmic reticulum
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-few bound ribosomes
-synthesis, store ca2+, detoxification |
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golgi apparatus
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-flattened stacks of interconnected membranes
-collects, packages, and distributes molecules synthesized at one location and used at another |
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lysosomes
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Enzymes catalyze breakdown of macromolecules and destroy cells or foreign matter
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microbodies
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include peroxisome
-oxidize fatty acids |
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vacuoles
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-central vacuole, contractile vacuole and storage vaculoes
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mitochondria
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-proteins carry out oxidative metabolism
*metabolizes sugar to generate ATP |
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chloroplast
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-contain chlorophyll for photosynthesis
-2 membranes *use light to generate ATP and sugar |
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cytoskeleton
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network of protein fibers
-support shape of cell -keep organelles in fixed locations -microfilaments(actin) -microtubles -intermediate fibers |
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centrosomes
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-plants and fungi lack this
-microtubule organizing center |
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cell movement
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actin filaments
microtubules or both |
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euk cell walls
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plants and protist
-cellulose fungi -chitin |
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cellular respiration
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-oxidation of organic compounds to extract energy from chemical bonds
- |
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dehydrogenation
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-loss of hydrogen atom
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redox
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-tranfer of electrons that carry energy with them
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NAD+
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electron carrier
-accepts 2 electrons and 1 proton=NADH -reversible |
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ATP
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-cells use ATP to drive endergonic reactions
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oxidation of glucose
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-glycolysis
-pyruvate oxidation -krebs cycle -electron transport chain & chemiosmosis |
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glycolysis
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-converts 1 glucose to 2 pyruvate
-10 step biochemical pathway -net energy production 2atp 2nadh |
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NADH must be recycled
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-aerobic respiration
-fermentation |
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pyruvate oxidation
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-occurs in mitochondria or plasma membrane
3 carbon pyruvate molecule: 1 CO2 1 NADH 1 Acetyl CoA |
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krebs cycle
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-oxidizes acetyl group from pyruvate
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after krebs
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glucose has been oxidized to
-6 CO2 -4ATP -10NADH -2FADH2 |
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electron transport chain
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-electrons from NADH & FADH2 are transferred to complexes of the ETC
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Chemiosmosis
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-uses gradient to produce atp
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